Cargando…
Aqua[1-(1,10-phenanthrolin-2-yl-κ(2) N,N′)-1H-pyrazol-3-amine-κN (2)](sulfato-κO)copper(II) methanol monosolvate dihydrate
In the title compound, [Cu(SO(4))(C(15)H(11)N(5))(H(2)O)]·CH(3)OH·2H(2)O, the Cu(II) ion is in a distorted square-pyramidal geometry, in which three N atoms from the chelating 1-(1,10-phenanthrolin-2-yl)-1H-pyrazol-3-amine ligand and one O atom from a sulfate anion define the basal plane and the O a...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344312/ https://www.ncbi.nlm.nih.gov/pubmed/22590078 http://dx.doi.org/10.1107/S1600536812014134 |
_version_ | 1782231964007268352 |
---|---|
author | Yuan, Liang Lian, Liu Shu Hui, Chi Yan Xia, Zhao Yan Min, Shi Jing |
author_facet | Yuan, Liang Lian, Liu Shu Hui, Chi Yan Xia, Zhao Yan Min, Shi Jing |
author_sort | Yuan, Liang |
collection | PubMed |
description | In the title compound, [Cu(SO(4))(C(15)H(11)N(5))(H(2)O)]·CH(3)OH·2H(2)O, the Cu(II) ion is in a distorted square-pyramidal geometry, in which three N atoms from the chelating 1-(1,10-phenanthrolin-2-yl)-1H-pyrazol-3-amine ligand and one O atom from a sulfate anion define the basal plane and the O atom from the coordinating water molecule is located at the apex. In the crystal, hydrogen-bonding interactions involving the coordinating and solvent water molecules, the methanol solvent molecule and the amine group (one with an intramolecular interaction to one of the sulfate O atoms) of the complex are observed. π–π interactions between symmetry-related phenantroline moieties, with a shortest centroid–centroid interaction of 3.573 (2)°, are also present. |
format | Online Article Text |
id | pubmed-3344312 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33443122012-05-15 Aqua[1-(1,10-phenanthrolin-2-yl-κ(2) N,N′)-1H-pyrazol-3-amine-κN (2)](sulfato-κO)copper(II) methanol monosolvate dihydrate Yuan, Liang Lian, Liu Shu Hui, Chi Yan Xia, Zhao Yan Min, Shi Jing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(SO(4))(C(15)H(11)N(5))(H(2)O)]·CH(3)OH·2H(2)O, the Cu(II) ion is in a distorted square-pyramidal geometry, in which three N atoms from the chelating 1-(1,10-phenanthrolin-2-yl)-1H-pyrazol-3-amine ligand and one O atom from a sulfate anion define the basal plane and the O atom from the coordinating water molecule is located at the apex. In the crystal, hydrogen-bonding interactions involving the coordinating and solvent water molecules, the methanol solvent molecule and the amine group (one with an intramolecular interaction to one of the sulfate O atoms) of the complex are observed. π–π interactions between symmetry-related phenantroline moieties, with a shortest centroid–centroid interaction of 3.573 (2)°, are also present. International Union of Crystallography 2012-04-13 /pmc/articles/PMC3344312/ /pubmed/22590078 http://dx.doi.org/10.1107/S1600536812014134 Text en © Yuan et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Yuan, Liang Lian, Liu Shu Hui, Chi Yan Xia, Zhao Yan Min, Shi Jing Aqua[1-(1,10-phenanthrolin-2-yl-κ(2) N,N′)-1H-pyrazol-3-amine-κN (2)](sulfato-κO)copper(II) methanol monosolvate dihydrate |
title | Aqua[1-(1,10-phenanthrolin-2-yl-κ(2)
N,N′)-1H-pyrazol-3-amine-κN
(2)](sulfato-κO)copper(II) methanol monosolvate dihydrate |
title_full | Aqua[1-(1,10-phenanthrolin-2-yl-κ(2)
N,N′)-1H-pyrazol-3-amine-κN
(2)](sulfato-κO)copper(II) methanol monosolvate dihydrate |
title_fullStr | Aqua[1-(1,10-phenanthrolin-2-yl-κ(2)
N,N′)-1H-pyrazol-3-amine-κN
(2)](sulfato-κO)copper(II) methanol monosolvate dihydrate |
title_full_unstemmed | Aqua[1-(1,10-phenanthrolin-2-yl-κ(2)
N,N′)-1H-pyrazol-3-amine-κN
(2)](sulfato-κO)copper(II) methanol monosolvate dihydrate |
title_short | Aqua[1-(1,10-phenanthrolin-2-yl-κ(2)
N,N′)-1H-pyrazol-3-amine-κN
(2)](sulfato-κO)copper(II) methanol monosolvate dihydrate |
title_sort | aqua[1-(1,10-phenanthrolin-2-yl-κ(2)
n,n′)-1h-pyrazol-3-amine-κn
(2)](sulfato-κo)copper(ii) methanol monosolvate dihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344312/ https://www.ncbi.nlm.nih.gov/pubmed/22590078 http://dx.doi.org/10.1107/S1600536812014134 |
work_keys_str_mv | AT yuanliang aqua1110phenanthrolin2ylk2nn1hpyrazol3aminekn2sulfatokocopperiimethanolmonosolvatedihydrate AT lianliushu aqua1110phenanthrolin2ylk2nn1hpyrazol3aminekn2sulfatokocopperiimethanolmonosolvatedihydrate AT huichiyan aqua1110phenanthrolin2ylk2nn1hpyrazol3aminekn2sulfatokocopperiimethanolmonosolvatedihydrate AT xiazhaoyan aqua1110phenanthrolin2ylk2nn1hpyrazol3aminekn2sulfatokocopperiimethanolmonosolvatedihydrate AT minshijing aqua1110phenanthrolin2ylk2nn1hpyrazol3aminekn2sulfatokocopperiimethanolmonosolvatedihydrate |