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cis-[1,4-Bis(diphenylphosphanyl)butane-κ(2) P,P′]dichlorido(cyclohexane-1,2-diamine-κ(2) N,N′)ruthenium(II) dichloromethane monosolvate
In the title compound, [RuCl(2)(C(6)H(14)N(2))(C(28)H(28)P(2))]·CH(2)Cl(2), the Ru(II) ion is coordinated in a slightly distorted octahedral environment, formed by two cis-oriented chloride ligands, two cis P atoms of a 1,4-bis(diphenylphosphanyl)butane ligand and two cis-chelating N atoms of a...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2012
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344316/ https://www.ncbi.nlm.nih.gov/pubmed/22590082 http://dx.doi.org/10.1107/S1600536812014080 |
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author | Warad, Ismail |
author_facet | Warad, Ismail |
author_sort | Warad, Ismail |
collection | PubMed |
description | In the title compound, [RuCl(2)(C(6)H(14)N(2))(C(28)H(28)P(2))]·CH(2)Cl(2), the Ru(II) ion is coordinated in a slightly distorted octahedral environment, formed by two cis-oriented chloride ligands, two cis P atoms of a 1,4-bis(diphenylphosphanyl)butane ligand and two cis-chelating N atoms of a bidentate cyclohexane-1,2-diamine ligand. In the crystal, pairs of molecules form inversion dimers via N—H⋯Cl hydrogen bonds. In addition, intramolecular N—H⋯Cl and weak C—H⋯Cl, C—H⋯N, N—H⋯π and C—H⋯π hydrogen bonds are observed. One of the Cl atoms of the solvent molecule is disordered over two sites with refined occupancies of 0.62 (1) and 0.38 (1). |
format | Online Article Text |
id | pubmed-3344316 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33443162012-05-15 cis-[1,4-Bis(diphenylphosphanyl)butane-κ(2) P,P′]dichlorido(cyclohexane-1,2-diamine-κ(2) N,N′)ruthenium(II) dichloromethane monosolvate Warad, Ismail Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [RuCl(2)(C(6)H(14)N(2))(C(28)H(28)P(2))]·CH(2)Cl(2), the Ru(II) ion is coordinated in a slightly distorted octahedral environment, formed by two cis-oriented chloride ligands, two cis P atoms of a 1,4-bis(diphenylphosphanyl)butane ligand and two cis-chelating N atoms of a bidentate cyclohexane-1,2-diamine ligand. In the crystal, pairs of molecules form inversion dimers via N—H⋯Cl hydrogen bonds. In addition, intramolecular N—H⋯Cl and weak C—H⋯Cl, C—H⋯N, N—H⋯π and C—H⋯π hydrogen bonds are observed. One of the Cl atoms of the solvent molecule is disordered over two sites with refined occupancies of 0.62 (1) and 0.38 (1). International Union of Crystallography 2012-04-13 /pmc/articles/PMC3344316/ /pubmed/22590082 http://dx.doi.org/10.1107/S1600536812014080 Text en © Ismail Warad 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Warad, Ismail cis-[1,4-Bis(diphenylphosphanyl)butane-κ(2) P,P′]dichlorido(cyclohexane-1,2-diamine-κ(2) N,N′)ruthenium(II) dichloromethane monosolvate |
title |
cis-[1,4-Bis(diphenylphosphanyl)butane-κ(2)
P,P′]dichlorido(cyclohexane-1,2-diamine-κ(2)
N,N′)ruthenium(II) dichloromethane monosolvate |
title_full |
cis-[1,4-Bis(diphenylphosphanyl)butane-κ(2)
P,P′]dichlorido(cyclohexane-1,2-diamine-κ(2)
N,N′)ruthenium(II) dichloromethane monosolvate |
title_fullStr |
cis-[1,4-Bis(diphenylphosphanyl)butane-κ(2)
P,P′]dichlorido(cyclohexane-1,2-diamine-κ(2)
N,N′)ruthenium(II) dichloromethane monosolvate |
title_full_unstemmed |
cis-[1,4-Bis(diphenylphosphanyl)butane-κ(2)
P,P′]dichlorido(cyclohexane-1,2-diamine-κ(2)
N,N′)ruthenium(II) dichloromethane monosolvate |
title_short |
cis-[1,4-Bis(diphenylphosphanyl)butane-κ(2)
P,P′]dichlorido(cyclohexane-1,2-diamine-κ(2)
N,N′)ruthenium(II) dichloromethane monosolvate |
title_sort | cis-[1,4-bis(diphenylphosphanyl)butane-κ(2)
p,p′]dichlorido(cyclohexane-1,2-diamine-κ(2)
n,n′)ruthenium(ii) dichloromethane monosolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344316/ https://www.ncbi.nlm.nih.gov/pubmed/22590082 http://dx.doi.org/10.1107/S1600536812014080 |
work_keys_str_mv | AT waradismail cis14bisdiphenylphosphanylbutanek2ppdichloridocyclohexane12diaminek2nnrutheniumiidichloromethanemonosolvate |