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Aqua­[1-(1,10-phenanthrolin-2-yl-κ(2) N,N′)-1H-pyrazol-3-amine-κN (2)](sulfato-κO)copper(II) methanol monosolvate dihydrate

In the title compound, [Cu(SO(4))(C(15)H(11)N(5))(H(2)O)]·CH(3)OH·2H(2)O, the Cu(II) ion is in a distorted square-pyramidal geometry, in which three N atoms from the chelating 1-(1,10-phenanthrolin-2-yl)-1H-pyrazol-3-amine ligand and one O atom from a sulfate anion define the basal plane and the O a...

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Detalles Bibliográficos
Autores principales: Yuan, Liang, Lian, Liu Shu, Hui, Chi Yan, Xia, Zhao Yan, Min, Shi Jing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344312/
https://www.ncbi.nlm.nih.gov/pubmed/22590078
http://dx.doi.org/10.1107/S1600536812014134
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author Yuan, Liang
Lian, Liu Shu
Hui, Chi Yan
Xia, Zhao Yan
Min, Shi Jing
author_facet Yuan, Liang
Lian, Liu Shu
Hui, Chi Yan
Xia, Zhao Yan
Min, Shi Jing
author_sort Yuan, Liang
collection PubMed
description In the title compound, [Cu(SO(4))(C(15)H(11)N(5))(H(2)O)]·CH(3)OH·2H(2)O, the Cu(II) ion is in a distorted square-pyramidal geometry, in which three N atoms from the chelating 1-(1,10-phenanthrolin-2-yl)-1H-pyrazol-3-amine ligand and one O atom from a sulfate anion define the basal plane and the O atom from the coordinating water mol­ecule is located at the apex. In the crystal, hydrogen-bonding inter­actions involving the coordinating and solvent water mol­ecules, the methanol solvent mol­ecule and the amine group (one with an intra­molecular inter­action to one of the sulfate O atoms) of the complex are observed. π–π inter­actions between symmetry-related phenantroline moieties, with a shortest centroid–centroid inter­action of 3.573 (2)°, are also present.
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spelling pubmed-33443122012-05-15 Aqua­[1-(1,10-phenanthrolin-2-yl-κ(2) N,N′)-1H-pyrazol-3-amine-κN (2)](sulfato-κO)copper(II) methanol monosolvate dihydrate Yuan, Liang Lian, Liu Shu Hui, Chi Yan Xia, Zhao Yan Min, Shi Jing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(SO(4))(C(15)H(11)N(5))(H(2)O)]·CH(3)OH·2H(2)O, the Cu(II) ion is in a distorted square-pyramidal geometry, in which three N atoms from the chelating 1-(1,10-phenanthrolin-2-yl)-1H-pyrazol-3-amine ligand and one O atom from a sulfate anion define the basal plane and the O atom from the coordinating water mol­ecule is located at the apex. In the crystal, hydrogen-bonding inter­actions involving the coordinating and solvent water mol­ecules, the methanol solvent mol­ecule and the amine group (one with an intra­molecular inter­action to one of the sulfate O atoms) of the complex are observed. π–π inter­actions between symmetry-related phenantroline moieties, with a shortest centroid–centroid inter­action of 3.573 (2)°, are also present. International Union of Crystallography 2012-04-13 /pmc/articles/PMC3344312/ /pubmed/22590078 http://dx.doi.org/10.1107/S1600536812014134 Text en © Yuan et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yuan, Liang
Lian, Liu Shu
Hui, Chi Yan
Xia, Zhao Yan
Min, Shi Jing
Aqua­[1-(1,10-phenanthrolin-2-yl-κ(2) N,N′)-1H-pyrazol-3-amine-κN (2)](sulfato-κO)copper(II) methanol monosolvate dihydrate
title Aqua­[1-(1,10-phenanthrolin-2-yl-κ(2) N,N′)-1H-pyrazol-3-amine-κN (2)](sulfato-κO)copper(II) methanol monosolvate dihydrate
title_full Aqua­[1-(1,10-phenanthrolin-2-yl-κ(2) N,N′)-1H-pyrazol-3-amine-κN (2)](sulfato-κO)copper(II) methanol monosolvate dihydrate
title_fullStr Aqua­[1-(1,10-phenanthrolin-2-yl-κ(2) N,N′)-1H-pyrazol-3-amine-κN (2)](sulfato-κO)copper(II) methanol monosolvate dihydrate
title_full_unstemmed Aqua­[1-(1,10-phenanthrolin-2-yl-κ(2) N,N′)-1H-pyrazol-3-amine-κN (2)](sulfato-κO)copper(II) methanol monosolvate dihydrate
title_short Aqua­[1-(1,10-phenanthrolin-2-yl-κ(2) N,N′)-1H-pyrazol-3-amine-κN (2)](sulfato-κO)copper(II) methanol monosolvate dihydrate
title_sort aqua­[1-(1,10-phenanthrolin-2-yl-κ(2) n,n′)-1h-pyrazol-3-amine-κn (2)](sulfato-κo)copper(ii) methanol monosolvate dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344312/
https://www.ncbi.nlm.nih.gov/pubmed/22590078
http://dx.doi.org/10.1107/S1600536812014134
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