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catena-Poly[[[aqua­(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc]-μ-3-chloro­benzene-1,2-dicaboxylato-κ(2) O (2):O (3)] [[(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc]-μ-3-chloro­benzene-1,2-dicaboxylato-κ(2) O (2):O (3)]]

In the title compound, {[Zn(C(8)H(3)ClO(4))(C(12)H(12)N(2))(H(2)O)]·[Zn(C(8)H(3)ClO(4))(C(12)H(12)N(2))]}(n), one Zn(2+) ion is five-coordin­ated by two O atoms from two different 3-chloro­benzene-1,2-dicarboxyl­ate ligands, one O atom from a water mol­ecule and two N atoms from a 4,4′-dimethyl-2,2′...

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Detalles Bibliográficos
Autores principales: Zhu, Yu, Li, Hai-Yang, Ma, Ming-Li
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344323/
https://www.ncbi.nlm.nih.gov/pubmed/22590089
http://dx.doi.org/10.1107/S1600536812014006
Descripción
Sumario:In the title compound, {[Zn(C(8)H(3)ClO(4))(C(12)H(12)N(2))(H(2)O)]·[Zn(C(8)H(3)ClO(4))(C(12)H(12)N(2))]}(n), one Zn(2+) ion is five-coordin­ated by two O atoms from two different 3-chloro­benzene-1,2-dicarboxyl­ate ligands, one O atom from a water mol­ecule and two N atoms from a 4,4′-dimethyl-2,2′-bipyridine ligand, while the second Zn(2+) ion is four-coordinated by two O atoms from two different 3-chloro­benzene-1,2-dicarboxyl­ate ligands, and two N atoms from a 4,4′-bimethyl-2,2′-bipyridine ligand. The crystal structure exhibits a three-dimensional supra­molecular structure composed of alternate Zn(C(8)H(3)O(4)Cl)(C(12)H(12)N(2)) and Zn(C(8)H(3)O(4)Cl)(C(12)H(12)N(2))(H(2)O) chains, which are linked together by face-to-face π–π inter­actions [shortest centroid–centroid distances of 3.661 (4) and 3.6901 (3) Å], O—H⋯O and C—H⋯O hydrogen bonds.