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catena-Poly[copper(I)-di-μ-bromido-copper(I)-bis[μ-4-methyl-1H-1,2,4-triazole-5(4H)-thione-κ(2) S:S]]
In the title coordination polymer, [CuBr(C(3)H(5)N(3)S)](n), the Cu(I) atom adopts a tetrahdral CuS(2)Br(2) coordination geometry arising from two S-bonded 4-methyl-1H-1,2,4-triazole-3(4H)-thione ligands and two bromide ions. Both the S and Br atoms act as bridging ligands, connecting pairs of Cu(I...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344317/ https://www.ncbi.nlm.nih.gov/pubmed/22590083 http://dx.doi.org/10.1107/S1600536812014444 |
| Sumario: | In the title coordination polymer, [CuBr(C(3)H(5)N(3)S)](n), the Cu(I) atom adopts a tetrahdral CuS(2)Br(2) coordination geometry arising from two S-bonded 4-methyl-1H-1,2,4-triazole-3(4H)-thione ligands and two bromide ions. Both the S and Br atoms act as bridging ligands, connecting pairs of Cu(I) atoms and generating chains propagating in [100]. Inter-chain N—H⋯N hydrogen bonds generate layers in the ac plane. Weak intra-chain N—H⋯Br interactions also occur. |
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