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Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))quinoline-κN]zinc
The Zn(II) atom in the title compound, [ZnCl(2)(C(14)H(13)N(3))], is coordinated by a Cl(2)N(2) donor set defined by quinoline and pyrazole N atoms of the chelating ligand and two Cl atoms. Distortions from the ideal tetrahedral geometry relate to the restricted bite angle of the chelating ligand [...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344321/ https://www.ncbi.nlm.nih.gov/pubmed/22590087 http://dx.doi.org/10.1107/S1600536812014390 |
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author | Najib, Muhd. Hidayat bin Tan, Ai Ling Young, David J. Ng, Seik Weng Tiekink, Edward R. T. |
author_facet | Najib, Muhd. Hidayat bin Tan, Ai Ling Young, David J. Ng, Seik Weng Tiekink, Edward R. T. |
author_sort | Najib, Muhd. Hidayat bin |
collection | PubMed |
description | The Zn(II) atom in the title compound, [ZnCl(2)(C(14)H(13)N(3))], is coordinated by a Cl(2)N(2) donor set defined by quinoline and pyrazole N atoms of the chelating ligand and two Cl atoms. Distortions from the ideal tetrahedral geometry relate to the restricted bite angle of the chelating ligand [N—Zn—N = 78.54 (12)°]. In the crystal, molecules are connected into a three-dimensional structure by C—H⋯Cl interactions, involving both Cl atoms, and π–π interactions that occur between the pyrazole ring and each of the pyridine and benzene rings of the quinoline residue [intercentroid distances = 3.655 (2) and 3.676 (2) Å]. |
format | Online Article Text |
id | pubmed-3344321 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33443212012-05-15 Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))quinoline-κN]zinc Najib, Muhd. Hidayat bin Tan, Ai Ling Young, David J. Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Zn(II) atom in the title compound, [ZnCl(2)(C(14)H(13)N(3))], is coordinated by a Cl(2)N(2) donor set defined by quinoline and pyrazole N atoms of the chelating ligand and two Cl atoms. Distortions from the ideal tetrahedral geometry relate to the restricted bite angle of the chelating ligand [N—Zn—N = 78.54 (12)°]. In the crystal, molecules are connected into a three-dimensional structure by C—H⋯Cl interactions, involving both Cl atoms, and π–π interactions that occur between the pyrazole ring and each of the pyridine and benzene rings of the quinoline residue [intercentroid distances = 3.655 (2) and 3.676 (2) Å]. International Union of Crystallography 2012-04-13 /pmc/articles/PMC3344321/ /pubmed/22590087 http://dx.doi.org/10.1107/S1600536812014390 Text en © Najib et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Najib, Muhd. Hidayat bin Tan, Ai Ling Young, David J. Ng, Seik Weng Tiekink, Edward R. T. Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))quinoline-κN]zinc |
title | Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN
(2))quinoline-κN]zinc |
title_full | Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN
(2))quinoline-κN]zinc |
title_fullStr | Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN
(2))quinoline-κN]zinc |
title_full_unstemmed | Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN
(2))quinoline-κN]zinc |
title_short | Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN
(2))quinoline-κN]zinc |
title_sort | dichlorido[2-(3,5-dimethyl-1h-pyrazol-1-yl-κn
(2))quinoline-κn]zinc |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344321/ https://www.ncbi.nlm.nih.gov/pubmed/22590087 http://dx.doi.org/10.1107/S1600536812014390 |
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