Bis[5-chloro-2-(phenyl­diazenyl-κN (2))pyridine-κN]bis­(thio­cyanato-κN)iron(II)

In the title complex, [Fe(NCS)(2)(C(11)H(8)ClN(3))(2)], the Fe(II) atom is coordinated by two N atoms from the thio­cyanate ligands and four N atoms from two chelating 5-chloro-2-(phenyl­diazen­yl)pyridine ligands, generating a fairly regular FeN(6) octa­hedral coordination geometry. The thio­cyanat...

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Autores principales: Vittaya, Luksamee, Leesakul, Nararak, Pakawatchai, Chaveng, Saithong, Saowanit, Hansongnern, Kanidtha
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344310/
https://www.ncbi.nlm.nih.gov/pubmed/22590076
http://dx.doi.org/10.1107/S1600536812014286
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author Vittaya, Luksamee
Leesakul, Nararak
Pakawatchai, Chaveng
Saithong, Saowanit
Hansongnern, Kanidtha
author_facet Vittaya, Luksamee
Leesakul, Nararak
Pakawatchai, Chaveng
Saithong, Saowanit
Hansongnern, Kanidtha
author_sort Vittaya, Luksamee
collection PubMed
description In the title complex, [Fe(NCS)(2)(C(11)H(8)ClN(3))(2)], the Fe(II) atom is coordinated by two N atoms from the thio­cyanate ligands and four N atoms from two chelating 5-chloro-2-(phenyl­diazen­yl)pyridine ligands, generating a fairly regular FeN(6) octa­hedral coordination geometry. The thio­cyanate ions are in a cis disposition and the pyridine N atoms are in a trans orientation. In the crystal, a short inter­molecular Cl⋯S contact [3.366 (3) Å] is observed.
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spelling pubmed-33443102012-05-15 Bis[5-chloro-2-(phenyl­diazenyl-κN (2))pyridine-κN]bis­(thio­cyanato-κN)iron(II) Vittaya, Luksamee Leesakul, Nararak Pakawatchai, Chaveng Saithong, Saowanit Hansongnern, Kanidtha Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Fe(NCS)(2)(C(11)H(8)ClN(3))(2)], the Fe(II) atom is coordinated by two N atoms from the thio­cyanate ligands and four N atoms from two chelating 5-chloro-2-(phenyl­diazen­yl)pyridine ligands, generating a fairly regular FeN(6) octa­hedral coordination geometry. The thio­cyanate ions are in a cis disposition and the pyridine N atoms are in a trans orientation. In the crystal, a short inter­molecular Cl⋯S contact [3.366 (3) Å] is observed. International Union of Crystallography 2012-04-13 /pmc/articles/PMC3344310/ /pubmed/22590076 http://dx.doi.org/10.1107/S1600536812014286 Text en © Vittaya et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Vittaya, Luksamee
Leesakul, Nararak
Pakawatchai, Chaveng
Saithong, Saowanit
Hansongnern, Kanidtha
Bis[5-chloro-2-(phenyl­diazenyl-κN (2))pyridine-κN]bis­(thio­cyanato-κN)iron(II)
title Bis[5-chloro-2-(phenyl­diazenyl-κN (2))pyridine-κN]bis­(thio­cyanato-κN)iron(II)
title_full Bis[5-chloro-2-(phenyl­diazenyl-κN (2))pyridine-κN]bis­(thio­cyanato-κN)iron(II)
title_fullStr Bis[5-chloro-2-(phenyl­diazenyl-κN (2))pyridine-κN]bis­(thio­cyanato-κN)iron(II)
title_full_unstemmed Bis[5-chloro-2-(phenyl­diazenyl-κN (2))pyridine-κN]bis­(thio­cyanato-κN)iron(II)
title_short Bis[5-chloro-2-(phenyl­diazenyl-κN (2))pyridine-κN]bis­(thio­cyanato-κN)iron(II)
title_sort bis[5-chloro-2-(phenyl­diazenyl-κn (2))pyridine-κn]bis­(thio­cyanato-κn)iron(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344310/
https://www.ncbi.nlm.nih.gov/pubmed/22590076
http://dx.doi.org/10.1107/S1600536812014286
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