(μ-4-Bromo-3,5-dimethyl­pyrazolato-κ(2) N (1):N (2))-μ-chlorido-bis­[bis(4-bromo-3,5-dimethyl­pyrazole-κN (2))chloridocopper(II)] acetonitrile monosolvate

In the title dinuclear complex, [Cu(2)(C(5)H(6)BrN(2))Cl(3)(C(5)H(7)BrN(2))(4)]·CH(3)CN, both Cu(II) ions are in slightly distorted square-pyramidal coordination geometries. The basal planes are defined by three N atoms from three 4-bromo-3,5-dimethyl­pyrazolate ligands, one of which is bridging, an...

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Detalles Bibliográficos
Autores principales: Wei, Wei, Xu, Yanhui
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344311/
https://www.ncbi.nlm.nih.gov/pubmed/22590077
http://dx.doi.org/10.1107/S160053681201402X
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author Wei, Wei
Xu, Yanhui
author_facet Wei, Wei
Xu, Yanhui
author_sort Wei, Wei
collection PubMed
description In the title dinuclear complex, [Cu(2)(C(5)H(6)BrN(2))Cl(3)(C(5)H(7)BrN(2))(4)]·CH(3)CN, both Cu(II) ions are in slightly distorted square-pyramidal coordination geometries. The basal planes are defined by three N atoms from three 4-bromo-3,5-dimethyl­pyrazolate ligands, one of which is bridging, and one Cl ligand. A bridging Cl ligand forms the apical site for both Cu(II) ions. In the crystal, N—H⋯Cl hydrogen bonds connect complex mol­ecules into chains along [100]. Intra­molecular N—H⋯Cl hydrogen bonds are also observed.
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spelling pubmed-33443112012-05-15 (μ-4-Bromo-3,5-dimethyl­pyrazolato-κ(2) N (1):N (2))-μ-chlorido-bis­[bis(4-bromo-3,5-dimethyl­pyrazole-κN (2))chloridocopper(II)] acetonitrile monosolvate Wei, Wei Xu, Yanhui Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title dinuclear complex, [Cu(2)(C(5)H(6)BrN(2))Cl(3)(C(5)H(7)BrN(2))(4)]·CH(3)CN, both Cu(II) ions are in slightly distorted square-pyramidal coordination geometries. The basal planes are defined by three N atoms from three 4-bromo-3,5-dimethyl­pyrazolate ligands, one of which is bridging, and one Cl ligand. A bridging Cl ligand forms the apical site for both Cu(II) ions. In the crystal, N—H⋯Cl hydrogen bonds connect complex mol­ecules into chains along [100]. Intra­molecular N—H⋯Cl hydrogen bonds are also observed. International Union of Crystallography 2012-04-13 /pmc/articles/PMC3344311/ /pubmed/22590077 http://dx.doi.org/10.1107/S160053681201402X Text en © Wei and Xu 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wei, Wei
Xu, Yanhui
(μ-4-Bromo-3,5-dimethyl­pyrazolato-κ(2) N (1):N (2))-μ-chlorido-bis­[bis(4-bromo-3,5-dimethyl­pyrazole-κN (2))chloridocopper(II)] acetonitrile monosolvate
title (μ-4-Bromo-3,5-dimethyl­pyrazolato-κ(2) N (1):N (2))-μ-chlorido-bis­[bis(4-bromo-3,5-dimethyl­pyrazole-κN (2))chloridocopper(II)] acetonitrile monosolvate
title_full (μ-4-Bromo-3,5-dimethyl­pyrazolato-κ(2) N (1):N (2))-μ-chlorido-bis­[bis(4-bromo-3,5-dimethyl­pyrazole-κN (2))chloridocopper(II)] acetonitrile monosolvate
title_fullStr (μ-4-Bromo-3,5-dimethyl­pyrazolato-κ(2) N (1):N (2))-μ-chlorido-bis­[bis(4-bromo-3,5-dimethyl­pyrazole-κN (2))chloridocopper(II)] acetonitrile monosolvate
title_full_unstemmed (μ-4-Bromo-3,5-dimethyl­pyrazolato-κ(2) N (1):N (2))-μ-chlorido-bis­[bis(4-bromo-3,5-dimethyl­pyrazole-κN (2))chloridocopper(II)] acetonitrile monosolvate
title_short (μ-4-Bromo-3,5-dimethyl­pyrazolato-κ(2) N (1):N (2))-μ-chlorido-bis­[bis(4-bromo-3,5-dimethyl­pyrazole-κN (2))chloridocopper(II)] acetonitrile monosolvate
title_sort (μ-4-bromo-3,5-dimethyl­pyrazolato-κ(2) n (1):n (2))-μ-chlorido-bis­[bis(4-bromo-3,5-dimethyl­pyrazole-κn (2))chloridocopper(ii)] acetonitrile monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344311/
https://www.ncbi.nlm.nih.gov/pubmed/22590077
http://dx.doi.org/10.1107/S160053681201402X
work_keys_str_mv AT weiwei m4bromo35dimethylpyrazolatok2n1n2mchloridobisbis4bromo35dimethylpyrazolekn2chloridocopperiiacetonitrilemonosolvate
AT xuyanhui m4bromo35dimethylpyrazolatok2n1n2mchloridobisbis4bromo35dimethylpyrazolekn2chloridocopperiiacetonitrilemonosolvate

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