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Bis(2,2′-bipyridyl-κ(2) N,N′)bis(dicyanamido-κN)manganese(II)
In title complex, [Mn(C(2)N(3))(2)(C(10)H(8)N(2))(2)], the Mn(II) ion is coordinated in a slightly distorted octahedral geometry by six N atoms. Four of the N atoms are from two chelating bipyridine ligands and two are from a pair of cis-coordinated dicyanamide ligands. The dihedral angle formed by...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344319/ https://www.ncbi.nlm.nih.gov/pubmed/22590085 http://dx.doi.org/10.1107/S1600536812014183 |
| Sumario: | In title complex, [Mn(C(2)N(3))(2)(C(10)H(8)N(2))(2)], the Mn(II) ion is coordinated in a slightly distorted octahedral geometry by six N atoms. Four of the N atoms are from two chelating bipyridine ligands and two are from a pair of cis-coordinated dicyanamide ligands. The dihedral angle formed by the mean planes of the bipyridine rings is 85.93 (14)°. The central N atom of one of the dicyanamide ligands was refined as disordered over two sites with equal occupancies. |
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