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Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))quinoline-κN]zinc

The Zn(II) atom in the title compound, [ZnCl(2)(C(14)H(13)N(3))], is coordinated by a Cl(2)N(2) donor set defined by quinoline and pyrazole N atoms of the chelating ligand and two Cl atoms. Distortions from the ideal tetra­hedral geometry relate to the restricted bite angle of the chelating ligand [...

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Autores principales: Najib, Muhd. Hidayat bin, Tan, Ai Ling, Young, David J., Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344321/
https://www.ncbi.nlm.nih.gov/pubmed/22590087
http://dx.doi.org/10.1107/S1600536812014390
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author Najib, Muhd. Hidayat bin
Tan, Ai Ling
Young, David J.
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Najib, Muhd. Hidayat bin
Tan, Ai Ling
Young, David J.
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Najib, Muhd. Hidayat bin
collection PubMed
description The Zn(II) atom in the title compound, [ZnCl(2)(C(14)H(13)N(3))], is coordinated by a Cl(2)N(2) donor set defined by quinoline and pyrazole N atoms of the chelating ligand and two Cl atoms. Distortions from the ideal tetra­hedral geometry relate to the restricted bite angle of the chelating ligand [N—Zn—N = 78.54 (12)°]. In the crystal, mol­ecules are connected into a three-dimensional structure by C—H⋯Cl inter­actions, involving both Cl atoms, and π–π inter­actions that occur between the pyrazole ring and each of the pyridine and benzene rings of the quinoline residue [inter­centroid distances = 3.655 (2) and 3.676 (2) Å].
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spelling pubmed-33443212012-05-15 Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))quinoline-κN]zinc Najib, Muhd. Hidayat bin Tan, Ai Ling Young, David J. Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Zn(II) atom in the title compound, [ZnCl(2)(C(14)H(13)N(3))], is coordinated by a Cl(2)N(2) donor set defined by quinoline and pyrazole N atoms of the chelating ligand and two Cl atoms. Distortions from the ideal tetra­hedral geometry relate to the restricted bite angle of the chelating ligand [N—Zn—N = 78.54 (12)°]. In the crystal, mol­ecules are connected into a three-dimensional structure by C—H⋯Cl inter­actions, involving both Cl atoms, and π–π inter­actions that occur between the pyrazole ring and each of the pyridine and benzene rings of the quinoline residue [inter­centroid distances = 3.655 (2) and 3.676 (2) Å]. International Union of Crystallography 2012-04-13 /pmc/articles/PMC3344321/ /pubmed/22590087 http://dx.doi.org/10.1107/S1600536812014390 Text en © Najib et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Najib, Muhd. Hidayat bin
Tan, Ai Ling
Young, David J.
Ng, Seik Weng
Tiekink, Edward R. T.
Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))quinoline-κN]zinc
title Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))quinoline-κN]zinc
title_full Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))quinoline-κN]zinc
title_fullStr Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))quinoline-κN]zinc
title_full_unstemmed Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))quinoline-κN]zinc
title_short Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))quinoline-κN]zinc
title_sort dichlorido[2-(3,5-dimethyl-1h-pyrazol-1-yl-κn (2))quinoline-κn]zinc
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344321/
https://www.ncbi.nlm.nih.gov/pubmed/22590087
http://dx.doi.org/10.1107/S1600536812014390
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