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[1,1′-Bis(diphenyl­phosphan­yl)ferrocene-κ(2) P,P′](η(5)-cyclo­penta­dien­yl)(dicyanamido-κN)ruthenium(II) dichloro­methane monosolvate

The title compound, [FeRu(C(5)H(5))(C(2)N(3))(C(17)H(14)P)(2)], was obtained by reaction of Cp(dppf)RuCl [dppf = 1,1′-bis­(diphenyl­phosphan­yl)ferrocene] with sodium dicyanamide in dichloro­methane. The Ru(II) atom is capped by an η(5)-cyclo­penta­dienyl (Cp) ring, a chelating dppf and a terminal C...

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Autor principal: Gao, Libin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344313/
https://www.ncbi.nlm.nih.gov/pubmed/22590079
http://dx.doi.org/10.1107/S1600536812014274
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author Gao, Libin
author_facet Gao, Libin
author_sort Gao, Libin
collection PubMed
description The title compound, [FeRu(C(5)H(5))(C(2)N(3))(C(17)H(14)P)(2)], was obtained by reaction of Cp(dppf)RuCl [dppf = 1,1′-bis­(diphenyl­phosphan­yl)ferrocene] with sodium dicyanamide in dichloro­methane. The Ru(II) atom is capped by an η(5)-cyclo­penta­dienyl (Cp) ring, a chelating dppf and a terminal C(2)N(3) unit, giving three-legged piano-stool geometry. The C—N—C angle of the N(CN)(2) ligand [120.8 (6)°] is significantly smaller than that in the corresponding diruthenium complex [127.2 (9)°; Zhang et al. (2003 ▶). Inorg. Chem. 42, 633–640] due to steric hindrance between the two {Cp(PPh(3))(2)Ru} building blocks. Disorder was found in the dichloro­methane solvent mol­ecule, which was refined as disordered over two positions, with a site-occupancy ratio of 0.53:0.47 (2).
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spelling pubmed-33443132012-05-15 [1,1′-Bis(diphenyl­phosphan­yl)ferrocene-κ(2) P,P′](η(5)-cyclo­penta­dien­yl)(dicyanamido-κN)ruthenium(II) dichloro­methane monosolvate Gao, Libin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [FeRu(C(5)H(5))(C(2)N(3))(C(17)H(14)P)(2)], was obtained by reaction of Cp(dppf)RuCl [dppf = 1,1′-bis­(diphenyl­phosphan­yl)ferrocene] with sodium dicyanamide in dichloro­methane. The Ru(II) atom is capped by an η(5)-cyclo­penta­dienyl (Cp) ring, a chelating dppf and a terminal C(2)N(3) unit, giving three-legged piano-stool geometry. The C—N—C angle of the N(CN)(2) ligand [120.8 (6)°] is significantly smaller than that in the corresponding diruthenium complex [127.2 (9)°; Zhang et al. (2003 ▶). Inorg. Chem. 42, 633–640] due to steric hindrance between the two {Cp(PPh(3))(2)Ru} building blocks. Disorder was found in the dichloro­methane solvent mol­ecule, which was refined as disordered over two positions, with a site-occupancy ratio of 0.53:0.47 (2). International Union of Crystallography 2012-04-13 /pmc/articles/PMC3344313/ /pubmed/22590079 http://dx.doi.org/10.1107/S1600536812014274 Text en © Libin Gao 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gao, Libin
[1,1′-Bis(diphenyl­phosphan­yl)ferrocene-κ(2) P,P′](η(5)-cyclo­penta­dien­yl)(dicyanamido-κN)ruthenium(II) dichloro­methane monosolvate
title [1,1′-Bis(diphenyl­phosphan­yl)ferrocene-κ(2) P,P′](η(5)-cyclo­penta­dien­yl)(dicyanamido-κN)ruthenium(II) dichloro­methane monosolvate
title_full [1,1′-Bis(diphenyl­phosphan­yl)ferrocene-κ(2) P,P′](η(5)-cyclo­penta­dien­yl)(dicyanamido-κN)ruthenium(II) dichloro­methane monosolvate
title_fullStr [1,1′-Bis(diphenyl­phosphan­yl)ferrocene-κ(2) P,P′](η(5)-cyclo­penta­dien­yl)(dicyanamido-κN)ruthenium(II) dichloro­methane monosolvate
title_full_unstemmed [1,1′-Bis(diphenyl­phosphan­yl)ferrocene-κ(2) P,P′](η(5)-cyclo­penta­dien­yl)(dicyanamido-κN)ruthenium(II) dichloro­methane monosolvate
title_short [1,1′-Bis(diphenyl­phosphan­yl)ferrocene-κ(2) P,P′](η(5)-cyclo­penta­dien­yl)(dicyanamido-κN)ruthenium(II) dichloro­methane monosolvate
title_sort [1,1′-bis(diphenyl­phosphan­yl)ferrocene-κ(2) p,p′](η(5)-cyclo­penta­dien­yl)(dicyanamido-κn)ruthenium(ii) dichloro­methane monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344313/
https://www.ncbi.nlm.nih.gov/pubmed/22590079
http://dx.doi.org/10.1107/S1600536812014274
work_keys_str_mv AT gaolibin 11bisdiphenylphosphanylferrocenek2ppē5cyclopentadienyldicyanamidoknrutheniumiidichloromethanemonosolvate