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catena-Poly[[[aqua­(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc]-μ-3-chloro­benzene-1,2-dicaboxylato-κ(2) O (2):O (3)] [[(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc]-μ-3-chloro­benzene-1,2-dicaboxylato-κ(2) O (2):O (3)]]

In the title compound, {[Zn(C(8)H(3)ClO(4))(C(12)H(12)N(2))(H(2)O)]·[Zn(C(8)H(3)ClO(4))(C(12)H(12)N(2))]}(n), one Zn(2+) ion is five-coordin­ated by two O atoms from two different 3-chloro­benzene-1,2-dicarboxyl­ate ligands, one O atom from a water mol­ecule and two N atoms from a 4,4′-dimethyl-2,2′...

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Detalles Bibliográficos
Autores principales: Zhu, Yu, Li, Hai-Yang, Ma, Ming-Li
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344323/
https://www.ncbi.nlm.nih.gov/pubmed/22590089
http://dx.doi.org/10.1107/S1600536812014006
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author Zhu, Yu
Li, Hai-Yang
Ma, Ming-Li
author_facet Zhu, Yu
Li, Hai-Yang
Ma, Ming-Li
author_sort Zhu, Yu
collection PubMed
description In the title compound, {[Zn(C(8)H(3)ClO(4))(C(12)H(12)N(2))(H(2)O)]·[Zn(C(8)H(3)ClO(4))(C(12)H(12)N(2))]}(n), one Zn(2+) ion is five-coordin­ated by two O atoms from two different 3-chloro­benzene-1,2-dicarboxyl­ate ligands, one O atom from a water mol­ecule and two N atoms from a 4,4′-dimethyl-2,2′-bipyridine ligand, while the second Zn(2+) ion is four-coordinated by two O atoms from two different 3-chloro­benzene-1,2-dicarboxyl­ate ligands, and two N atoms from a 4,4′-bimethyl-2,2′-bipyridine ligand. The crystal structure exhibits a three-dimensional supra­molecular structure composed of alternate Zn(C(8)H(3)O(4)Cl)(C(12)H(12)N(2)) and Zn(C(8)H(3)O(4)Cl)(C(12)H(12)N(2))(H(2)O) chains, which are linked together by face-to-face π–π inter­actions [shortest centroid–centroid distances of 3.661 (4) and 3.6901 (3) Å], O—H⋯O and C—H⋯O hydrogen bonds.
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spelling pubmed-33443232012-05-15 catena-Poly[[[aqua­(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc]-μ-3-chloro­benzene-1,2-dicaboxylato-κ(2) O (2):O (3)] [[(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc]-μ-3-chloro­benzene-1,2-dicaboxylato-κ(2) O (2):O (3)]] Zhu, Yu Li, Hai-Yang Ma, Ming-Li Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Zn(C(8)H(3)ClO(4))(C(12)H(12)N(2))(H(2)O)]·[Zn(C(8)H(3)ClO(4))(C(12)H(12)N(2))]}(n), one Zn(2+) ion is five-coordin­ated by two O atoms from two different 3-chloro­benzene-1,2-dicarboxyl­ate ligands, one O atom from a water mol­ecule and two N atoms from a 4,4′-dimethyl-2,2′-bipyridine ligand, while the second Zn(2+) ion is four-coordinated by two O atoms from two different 3-chloro­benzene-1,2-dicarboxyl­ate ligands, and two N atoms from a 4,4′-bimethyl-2,2′-bipyridine ligand. The crystal structure exhibits a three-dimensional supra­molecular structure composed of alternate Zn(C(8)H(3)O(4)Cl)(C(12)H(12)N(2)) and Zn(C(8)H(3)O(4)Cl)(C(12)H(12)N(2))(H(2)O) chains, which are linked together by face-to-face π–π inter­actions [shortest centroid–centroid distances of 3.661 (4) and 3.6901 (3) Å], O—H⋯O and C—H⋯O hydrogen bonds. International Union of Crystallography 2012-04-13 /pmc/articles/PMC3344323/ /pubmed/22590089 http://dx.doi.org/10.1107/S1600536812014006 Text en © Zhu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhu, Yu
Li, Hai-Yang
Ma, Ming-Li
catena-Poly[[[aqua­(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc]-μ-3-chloro­benzene-1,2-dicaboxylato-κ(2) O (2):O (3)] [[(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc]-μ-3-chloro­benzene-1,2-dicaboxylato-κ(2) O (2):O (3)]]
title catena-Poly[[[aqua­(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc]-μ-3-chloro­benzene-1,2-dicaboxylato-κ(2) O (2):O (3)] [[(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc]-μ-3-chloro­benzene-1,2-dicaboxylato-κ(2) O (2):O (3)]]
title_full catena-Poly[[[aqua­(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc]-μ-3-chloro­benzene-1,2-dicaboxylato-κ(2) O (2):O (3)] [[(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc]-μ-3-chloro­benzene-1,2-dicaboxylato-κ(2) O (2):O (3)]]
title_fullStr catena-Poly[[[aqua­(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc]-μ-3-chloro­benzene-1,2-dicaboxylato-κ(2) O (2):O (3)] [[(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc]-μ-3-chloro­benzene-1,2-dicaboxylato-κ(2) O (2):O (3)]]
title_full_unstemmed catena-Poly[[[aqua­(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc]-μ-3-chloro­benzene-1,2-dicaboxylato-κ(2) O (2):O (3)] [[(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc]-μ-3-chloro­benzene-1,2-dicaboxylato-κ(2) O (2):O (3)]]
title_short catena-Poly[[[aqua­(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc]-μ-3-chloro­benzene-1,2-dicaboxylato-κ(2) O (2):O (3)] [[(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc]-μ-3-chloro­benzene-1,2-dicaboxylato-κ(2) O (2):O (3)]]
title_sort catena-poly[[[aqua­(4,4′-dimethyl-2,2′-bipyridine-κ(2) n,n′)zinc]-μ-3-chloro­benzene-1,2-dicaboxylato-κ(2) o (2):o (3)] [[(4,4′-dimethyl-2,2′-bipyridine-κ(2) n,n′)zinc]-μ-3-chloro­benzene-1,2-dicaboxylato-κ(2) o (2):o (3)]]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344323/
https://www.ncbi.nlm.nih.gov/pubmed/22590089
http://dx.doi.org/10.1107/S1600536812014006
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