Bis(acetato-κO)bis­(pyridine-2-aldoxime-κ(2) N,N′)nickel(II)

In the mononuclear title compound, [Ni(CH(3)COO)(2)(C(6)H(6)N(2)O)(2)], the Ni(II) atom is coordinated by two pyridine-2-aldoxime (PaoH) ligands and two acetate groups, with cis coordination for the pairs of identical ligands. While each acetate group binds to the Ni(II) atom by one O atom, each Pao...

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Detalles Bibliográficos
Autor principal: Si, Youtao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344309/
https://www.ncbi.nlm.nih.gov/pubmed/22590075
http://dx.doi.org/10.1107/S1600536812014377
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author Si, Youtao
author_facet Si, Youtao
author_sort Si, Youtao
collection PubMed
description In the mononuclear title compound, [Ni(CH(3)COO)(2)(C(6)H(6)N(2)O)(2)], the Ni(II) atom is coordinated by two pyridine-2-aldoxime (PaoH) ligands and two acetate groups, with cis coordination for the pairs of identical ligands. While each acetate group binds to the Ni(II) atom by one O atom, each PaoH chelates the Ni(II) atom through two N atoms. The O atom on PaoH is not deprotonated and does not participate in bonding to the Ni(II) atom. Thus, the Ni(II) atom exhibits an octa­hedral environment. Intra­molecular O—H⋯O hydrogen-bonding inter­actions and inter­molecular C—H⋯O hydrogen-bonding inter­actions are present in the structure. Adjacent mol­ecules pack along [100] through van der Waals forces.
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spelling pubmed-33443092012-05-15 Bis(acetato-κO)bis­(pyridine-2-aldoxime-κ(2) N,N′)nickel(II) Si, Youtao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mononuclear title compound, [Ni(CH(3)COO)(2)(C(6)H(6)N(2)O)(2)], the Ni(II) atom is coordinated by two pyridine-2-aldoxime (PaoH) ligands and two acetate groups, with cis coordination for the pairs of identical ligands. While each acetate group binds to the Ni(II) atom by one O atom, each PaoH chelates the Ni(II) atom through two N atoms. The O atom on PaoH is not deprotonated and does not participate in bonding to the Ni(II) atom. Thus, the Ni(II) atom exhibits an octa­hedral environment. Intra­molecular O—H⋯O hydrogen-bonding inter­actions and inter­molecular C—H⋯O hydrogen-bonding inter­actions are present in the structure. Adjacent mol­ecules pack along [100] through van der Waals forces. International Union of Crystallography 2012-04-13 /pmc/articles/PMC3344309/ /pubmed/22590075 http://dx.doi.org/10.1107/S1600536812014377 Text en © Youtao Si 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Si, Youtao
Bis(acetato-κO)bis­(pyridine-2-aldoxime-κ(2) N,N′)nickel(II)
title Bis(acetato-κO)bis­(pyridine-2-aldoxime-κ(2) N,N′)nickel(II)
title_full Bis(acetato-κO)bis­(pyridine-2-aldoxime-κ(2) N,N′)nickel(II)
title_fullStr Bis(acetato-κO)bis­(pyridine-2-aldoxime-κ(2) N,N′)nickel(II)
title_full_unstemmed Bis(acetato-κO)bis­(pyridine-2-aldoxime-κ(2) N,N′)nickel(II)
title_short Bis(acetato-κO)bis­(pyridine-2-aldoxime-κ(2) N,N′)nickel(II)
title_sort bis(acetato-κo)bis­(pyridine-2-aldoxime-κ(2) n,n′)nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344309/
https://www.ncbi.nlm.nih.gov/pubmed/22590075
http://dx.doi.org/10.1107/S1600536812014377
work_keys_str_mv AT siyoutao bisacetatokobispyridine2aldoximek2nnnickelii

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