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catena-Poly[(dichloridozinc)-μ-4,4′-bis[(1H-imidazol-1-yl)methyl]biphenyl-κ(2) N (3):N (3′)]
In the title compound, [ZnCl(2)(C(20)H(18)N(4))](n), the Zn(II) ion lies on a twofold rotation axis and is four-coordinated in a tetrahedral geometry defined by two Cl anions and two N atoms from two 4,4′-bis[(imidazol-1-yl)methyl]biphenyl ligands. The mid-point of the ligand is located on an inv...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344324/ https://www.ncbi.nlm.nih.gov/pubmed/22590090 http://dx.doi.org/10.1107/S1600536812014043 |
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author | Wang, Cheng Wen, Bo Sun, Zhi-Yao Yan, Peng-Fei Gao, Jin-Sheng |
author_facet | Wang, Cheng Wen, Bo Sun, Zhi-Yao Yan, Peng-Fei Gao, Jin-Sheng |
author_sort | Wang, Cheng |
collection | PubMed |
description | In the title compound, [ZnCl(2)(C(20)H(18)N(4))](n), the Zn(II) ion lies on a twofold rotation axis and is four-coordinated in a tetrahedral geometry defined by two Cl anions and two N atoms from two 4,4′-bis[(imidazol-1-yl)methyl]biphenyl ligands. The mid-point of the ligand is located on an inversion center, and shows a trans conformation. The ligands link the Zn(II) ions, forming a chain structure along [10-1]. |
format | Online Article Text |
id | pubmed-3344324 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33443242012-05-15 catena-Poly[(dichloridozinc)-μ-4,4′-bis[(1H-imidazol-1-yl)methyl]biphenyl-κ(2) N (3):N (3′)] Wang, Cheng Wen, Bo Sun, Zhi-Yao Yan, Peng-Fei Gao, Jin-Sheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [ZnCl(2)(C(20)H(18)N(4))](n), the Zn(II) ion lies on a twofold rotation axis and is four-coordinated in a tetrahedral geometry defined by two Cl anions and two N atoms from two 4,4′-bis[(imidazol-1-yl)methyl]biphenyl ligands. The mid-point of the ligand is located on an inversion center, and shows a trans conformation. The ligands link the Zn(II) ions, forming a chain structure along [10-1]. International Union of Crystallography 2012-04-13 /pmc/articles/PMC3344324/ /pubmed/22590090 http://dx.doi.org/10.1107/S1600536812014043 Text en © Wang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Cheng Wen, Bo Sun, Zhi-Yao Yan, Peng-Fei Gao, Jin-Sheng catena-Poly[(dichloridozinc)-μ-4,4′-bis[(1H-imidazol-1-yl)methyl]biphenyl-κ(2) N (3):N (3′)] |
title |
catena-Poly[(dichloridozinc)-μ-4,4′-bis[(1H-imidazol-1-yl)methyl]biphenyl-κ(2)
N
(3):N
(3′)] |
title_full |
catena-Poly[(dichloridozinc)-μ-4,4′-bis[(1H-imidazol-1-yl)methyl]biphenyl-κ(2)
N
(3):N
(3′)] |
title_fullStr |
catena-Poly[(dichloridozinc)-μ-4,4′-bis[(1H-imidazol-1-yl)methyl]biphenyl-κ(2)
N
(3):N
(3′)] |
title_full_unstemmed |
catena-Poly[(dichloridozinc)-μ-4,4′-bis[(1H-imidazol-1-yl)methyl]biphenyl-κ(2)
N
(3):N
(3′)] |
title_short |
catena-Poly[(dichloridozinc)-μ-4,4′-bis[(1H-imidazol-1-yl)methyl]biphenyl-κ(2)
N
(3):N
(3′)] |
title_sort | catena-poly[(dichloridozinc)-μ-4,4′-bis[(1h-imidazol-1-yl)methyl]biphenyl-κ(2)
n
(3):n
(3′)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344324/ https://www.ncbi.nlm.nih.gov/pubmed/22590090 http://dx.doi.org/10.1107/S1600536812014043 |
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