Trichloridotris{N-[phen­yl(pyridin-2-yl)methyl­idene]hydroxyl­amine-κ(2) N,N′}neodymium(III)

In the title compound, [NdCl(3)(C(12)H(10)N(2)O)(3)], the central Nd(III) ion is nine-coordinated by six N atoms from three bidentate chelate N-[phen­yl(pyridin-2-yl)methyl­idene]hydroxyl­amine ligands and three Cl(−) ions, and displays a distorted tricapped trigonal prismatic geometry. The complex...

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Detalles Bibliográficos
Autor principal: Yang, Hua
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344326/
https://www.ncbi.nlm.nih.gov/pubmed/22590092
http://dx.doi.org/10.1107/S1600536812014055
Descripción
Sumario:In the title compound, [NdCl(3)(C(12)H(10)N(2)O)(3)], the central Nd(III) ion is nine-coordinated by six N atoms from three bidentate chelate N-[phen­yl(pyridin-2-yl)methyl­idene]hydroxyl­amine ligands and three Cl(−) ions, and displays a distorted tricapped trigonal prismatic geometry. The complex mol­ecules are stabilized by intra­molecular O—H⋯Cl hydrogen bonds.

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