catena-Poly[copper(I)-di-μ-bromido-copper(I)-bis­[μ-4-methyl-1H-1,2,4-triazole-5(4H)-thione-κ(2) S:S]]

In the title coordination polymer, [CuBr(C(3)H(5)N(3)S)](n), the Cu(I) atom adopts a tetra­hdral CuS(2)Br(2) coordination geometry arising from two S-bonded 4-methyl-1H-1,2,4-triazole-3(4H)-thione ligands and two bromide ions. Both the S and Br atoms act as bridging ligands, connecting pairs of Cu(I...

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Detalles Bibliográficos
Autores principales: Saithong, Saowanit, Charmant, Jonathan, Pakawatchai, Chaveng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344317/
https://www.ncbi.nlm.nih.gov/pubmed/22590083
http://dx.doi.org/10.1107/S1600536812014444
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author Saithong, Saowanit
Charmant, Jonathan
Pakawatchai, Chaveng
author_facet Saithong, Saowanit
Charmant, Jonathan
Pakawatchai, Chaveng
author_sort Saithong, Saowanit
collection PubMed
description In the title coordination polymer, [CuBr(C(3)H(5)N(3)S)](n), the Cu(I) atom adopts a tetra­hdral CuS(2)Br(2) coordination geometry arising from two S-bonded 4-methyl-1H-1,2,4-triazole-3(4H)-thione ligands and two bromide ions. Both the S and Br atoms act as bridging ligands, connecting pairs of Cu(I) atoms and generating chains propagating in [100]. Inter-chain N—H⋯N hydrogen bonds generate layers in the ac plane. Weak intra-chain N—H⋯Br inter­actions also occur.
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spelling pubmed-33443172012-05-15 catena-Poly[copper(I)-di-μ-bromido-copper(I)-bis­[μ-4-methyl-1H-1,2,4-triazole-5(4H)-thione-κ(2) S:S]] Saithong, Saowanit Charmant, Jonathan Pakawatchai, Chaveng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, [CuBr(C(3)H(5)N(3)S)](n), the Cu(I) atom adopts a tetra­hdral CuS(2)Br(2) coordination geometry arising from two S-bonded 4-methyl-1H-1,2,4-triazole-3(4H)-thione ligands and two bromide ions. Both the S and Br atoms act as bridging ligands, connecting pairs of Cu(I) atoms and generating chains propagating in [100]. Inter-chain N—H⋯N hydrogen bonds generate layers in the ac plane. Weak intra-chain N—H⋯Br inter­actions also occur. International Union of Crystallography 2012-04-13 /pmc/articles/PMC3344317/ /pubmed/22590083 http://dx.doi.org/10.1107/S1600536812014444 Text en © Saithong et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Saithong, Saowanit
Charmant, Jonathan
Pakawatchai, Chaveng
catena-Poly[copper(I)-di-μ-bromido-copper(I)-bis­[μ-4-methyl-1H-1,2,4-triazole-5(4H)-thione-κ(2) S:S]]
title catena-Poly[copper(I)-di-μ-bromido-copper(I)-bis­[μ-4-methyl-1H-1,2,4-triazole-5(4H)-thione-κ(2) S:S]]
title_full catena-Poly[copper(I)-di-μ-bromido-copper(I)-bis­[μ-4-methyl-1H-1,2,4-triazole-5(4H)-thione-κ(2) S:S]]
title_fullStr catena-Poly[copper(I)-di-μ-bromido-copper(I)-bis­[μ-4-methyl-1H-1,2,4-triazole-5(4H)-thione-κ(2) S:S]]
title_full_unstemmed catena-Poly[copper(I)-di-μ-bromido-copper(I)-bis­[μ-4-methyl-1H-1,2,4-triazole-5(4H)-thione-κ(2) S:S]]
title_short catena-Poly[copper(I)-di-μ-bromido-copper(I)-bis­[μ-4-methyl-1H-1,2,4-triazole-5(4H)-thione-κ(2) S:S]]
title_sort catena-poly[copper(i)-di-μ-bromido-copper(i)-bis­[μ-4-methyl-1h-1,2,4-triazole-5(4h)-thione-κ(2) s:s]]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344317/
https://www.ncbi.nlm.nih.gov/pubmed/22590083
http://dx.doi.org/10.1107/S1600536812014444
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