Bis[2-(benzyl­imino­meth­yl)pyrrol-1-ido-κ(2) N,N′]bis­(dimethyl­amido-κN)titanium(IV)

The mononuclear title complex, [Ti(C(2)H(6)N)(2)(C(12)H(11)N(2))(2)], was synthesized by the reaction of 1-phenyl-N-[(pyrrol-2-yl)methyl­idene]methanamine with Ti(NMe(2))(4). The Ti(IV) atom is coordinated in a distorted octa­hedral geometry by four N atoms from two derivatized methanamine ligands a...

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Detalles Bibliográficos
Autores principales: Chen, Zhou, Liu, Yonglu, Li, Yahong, Hu, Bin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344322/
https://www.ncbi.nlm.nih.gov/pubmed/22590088
http://dx.doi.org/10.1107/S1600536812014365
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author Chen, Zhou
Liu, Yonglu
Li, Yahong
Hu, Bin
author_facet Chen, Zhou
Liu, Yonglu
Li, Yahong
Hu, Bin
author_sort Chen, Zhou
collection PubMed
description The mononuclear title complex, [Ti(C(2)H(6)N)(2)(C(12)H(11)N(2))(2)], was synthesized by the reaction of 1-phenyl-N-[(pyrrol-2-yl)methyl­idene]methanamine with Ti(NMe(2))(4). The Ti(IV) atom is coordinated in a distorted octa­hedral geometry by four N atoms from two derivatized methanamine ligands and two N atoms from two dimethyl­amide ions. The dihedral angles between the pyrrole and phenyl rings in the bidentate ligands are 62.36 (9) and 78.32 (8)°. In the crystal, a weak π–π stacking inter­action [centroid–centroid distance = 3.864 (2) Å] involving centrosymmetrically related mol­ecules is observed.
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spelling pubmed-33443222012-05-15 Bis[2-(benzyl­imino­meth­yl)pyrrol-1-ido-κ(2) N,N′]bis­(dimethyl­amido-κN)titanium(IV) Chen, Zhou Liu, Yonglu Li, Yahong Hu, Bin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The mononuclear title complex, [Ti(C(2)H(6)N)(2)(C(12)H(11)N(2))(2)], was synthesized by the reaction of 1-phenyl-N-[(pyrrol-2-yl)methyl­idene]methanamine with Ti(NMe(2))(4). The Ti(IV) atom is coordinated in a distorted octa­hedral geometry by four N atoms from two derivatized methanamine ligands and two N atoms from two dimethyl­amide ions. The dihedral angles between the pyrrole and phenyl rings in the bidentate ligands are 62.36 (9) and 78.32 (8)°. In the crystal, a weak π–π stacking inter­action [centroid–centroid distance = 3.864 (2) Å] involving centrosymmetrically related mol­ecules is observed. International Union of Crystallography 2012-04-13 /pmc/articles/PMC3344322/ /pubmed/22590088 http://dx.doi.org/10.1107/S1600536812014365 Text en © Chen et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chen, Zhou
Liu, Yonglu
Li, Yahong
Hu, Bin
Bis[2-(benzyl­imino­meth­yl)pyrrol-1-ido-κ(2) N,N′]bis­(dimethyl­amido-κN)titanium(IV)
title Bis[2-(benzyl­imino­meth­yl)pyrrol-1-ido-κ(2) N,N′]bis­(dimethyl­amido-κN)titanium(IV)
title_full Bis[2-(benzyl­imino­meth­yl)pyrrol-1-ido-κ(2) N,N′]bis­(dimethyl­amido-κN)titanium(IV)
title_fullStr Bis[2-(benzyl­imino­meth­yl)pyrrol-1-ido-κ(2) N,N′]bis­(dimethyl­amido-κN)titanium(IV)
title_full_unstemmed Bis[2-(benzyl­imino­meth­yl)pyrrol-1-ido-κ(2) N,N′]bis­(dimethyl­amido-κN)titanium(IV)
title_short Bis[2-(benzyl­imino­meth­yl)pyrrol-1-ido-κ(2) N,N′]bis­(dimethyl­amido-κN)titanium(IV)
title_sort bis[2-(benzyl­imino­meth­yl)pyrrol-1-ido-κ(2) n,n′]bis­(dimethyl­amido-κn)titanium(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344322/
https://www.ncbi.nlm.nih.gov/pubmed/22590088
http://dx.doi.org/10.1107/S1600536812014365
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