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trans-Bis(acetato-κO)bis(2-aminoethanol-κ(2) N,O)nickel(II)
In the title compound, [Ni(CH(3)CO(2))(2)(C(2)H(7)NO)(2)], the Ni(II) cation, located on an inversion center, is N,O-chelated by two 2-aminoethanol molecules and further coordinated by two monodendate acetate anions in a slightly distorted octahedral geometry. The latter is stabilized by intramo...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344318/ https://www.ncbi.nlm.nih.gov/pubmed/22590084 http://dx.doi.org/10.1107/S1600536812014237 |
Sumario: | In the title compound, [Ni(CH(3)CO(2))(2)(C(2)H(7)NO)(2)], the Ni(II) cation, located on an inversion center, is N,O-chelated by two 2-aminoethanol molecules and further coordinated by two monodendate acetate anions in a slightly distorted octahedral geometry. The latter is stabilized by intramolecular O—H⋯O hydrogen bonds involving the non-coordinated O atom of the acetate and the H atom of the hydroxy group of the 2-aminoethanol ligand. In the crystal, N—H⋯O hydrogen bonds link the molecules into a three-dimensional supramolecular framework that involves (a) the coordinated acetate O atom and one of the H atoms of the amino group and (b) the non-coordinated acetate O atom and the other H atom of the amino group. |
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