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catena-Poly[(dichloridozinc)-μ-4,4′-bis­[(1H-imidazol-1-yl)meth­yl]biphenyl-κ(2) N (3):N (3′)]

In the title compound, [ZnCl(2)(C(20)H(18)N(4))](n), the Zn(II) ion lies on a twofold rotation axis and is four-coordinated in a tetra­hedral geometry defined by two Cl anions and two N atoms from two 4,4′-bis­[(imidazol-1-yl)meth­yl]biphenyl ligands. The mid-point of the ligand is located on an inv...

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Detalles Bibliográficos
Autores principales: Wang, Cheng, Wen, Bo, Sun, Zhi-Yao, Yan, Peng-Fei, Gao, Jin-Sheng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344324/
https://www.ncbi.nlm.nih.gov/pubmed/22590090
http://dx.doi.org/10.1107/S1600536812014043
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author Wang, Cheng
Wen, Bo
Sun, Zhi-Yao
Yan, Peng-Fei
Gao, Jin-Sheng
author_facet Wang, Cheng
Wen, Bo
Sun, Zhi-Yao
Yan, Peng-Fei
Gao, Jin-Sheng
author_sort Wang, Cheng
collection PubMed
description In the title compound, [ZnCl(2)(C(20)H(18)N(4))](n), the Zn(II) ion lies on a twofold rotation axis and is four-coordinated in a tetra­hedral geometry defined by two Cl anions and two N atoms from two 4,4′-bis­[(imidazol-1-yl)meth­yl]biphenyl ligands. The mid-point of the ligand is located on an inversion center, and shows a trans conformation. The ligands link the Zn(II) ions, forming a chain structure along [10-1].
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spelling pubmed-33443242012-05-15 catena-Poly[(dichloridozinc)-μ-4,4′-bis­[(1H-imidazol-1-yl)meth­yl]biphenyl-κ(2) N (3):N (3′)] Wang, Cheng Wen, Bo Sun, Zhi-Yao Yan, Peng-Fei Gao, Jin-Sheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [ZnCl(2)(C(20)H(18)N(4))](n), the Zn(II) ion lies on a twofold rotation axis and is four-coordinated in a tetra­hedral geometry defined by two Cl anions and two N atoms from two 4,4′-bis­[(imidazol-1-yl)meth­yl]biphenyl ligands. The mid-point of the ligand is located on an inversion center, and shows a trans conformation. The ligands link the Zn(II) ions, forming a chain structure along [10-1]. International Union of Crystallography 2012-04-13 /pmc/articles/PMC3344324/ /pubmed/22590090 http://dx.doi.org/10.1107/S1600536812014043 Text en © Wang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Cheng
Wen, Bo
Sun, Zhi-Yao
Yan, Peng-Fei
Gao, Jin-Sheng
catena-Poly[(dichloridozinc)-μ-4,4′-bis­[(1H-imidazol-1-yl)meth­yl]biphenyl-κ(2) N (3):N (3′)]
title catena-Poly[(dichloridozinc)-μ-4,4′-bis­[(1H-imidazol-1-yl)meth­yl]biphenyl-κ(2) N (3):N (3′)]
title_full catena-Poly[(dichloridozinc)-μ-4,4′-bis­[(1H-imidazol-1-yl)meth­yl]biphenyl-κ(2) N (3):N (3′)]
title_fullStr catena-Poly[(dichloridozinc)-μ-4,4′-bis­[(1H-imidazol-1-yl)meth­yl]biphenyl-κ(2) N (3):N (3′)]
title_full_unstemmed catena-Poly[(dichloridozinc)-μ-4,4′-bis­[(1H-imidazol-1-yl)meth­yl]biphenyl-κ(2) N (3):N (3′)]
title_short catena-Poly[(dichloridozinc)-μ-4,4′-bis­[(1H-imidazol-1-yl)meth­yl]biphenyl-κ(2) N (3):N (3′)]
title_sort catena-poly[(dichloridozinc)-μ-4,4′-bis­[(1h-imidazol-1-yl)meth­yl]biphenyl-κ(2) n (3):n (3′)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344324/
https://www.ncbi.nlm.nih.gov/pubmed/22590090
http://dx.doi.org/10.1107/S1600536812014043
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