Tetra­kis[μ(3)-4-nitro-N-(5-phenyl-1,3,4-oxadiazol-2-yl)benzamidato]tetra­kis­[methano­lsodium(I)]

In the title compound, [Na(4)(C(15)H(9)N(4)O(4))(4)(CH(3)OH)(4)], the N(3)O(3) environment around the Na(+) ion is distorted octa­hedral. In the unit cell, four Na(+) ions are bridged by four Schiff base anions, leading to a tetra­nuclear complex with -4 symmetry. O—H⋯N hydrogen bonds between the me...

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Detalles Bibliográficos
Autores principales: Yin, Guo-Jie, Zhang, Qing, Li, Dong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344320/
https://www.ncbi.nlm.nih.gov/pubmed/22590086
http://dx.doi.org/10.1107/S1600536812014791
Descripción
Sumario:In the title compound, [Na(4)(C(15)H(9)N(4)O(4))(4)(CH(3)OH)(4)], the N(3)O(3) environment around the Na(+) ion is distorted octa­hedral. In the unit cell, four Na(+) ions are bridged by four Schiff base anions, leading to a tetra­nuclear complex with -4 symmetry. O—H⋯N hydrogen bonds between the methanol mol­ecule and the Schiff base anion stabilize the structural set-up.

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