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trans-Bis(acetato-κO)bis(2-aminoethanol-κ(2) N,O)nickel(II)
In the title compound, [Ni(CH(3)CO(2))(2)(C(2)H(7)NO)(2)], the Ni(II) cation, located on an inversion center, is N,O-chelated by two 2-aminoethanol molecules and further coordinated by two monodendate acetate anions in a slightly distorted octahedral geometry. The latter is stabilized by intramo...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344318/ https://www.ncbi.nlm.nih.gov/pubmed/22590084 http://dx.doi.org/10.1107/S1600536812014237 |
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author | Seifollahi Bazarjani, Mahdi Foro, Sabine Donner, Wolfgang Gurlo, Aleksander Riedel, Ralf |
author_facet | Seifollahi Bazarjani, Mahdi Foro, Sabine Donner, Wolfgang Gurlo, Aleksander Riedel, Ralf |
author_sort | Seifollahi Bazarjani, Mahdi |
collection | PubMed |
description | In the title compound, [Ni(CH(3)CO(2))(2)(C(2)H(7)NO)(2)], the Ni(II) cation, located on an inversion center, is N,O-chelated by two 2-aminoethanol molecules and further coordinated by two monodendate acetate anions in a slightly distorted octahedral geometry. The latter is stabilized by intramolecular O—H⋯O hydrogen bonds involving the non-coordinated O atom of the acetate and the H atom of the hydroxy group of the 2-aminoethanol ligand. In the crystal, N—H⋯O hydrogen bonds link the molecules into a three-dimensional supramolecular framework that involves (a) the coordinated acetate O atom and one of the H atoms of the amino group and (b) the non-coordinated acetate O atom and the other H atom of the amino group. |
format | Online Article Text |
id | pubmed-3344318 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33443182012-05-15 trans-Bis(acetato-κO)bis(2-aminoethanol-κ(2) N,O)nickel(II) Seifollahi Bazarjani, Mahdi Foro, Sabine Donner, Wolfgang Gurlo, Aleksander Riedel, Ralf Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(CH(3)CO(2))(2)(C(2)H(7)NO)(2)], the Ni(II) cation, located on an inversion center, is N,O-chelated by two 2-aminoethanol molecules and further coordinated by two monodendate acetate anions in a slightly distorted octahedral geometry. The latter is stabilized by intramolecular O—H⋯O hydrogen bonds involving the non-coordinated O atom of the acetate and the H atom of the hydroxy group of the 2-aminoethanol ligand. In the crystal, N—H⋯O hydrogen bonds link the molecules into a three-dimensional supramolecular framework that involves (a) the coordinated acetate O atom and one of the H atoms of the amino group and (b) the non-coordinated acetate O atom and the other H atom of the amino group. International Union of Crystallography 2012-04-13 /pmc/articles/PMC3344318/ /pubmed/22590084 http://dx.doi.org/10.1107/S1600536812014237 Text en © Seifollahi Bazarjani et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Seifollahi Bazarjani, Mahdi Foro, Sabine Donner, Wolfgang Gurlo, Aleksander Riedel, Ralf trans-Bis(acetato-κO)bis(2-aminoethanol-κ(2) N,O)nickel(II) |
title |
trans-Bis(acetato-κO)bis(2-aminoethanol-κ(2)
N,O)nickel(II) |
title_full |
trans-Bis(acetato-κO)bis(2-aminoethanol-κ(2)
N,O)nickel(II) |
title_fullStr |
trans-Bis(acetato-κO)bis(2-aminoethanol-κ(2)
N,O)nickel(II) |
title_full_unstemmed |
trans-Bis(acetato-κO)bis(2-aminoethanol-κ(2)
N,O)nickel(II) |
title_short |
trans-Bis(acetato-κO)bis(2-aminoethanol-κ(2)
N,O)nickel(II) |
title_sort | trans-bis(acetato-κo)bis(2-aminoethanol-κ(2)
n,o)nickel(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344318/ https://www.ncbi.nlm.nih.gov/pubmed/22590084 http://dx.doi.org/10.1107/S1600536812014237 |
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