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catena-Poly[[[aqua(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc]-μ-3-chlorobenzene-1,2-dicaboxylato-κ(2) O (2):O (3)] [[(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc]-μ-3-chlorobenzene-1,2-dicaboxylato-κ(2) O (2):O (3)]]
In the title compound, {[Zn(C(8)H(3)ClO(4))(C(12)H(12)N(2))(H(2)O)]·[Zn(C(8)H(3)ClO(4))(C(12)H(12)N(2))]}(n), one Zn(2+) ion is five-coordinated by two O atoms from two different 3-chlorobenzene-1,2-dicarboxylate ligands, one O atom from a water molecule and two N atoms from a 4,4′-dimethyl-2,2′...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344323/ https://www.ncbi.nlm.nih.gov/pubmed/22590089 http://dx.doi.org/10.1107/S1600536812014006 |
_version_ | 1782231966510219264 |
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author | Zhu, Yu Li, Hai-Yang Ma, Ming-Li |
author_facet | Zhu, Yu Li, Hai-Yang Ma, Ming-Li |
author_sort | Zhu, Yu |
collection | PubMed |
description | In the title compound, {[Zn(C(8)H(3)ClO(4))(C(12)H(12)N(2))(H(2)O)]·[Zn(C(8)H(3)ClO(4))(C(12)H(12)N(2))]}(n), one Zn(2+) ion is five-coordinated by two O atoms from two different 3-chlorobenzene-1,2-dicarboxylate ligands, one O atom from a water molecule and two N atoms from a 4,4′-dimethyl-2,2′-bipyridine ligand, while the second Zn(2+) ion is four-coordinated by two O atoms from two different 3-chlorobenzene-1,2-dicarboxylate ligands, and two N atoms from a 4,4′-bimethyl-2,2′-bipyridine ligand. The crystal structure exhibits a three-dimensional supramolecular structure composed of alternate Zn(C(8)H(3)O(4)Cl)(C(12)H(12)N(2)) and Zn(C(8)H(3)O(4)Cl)(C(12)H(12)N(2))(H(2)O) chains, which are linked together by face-to-face π–π interactions [shortest centroid–centroid distances of 3.661 (4) and 3.6901 (3) Å], O—H⋯O and C—H⋯O hydrogen bonds. |
format | Online Article Text |
id | pubmed-3344323 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33443232012-05-15 catena-Poly[[[aqua(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc]-μ-3-chlorobenzene-1,2-dicaboxylato-κ(2) O (2):O (3)] [[(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc]-μ-3-chlorobenzene-1,2-dicaboxylato-κ(2) O (2):O (3)]] Zhu, Yu Li, Hai-Yang Ma, Ming-Li Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Zn(C(8)H(3)ClO(4))(C(12)H(12)N(2))(H(2)O)]·[Zn(C(8)H(3)ClO(4))(C(12)H(12)N(2))]}(n), one Zn(2+) ion is five-coordinated by two O atoms from two different 3-chlorobenzene-1,2-dicarboxylate ligands, one O atom from a water molecule and two N atoms from a 4,4′-dimethyl-2,2′-bipyridine ligand, while the second Zn(2+) ion is four-coordinated by two O atoms from two different 3-chlorobenzene-1,2-dicarboxylate ligands, and two N atoms from a 4,4′-bimethyl-2,2′-bipyridine ligand. The crystal structure exhibits a three-dimensional supramolecular structure composed of alternate Zn(C(8)H(3)O(4)Cl)(C(12)H(12)N(2)) and Zn(C(8)H(3)O(4)Cl)(C(12)H(12)N(2))(H(2)O) chains, which are linked together by face-to-face π–π interactions [shortest centroid–centroid distances of 3.661 (4) and 3.6901 (3) Å], O—H⋯O and C—H⋯O hydrogen bonds. International Union of Crystallography 2012-04-13 /pmc/articles/PMC3344323/ /pubmed/22590089 http://dx.doi.org/10.1107/S1600536812014006 Text en © Zhu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhu, Yu Li, Hai-Yang Ma, Ming-Li catena-Poly[[[aqua(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc]-μ-3-chlorobenzene-1,2-dicaboxylato-κ(2) O (2):O (3)] [[(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc]-μ-3-chlorobenzene-1,2-dicaboxylato-κ(2) O (2):O (3)]] |
title |
catena-Poly[[[aqua(4,4′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)zinc]-μ-3-chlorobenzene-1,2-dicaboxylato-κ(2)
O
(2):O
(3)] [[(4,4′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)zinc]-μ-3-chlorobenzene-1,2-dicaboxylato-κ(2)
O
(2):O
(3)]] |
title_full |
catena-Poly[[[aqua(4,4′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)zinc]-μ-3-chlorobenzene-1,2-dicaboxylato-κ(2)
O
(2):O
(3)] [[(4,4′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)zinc]-μ-3-chlorobenzene-1,2-dicaboxylato-κ(2)
O
(2):O
(3)]] |
title_fullStr |
catena-Poly[[[aqua(4,4′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)zinc]-μ-3-chlorobenzene-1,2-dicaboxylato-κ(2)
O
(2):O
(3)] [[(4,4′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)zinc]-μ-3-chlorobenzene-1,2-dicaboxylato-κ(2)
O
(2):O
(3)]] |
title_full_unstemmed |
catena-Poly[[[aqua(4,4′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)zinc]-μ-3-chlorobenzene-1,2-dicaboxylato-κ(2)
O
(2):O
(3)] [[(4,4′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)zinc]-μ-3-chlorobenzene-1,2-dicaboxylato-κ(2)
O
(2):O
(3)]] |
title_short |
catena-Poly[[[aqua(4,4′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)zinc]-μ-3-chlorobenzene-1,2-dicaboxylato-κ(2)
O
(2):O
(3)] [[(4,4′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)zinc]-μ-3-chlorobenzene-1,2-dicaboxylato-κ(2)
O
(2):O
(3)]] |
title_sort | catena-poly[[[aqua(4,4′-dimethyl-2,2′-bipyridine-κ(2)
n,n′)zinc]-μ-3-chlorobenzene-1,2-dicaboxylato-κ(2)
o
(2):o
(3)] [[(4,4′-dimethyl-2,2′-bipyridine-κ(2)
n,n′)zinc]-μ-3-chlorobenzene-1,2-dicaboxylato-κ(2)
o
(2):o
(3)]] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344323/ https://www.ncbi.nlm.nih.gov/pubmed/22590089 http://dx.doi.org/10.1107/S1600536812014006 |
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