Bis[5-chloro-2-(phenyl­diazenyl-κN (2))pyridine-κN]bis­(thio­cyanato-κN)iron(II)

In the title complex, [Fe(NCS)(2)(C(11)H(8)ClN(3))(2)], the Fe(II) atom is coordinated by two N atoms from the thio­cyanate ligands and four N atoms from two chelating 5-chloro-2-(phenyl­diazen­yl)pyridine ligands, generating a fairly regular FeN(6) octa­hedral coordination geometry. The thio­cyanat...

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Detalles Bibliográficos
Autores principales: Vittaya, Luksamee, Leesakul, Nararak, Pakawatchai, Chaveng, Saithong, Saowanit, Hansongnern, Kanidtha
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344310/
https://www.ncbi.nlm.nih.gov/pubmed/22590076
http://dx.doi.org/10.1107/S1600536812014286
Descripción
Sumario:In the title complex, [Fe(NCS)(2)(C(11)H(8)ClN(3))(2)], the Fe(II) atom is coordinated by two N atoms from the thio­cyanate ligands and four N atoms from two chelating 5-chloro-2-(phenyl­diazen­yl)pyridine ligands, generating a fairly regular FeN(6) octa­hedral coordination geometry. The thio­cyanate ions are in a cis disposition and the pyridine N atoms are in a trans orientation. In the crystal, a short inter­molecular Cl⋯S contact [3.366 (3) Å] is observed.

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