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Tetraaquabis[3-(pyridin-4-yl)benzoato-κN]manganese(II)
In the title compound, [Mn(C(12)H(8)NO(2))(2)(H(2)O)(4)], the Mn(2+) ion lies on a twofold rotation axis and has a distorted N(2)O(4) octahedral coordination geometry formed by four water O atoms in the equatorial plane and two apical pyridyl N atoms. A three-dimensional network is formed in the cr...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344315/ https://www.ncbi.nlm.nih.gov/pubmed/22590081 http://dx.doi.org/10.1107/S1600536812014602 |
| _version_ | 1782231964682551296 |
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| author | Gao, Ru-Qin Li, Guo-Ting |
| author_facet | Gao, Ru-Qin Li, Guo-Ting |
| author_sort | Gao, Ru-Qin |
| collection | PubMed |
| description | In the title compound, [Mn(C(12)H(8)NO(2))(2)(H(2)O)(4)], the Mn(2+) ion lies on a twofold rotation axis and has a distorted N(2)O(4) octahedral coordination geometry formed by four water O atoms in the equatorial plane and two apical pyridyl N atoms. A three-dimensional network is formed in the crystal structure by multiple O—H⋯O hydrogen bonds between the coordinating water molecules and the free carboxylate groups. |
| format | Online Article Text |
| id | pubmed-3344315 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33443152012-05-15 Tetraaquabis[3-(pyridin-4-yl)benzoato-κN]manganese(II) Gao, Ru-Qin Li, Guo-Ting Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mn(C(12)H(8)NO(2))(2)(H(2)O)(4)], the Mn(2+) ion lies on a twofold rotation axis and has a distorted N(2)O(4) octahedral coordination geometry formed by four water O atoms in the equatorial plane and two apical pyridyl N atoms. A three-dimensional network is formed in the crystal structure by multiple O—H⋯O hydrogen bonds between the coordinating water molecules and the free carboxylate groups. International Union of Crystallography 2012-04-13 /pmc/articles/PMC3344315/ /pubmed/22590081 http://dx.doi.org/10.1107/S1600536812014602 Text en © Gao and Li 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Gao, Ru-Qin Li, Guo-Ting Tetraaquabis[3-(pyridin-4-yl)benzoato-κN]manganese(II) |
| title | Tetraaquabis[3-(pyridin-4-yl)benzoato-κN]manganese(II) |
| title_full | Tetraaquabis[3-(pyridin-4-yl)benzoato-κN]manganese(II) |
| title_fullStr | Tetraaquabis[3-(pyridin-4-yl)benzoato-κN]manganese(II) |
| title_full_unstemmed | Tetraaquabis[3-(pyridin-4-yl)benzoato-κN]manganese(II) |
| title_short | Tetraaquabis[3-(pyridin-4-yl)benzoato-κN]manganese(II) |
| title_sort | tetraaquabis[3-(pyridin-4-yl)benzoato-κn]manganese(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344315/ https://www.ncbi.nlm.nih.gov/pubmed/22590081 http://dx.doi.org/10.1107/S1600536812014602 |
| work_keys_str_mv | AT gaoruqin tetraaquabis3pyridin4ylbenzoatoknmanganeseii AT liguoting tetraaquabis3pyridin4ylbenzoatoknmanganeseii |