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5,6-Dihydro-1,10-phenanthroline-1,10-diium μ-oxido-bis­[penta­fluoridotantalate(V)]

In the title compound, (C(12)H(12)N(2))[Ta(2)F(10)O], the doubly protonated 5,6-dihydro-1,10-phenantroline-1,10-diium cation is located on a twofold rotation axis, whereas the isolated [Ta(2)OF(10)](2−) dianion has -1 symmetry. In the so far unknown dianion, the symmetry-related Ta(V) atoms are octa...

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Detalles Bibliográficos
Autores principales: Meng, Zhao-Hui, Feng, Yu-Quan, Chen, Xin-Feng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344314/
https://www.ncbi.nlm.nih.gov/pubmed/22590080
http://dx.doi.org/10.1107/S1600536812014742
Descripción
Sumario:In the title compound, (C(12)H(12)N(2))[Ta(2)F(10)O], the doubly protonated 5,6-dihydro-1,10-phenantroline-1,10-diium cation is located on a twofold rotation axis, whereas the isolated [Ta(2)OF(10)](2−) dianion has -1 symmetry. In the so far unknown dianion, the symmetry-related Ta(V) atoms are octa­hedrally coordinated by five F atoms and a bridging O atom, the latter being located on an inversion centre. The two pyridine rings in the cation make a dihedral angle of 22.8 (4)°. The cations and dianions are arranged in layers parallel to (100) and are connected through N—H⋯F and C—H⋯F hydrogen-bonding inter­actions into a three-dimensional structure.