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Bis{2-amino-2-oxo-N-[(1E)-1-(pyridin-2-yl-κN)ethylidene]acetohydrazidato-κ(2) N′,O (1)}nickel(II)
In the title compound, [Ni(C(9)H(9)N(4)O(2))(2)], the Ni(II) ion is situated on a twofold rotation axis and is coordinated by two O and four N atoms from two tridentate {2-amino-2-oxo-N-[(1E)-1-(pyridin-2-yl-κN)ethylidene]acetohydrazidate ligands in a distorted octahedral geometry. In the crystal,...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344308/ https://www.ncbi.nlm.nih.gov/pubmed/22590074 http://dx.doi.org/10.1107/S1600536812014109 |
| _version_ | 1782231963102347264 |
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| author | Kane, Cheikh Hamidou Thiam, Ibrahima Elhadj Tamboura, Farba Bouyagui Gaye, Mohamed Retailleau, Pascal |
| author_facet | Kane, Cheikh Hamidou Thiam, Ibrahima Elhadj Tamboura, Farba Bouyagui Gaye, Mohamed Retailleau, Pascal |
| author_sort | Kane, Cheikh Hamidou |
| collection | PubMed |
| description | In the title compound, [Ni(C(9)H(9)N(4)O(2))(2)], the Ni(II) ion is situated on a twofold rotation axis and is coordinated by two O and four N atoms from two tridentate {2-amino-2-oxo-N-[(1E)-1-(pyridin-2-yl-κN)ethylidene]acetohydrazidate ligands in a distorted octahedral geometry. In the crystal, N—H⋯O and N—H⋯N hydrogen bonds link the molecules into columns in [001]. The porous crystal packing is further stabilized via π–π interactions between the pyridine rings of neighbouring molecules [centroid–centroid distance = 3.746 (3) Å] with voids of 270 Å(3). |
| format | Online Article Text |
| id | pubmed-3344308 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33443082012-05-15 Bis{2-amino-2-oxo-N-[(1E)-1-(pyridin-2-yl-κN)ethylidene]acetohydrazidato-κ(2) N′,O (1)}nickel(II) Kane, Cheikh Hamidou Thiam, Ibrahima Elhadj Tamboura, Farba Bouyagui Gaye, Mohamed Retailleau, Pascal Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(9)H(9)N(4)O(2))(2)], the Ni(II) ion is situated on a twofold rotation axis and is coordinated by two O and four N atoms from two tridentate {2-amino-2-oxo-N-[(1E)-1-(pyridin-2-yl-κN)ethylidene]acetohydrazidate ligands in a distorted octahedral geometry. In the crystal, N—H⋯O and N—H⋯N hydrogen bonds link the molecules into columns in [001]. The porous crystal packing is further stabilized via π–π interactions between the pyridine rings of neighbouring molecules [centroid–centroid distance = 3.746 (3) Å] with voids of 270 Å(3). International Union of Crystallography 2012-04-06 /pmc/articles/PMC3344308/ /pubmed/22590074 http://dx.doi.org/10.1107/S1600536812014109 Text en © Kane et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Kane, Cheikh Hamidou Thiam, Ibrahima Elhadj Tamboura, Farba Bouyagui Gaye, Mohamed Retailleau, Pascal Bis{2-amino-2-oxo-N-[(1E)-1-(pyridin-2-yl-κN)ethylidene]acetohydrazidato-κ(2) N′,O (1)}nickel(II) |
| title | Bis{2-amino-2-oxo-N-[(1E)-1-(pyridin-2-yl-κN)ethylidene]acetohydrazidato-κ(2)
N′,O
(1)}nickel(II) |
| title_full | Bis{2-amino-2-oxo-N-[(1E)-1-(pyridin-2-yl-κN)ethylidene]acetohydrazidato-κ(2)
N′,O
(1)}nickel(II) |
| title_fullStr | Bis{2-amino-2-oxo-N-[(1E)-1-(pyridin-2-yl-κN)ethylidene]acetohydrazidato-κ(2)
N′,O
(1)}nickel(II) |
| title_full_unstemmed | Bis{2-amino-2-oxo-N-[(1E)-1-(pyridin-2-yl-κN)ethylidene]acetohydrazidato-κ(2)
N′,O
(1)}nickel(II) |
| title_short | Bis{2-amino-2-oxo-N-[(1E)-1-(pyridin-2-yl-κN)ethylidene]acetohydrazidato-κ(2)
N′,O
(1)}nickel(II) |
| title_sort | bis{2-amino-2-oxo-n-[(1e)-1-(pyridin-2-yl-κn)ethylidene]acetohydrazidato-κ(2)
n′,o
(1)}nickel(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344308/ https://www.ncbi.nlm.nih.gov/pubmed/22590074 http://dx.doi.org/10.1107/S1600536812014109 |
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