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cis-[1,4-Bis(diphenyl­phosphan­yl)butane-κ(2) P,P′]dichlorido(cyclo­hexane-1,2-diamine-κ(2) N,N′)ruthenium(II) dichloro­methane monosolvate

In the title compound, [RuCl(2)(C(6)H(14)N(2))(C(28)H(28)P(2))]·CH(2)Cl(2), the Ru(II) ion is coordinated in a slightly distorted octa­hedral environment, formed by two cis-oriented chloride ligands, two cis P atoms of a 1,4-bis­(diphenyl­phosphan­yl)butane ligand and two cis-chelating N atoms of a...

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Autor principal: Warad, Ismail
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344316/
https://www.ncbi.nlm.nih.gov/pubmed/22590082
http://dx.doi.org/10.1107/S1600536812014080
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author Warad, Ismail
author_facet Warad, Ismail
author_sort Warad, Ismail
collection PubMed
description In the title compound, [RuCl(2)(C(6)H(14)N(2))(C(28)H(28)P(2))]·CH(2)Cl(2), the Ru(II) ion is coordinated in a slightly distorted octa­hedral environment, formed by two cis-oriented chloride ligands, two cis P atoms of a 1,4-bis­(diphenyl­phosphan­yl)butane ligand and two cis-chelating N atoms of a bidentate cyclo­hexane-1,2-diamine ligand. In the crystal, pairs of mol­ecules form inversion dimers via N—H⋯Cl hydrogen bonds. In addition, intra­molecular N—H⋯Cl and weak C—H⋯Cl, C—H⋯N, N—H⋯π and C—H⋯π hydrogen bonds are observed. One of the Cl atoms of the solvent mol­ecule is disordered over two sites with refined occupancies of 0.62 (1) and 0.38 (1).
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spelling pubmed-33443162012-05-15 cis-[1,4-Bis(diphenyl­phosphan­yl)butane-κ(2) P,P′]dichlorido(cyclo­hexane-1,2-diamine-κ(2) N,N′)ruthenium(II) dichloro­methane monosolvate Warad, Ismail Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [RuCl(2)(C(6)H(14)N(2))(C(28)H(28)P(2))]·CH(2)Cl(2), the Ru(II) ion is coordinated in a slightly distorted octa­hedral environment, formed by two cis-oriented chloride ligands, two cis P atoms of a 1,4-bis­(diphenyl­phosphan­yl)butane ligand and two cis-chelating N atoms of a bidentate cyclo­hexane-1,2-diamine ligand. In the crystal, pairs of mol­ecules form inversion dimers via N—H⋯Cl hydrogen bonds. In addition, intra­molecular N—H⋯Cl and weak C—H⋯Cl, C—H⋯N, N—H⋯π and C—H⋯π hydrogen bonds are observed. One of the Cl atoms of the solvent mol­ecule is disordered over two sites with refined occupancies of 0.62 (1) and 0.38 (1). International Union of Crystallography 2012-04-13 /pmc/articles/PMC3344316/ /pubmed/22590082 http://dx.doi.org/10.1107/S1600536812014080 Text en © Ismail Warad 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Warad, Ismail
cis-[1,4-Bis(diphenyl­phosphan­yl)butane-κ(2) P,P′]dichlorido(cyclo­hexane-1,2-diamine-κ(2) N,N′)ruthenium(II) dichloro­methane monosolvate
title cis-[1,4-Bis(diphenyl­phosphan­yl)butane-κ(2) P,P′]dichlorido(cyclo­hexane-1,2-diamine-κ(2) N,N′)ruthenium(II) dichloro­methane monosolvate
title_full cis-[1,4-Bis(diphenyl­phosphan­yl)butane-κ(2) P,P′]dichlorido(cyclo­hexane-1,2-diamine-κ(2) N,N′)ruthenium(II) dichloro­methane monosolvate
title_fullStr cis-[1,4-Bis(diphenyl­phosphan­yl)butane-κ(2) P,P′]dichlorido(cyclo­hexane-1,2-diamine-κ(2) N,N′)ruthenium(II) dichloro­methane monosolvate
title_full_unstemmed cis-[1,4-Bis(diphenyl­phosphan­yl)butane-κ(2) P,P′]dichlorido(cyclo­hexane-1,2-diamine-κ(2) N,N′)ruthenium(II) dichloro­methane monosolvate
title_short cis-[1,4-Bis(diphenyl­phosphan­yl)butane-κ(2) P,P′]dichlorido(cyclo­hexane-1,2-diamine-κ(2) N,N′)ruthenium(II) dichloro­methane monosolvate
title_sort cis-[1,4-bis(diphenyl­phosphan­yl)butane-κ(2) p,p′]dichlorido(cyclo­hexane-1,2-diamine-κ(2) n,n′)ruthenium(ii) dichloro­methane monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344316/
https://www.ncbi.nlm.nih.gov/pubmed/22590082
http://dx.doi.org/10.1107/S1600536812014080
work_keys_str_mv AT waradismail cis14bisdiphenylphosphanylbutanek2ppdichloridocyclohexane12diaminek2nnrutheniumiidichloromethanemonosolvate