trans-Carbonyl­chloridobis[diphen­yl(4-vinyl­phen­yl)phosphane-κP]rhodium(I)

In the title compound, trans-[RhCl(C(20)H(17)P)(2)(CO)], the Rh(I) atom is situated on a center of symmetry, resulting in a statistical 1:1 disorder of the chloride [Rh—Cl = 2.383 (2) Å] and carbonyl [Rh—C = 1.752 (7) Å] ligands. The distorted trans square-planar environment is completed by two P at...

Descripción completa

Detalles Bibliográficos
Autores principales: Ogutu, Hezron, Kirsten, Leo, Meijboom, Reinout
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344302/
https://www.ncbi.nlm.nih.gov/pubmed/22590068
http://dx.doi.org/10.1107/S1600536812013669
_version_ 1782231961745489920
author Ogutu, Hezron
Kirsten, Leo
Meijboom, Reinout
author_facet Ogutu, Hezron
Kirsten, Leo
Meijboom, Reinout
author_sort Ogutu, Hezron
collection PubMed
description In the title compound, trans-[RhCl(C(20)H(17)P)(2)(CO)], the Rh(I) atom is situated on a center of symmetry, resulting in a statistical 1:1 disorder of the chloride [Rh—Cl = 2.383 (2) Å] and carbonyl [Rh—C = 1.752 (7) Å] ligands. The distorted trans square-planar environment is completed by two P atoms [Rh—P = 2.3251 (4) Å] from two diphen­yl(4-vinyl­phen­yl)phosphane ligands. The vinyl group is disordered over two sets of sites in a 0.668 (10):0.332 (10) ratio. The crystal packing exhibits weak C—H⋯Cl and C—H⋯O hydrogen bonds and π–π inter­actions between the phenyl rings of neighbouring mol­ecules, with a centroid–centroid distance of 3.682 (2) Å.
format Online
Article
Text
id pubmed-3344302
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-33443022012-05-15 trans-Carbonyl­chloridobis[diphen­yl(4-vinyl­phen­yl)phosphane-κP]rhodium(I) Ogutu, Hezron Kirsten, Leo Meijboom, Reinout Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, trans-[RhCl(C(20)H(17)P)(2)(CO)], the Rh(I) atom is situated on a center of symmetry, resulting in a statistical 1:1 disorder of the chloride [Rh—Cl = 2.383 (2) Å] and carbonyl [Rh—C = 1.752 (7) Å] ligands. The distorted trans square-planar environment is completed by two P atoms [Rh—P = 2.3251 (4) Å] from two diphen­yl(4-vinyl­phen­yl)phosphane ligands. The vinyl group is disordered over two sets of sites in a 0.668 (10):0.332 (10) ratio. The crystal packing exhibits weak C—H⋯Cl and C—H⋯O hydrogen bonds and π–π inter­actions between the phenyl rings of neighbouring mol­ecules, with a centroid–centroid distance of 3.682 (2) Å. International Union of Crystallography 2012-04-04 /pmc/articles/PMC3344302/ /pubmed/22590068 http://dx.doi.org/10.1107/S1600536812013669 Text en © Ogutu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ogutu, Hezron
Kirsten, Leo
Meijboom, Reinout
trans-Carbonyl­chloridobis[diphen­yl(4-vinyl­phen­yl)phosphane-κP]rhodium(I)
title trans-Carbonyl­chloridobis[diphen­yl(4-vinyl­phen­yl)phosphane-κP]rhodium(I)
title_full trans-Carbonyl­chloridobis[diphen­yl(4-vinyl­phen­yl)phosphane-κP]rhodium(I)
title_fullStr trans-Carbonyl­chloridobis[diphen­yl(4-vinyl­phen­yl)phosphane-κP]rhodium(I)
title_full_unstemmed trans-Carbonyl­chloridobis[diphen­yl(4-vinyl­phen­yl)phosphane-κP]rhodium(I)
title_short trans-Carbonyl­chloridobis[diphen­yl(4-vinyl­phen­yl)phosphane-κP]rhodium(I)
title_sort trans-carbonyl­chloridobis[diphen­yl(4-vinyl­phen­yl)phosphane-κp]rhodium(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344302/
https://www.ncbi.nlm.nih.gov/pubmed/22590068
http://dx.doi.org/10.1107/S1600536812013669
work_keys_str_mv AT ogutuhezron transcarbonylchloridobisdiphenyl4vinylphenylphosphanekprhodiumi
AT kirstenleo transcarbonylchloridobisdiphenyl4vinylphenylphosphanekprhodiumi
AT meijboomreinout transcarbonylchloridobisdiphenyl4vinylphenylphosphanekprhodiumi

Ejemplares similares