cis-Tetra­chloridobis(1H-imidazole-κN (3))platinum(IV)

In the title complex, cis-[PtCl(4)(C(3)H(4)N(2))(2)], the Pt(IV) ion lies on a twofold rotation axis and is coordinated in a slightly distorted octa­hedral geometry. The dihedral angle between the imidazole rings is 69.9 (2)°. In the crystal, mol­ecules are linked by N—H⋯Cl hydrogen bonds, forming a...

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Detalles Bibliográficos
Autores principales: Bokach, Nadezhda A., Kukushkin, Vadim Yu., Izotova, Yulia A., Usenko, Natalia I., Haukka, Matti
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344304/
https://www.ncbi.nlm.nih.gov/pubmed/22590070
http://dx.doi.org/10.1107/S1600536812013323
Descripción
Sumario:In the title complex, cis-[PtCl(4)(C(3)H(4)N(2))(2)], the Pt(IV) ion lies on a twofold rotation axis and is coordinated in a slightly distorted octa­hedral geometry. The dihedral angle between the imidazole rings is 69.9 (2)°. In the crystal, mol­ecules are linked by N—H⋯Cl hydrogen bonds, forming a three-dimensional network.

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