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trans-Bis(acetato-κO)bis­(2-amino­ethanol-κ(2) N,O)nickel(II)

In the title compound, [Ni(CH(3)CO(2))(2)(C(2)H(7)NO)(2)], the Ni(II) cation, located on an inversion center, is N,O-chelated by two 2-amino­ethanol mol­ecules and further coordinated by two monodendate acetate anions in a slightly distorted octa­hedral geometry. The latter is stabilized by intra­mo...

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Autores principales: Seifollahi Bazarjani, Mahdi, Foro, Sabine, Donner, Wolfgang, Gurlo, Aleksander, Riedel, Ralf
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344318/
https://www.ncbi.nlm.nih.gov/pubmed/22590084
http://dx.doi.org/10.1107/S1600536812014237
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author Seifollahi Bazarjani, Mahdi
Foro, Sabine
Donner, Wolfgang
Gurlo, Aleksander
Riedel, Ralf
author_facet Seifollahi Bazarjani, Mahdi
Foro, Sabine
Donner, Wolfgang
Gurlo, Aleksander
Riedel, Ralf
author_sort Seifollahi Bazarjani, Mahdi
collection PubMed
description In the title compound, [Ni(CH(3)CO(2))(2)(C(2)H(7)NO)(2)], the Ni(II) cation, located on an inversion center, is N,O-chelated by two 2-amino­ethanol mol­ecules and further coordinated by two monodendate acetate anions in a slightly distorted octa­hedral geometry. The latter is stabilized by intra­molecular O—H⋯O hydrogen bonds involving the non-coordinated O atom of the acetate and the H atom of the hy­droxy group of the 2-amino­ethanol ligand. In the crystal, N—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional supra­molecular framework that involves (a) the coordinated acetate O atom and one of the H atoms of the amino group and (b) the non-coordinated acetate O atom and the other H atom of the amino group.
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spelling pubmed-33443182012-05-15 trans-Bis(acetato-κO)bis­(2-amino­ethanol-κ(2) N,O)nickel(II) Seifollahi Bazarjani, Mahdi Foro, Sabine Donner, Wolfgang Gurlo, Aleksander Riedel, Ralf Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(CH(3)CO(2))(2)(C(2)H(7)NO)(2)], the Ni(II) cation, located on an inversion center, is N,O-chelated by two 2-amino­ethanol mol­ecules and further coordinated by two monodendate acetate anions in a slightly distorted octa­hedral geometry. The latter is stabilized by intra­molecular O—H⋯O hydrogen bonds involving the non-coordinated O atom of the acetate and the H atom of the hy­droxy group of the 2-amino­ethanol ligand. In the crystal, N—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional supra­molecular framework that involves (a) the coordinated acetate O atom and one of the H atoms of the amino group and (b) the non-coordinated acetate O atom and the other H atom of the amino group. International Union of Crystallography 2012-04-13 /pmc/articles/PMC3344318/ /pubmed/22590084 http://dx.doi.org/10.1107/S1600536812014237 Text en © Seifollahi Bazarjani et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Seifollahi Bazarjani, Mahdi
Foro, Sabine
Donner, Wolfgang
Gurlo, Aleksander
Riedel, Ralf
trans-Bis(acetato-κO)bis­(2-amino­ethanol-κ(2) N,O)nickel(II)
title trans-Bis(acetato-κO)bis­(2-amino­ethanol-κ(2) N,O)nickel(II)
title_full trans-Bis(acetato-κO)bis­(2-amino­ethanol-κ(2) N,O)nickel(II)
title_fullStr trans-Bis(acetato-κO)bis­(2-amino­ethanol-κ(2) N,O)nickel(II)
title_full_unstemmed trans-Bis(acetato-κO)bis­(2-amino­ethanol-κ(2) N,O)nickel(II)
title_short trans-Bis(acetato-κO)bis­(2-amino­ethanol-κ(2) N,O)nickel(II)
title_sort trans-bis(acetato-κo)bis­(2-amino­ethanol-κ(2) n,o)nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344318/
https://www.ncbi.nlm.nih.gov/pubmed/22590084
http://dx.doi.org/10.1107/S1600536812014237
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