catena-Poly[(dichloridozinc)-μ-4,4′-bis­[(1H-imidazol-1-yl)meth­yl]biphenyl-κ(2) N (3):N (3′)]

In the title compound, [ZnCl(2)(C(20)H(18)N(4))](n), the Zn(II) ion lies on a twofold rotation axis and is four-coordinated in a tetra­hedral geometry defined by two Cl anions and two N atoms from two 4,4′-bis­[(imidazol-1-yl)meth­yl]biphenyl ligands. The mid-point of the ligand is located on an inv...

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Detalles Bibliográficos
Autores principales: Wang, Cheng, Wen, Bo, Sun, Zhi-Yao, Yan, Peng-Fei, Gao, Jin-Sheng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344324/
https://www.ncbi.nlm.nih.gov/pubmed/22590090
http://dx.doi.org/10.1107/S1600536812014043
Descripción
Sumario:In the title compound, [ZnCl(2)(C(20)H(18)N(4))](n), the Zn(II) ion lies on a twofold rotation axis and is four-coordinated in a tetra­hedral geometry defined by two Cl anions and two N atoms from two 4,4′-bis­[(imidazol-1-yl)meth­yl]biphenyl ligands. The mid-point of the ligand is located on an inversion center, and shows a trans conformation. The ligands link the Zn(II) ions, forming a chain structure along [10-1].

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