Trichloridotris{N-[phen­yl(pyridin-2-yl)methyl­idene]hydroxyl­amine-κ(2) N,N′}neodymium(III)

In the title compound, [NdCl(3)(C(12)H(10)N(2)O)(3)], the central Nd(III) ion is nine-coordinated by six N atoms from three bidentate chelate N-[phen­yl(pyridin-2-yl)methyl­idene]hydroxyl­amine ligands and three Cl(−) ions, and displays a distorted tricapped trigonal prismatic geometry. The complex...

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Detalles Bibliográficos
Autor principal: Yang, Hua
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344326/
https://www.ncbi.nlm.nih.gov/pubmed/22590092
http://dx.doi.org/10.1107/S1600536812014055
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author Yang, Hua
author_facet Yang, Hua
author_sort Yang, Hua
collection PubMed
description In the title compound, [NdCl(3)(C(12)H(10)N(2)O)(3)], the central Nd(III) ion is nine-coordinated by six N atoms from three bidentate chelate N-[phen­yl(pyridin-2-yl)methyl­idene]hydroxyl­amine ligands and three Cl(−) ions, and displays a distorted tricapped trigonal prismatic geometry. The complex mol­ecules are stabilized by intra­molecular O—H⋯Cl hydrogen bonds.
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spelling pubmed-33443262012-05-15 Trichloridotris{N-[phen­yl(pyridin-2-yl)methyl­idene]hydroxyl­amine-κ(2) N,N′}neodymium(III) Yang, Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [NdCl(3)(C(12)H(10)N(2)O)(3)], the central Nd(III) ion is nine-coordinated by six N atoms from three bidentate chelate N-[phen­yl(pyridin-2-yl)methyl­idene]hydroxyl­amine ligands and three Cl(−) ions, and displays a distorted tricapped trigonal prismatic geometry. The complex mol­ecules are stabilized by intra­molecular O—H⋯Cl hydrogen bonds. International Union of Crystallography 2012-04-13 /pmc/articles/PMC3344326/ /pubmed/22590092 http://dx.doi.org/10.1107/S1600536812014055 Text en © Hua Yang 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yang, Hua
Trichloridotris{N-[phen­yl(pyridin-2-yl)methyl­idene]hydroxyl­amine-κ(2) N,N′}neodymium(III)
title Trichloridotris{N-[phen­yl(pyridin-2-yl)methyl­idene]hydroxyl­amine-κ(2) N,N′}neodymium(III)
title_full Trichloridotris{N-[phen­yl(pyridin-2-yl)methyl­idene]hydroxyl­amine-κ(2) N,N′}neodymium(III)
title_fullStr Trichloridotris{N-[phen­yl(pyridin-2-yl)methyl­idene]hydroxyl­amine-κ(2) N,N′}neodymium(III)
title_full_unstemmed Trichloridotris{N-[phen­yl(pyridin-2-yl)methyl­idene]hydroxyl­amine-κ(2) N,N′}neodymium(III)
title_short Trichloridotris{N-[phen­yl(pyridin-2-yl)methyl­idene]hydroxyl­amine-κ(2) N,N′}neodymium(III)
title_sort trichloridotris{n-[phen­yl(pyridin-2-yl)methyl­idene]hydroxyl­amine-κ(2) n,n′}neodymium(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344326/
https://www.ncbi.nlm.nih.gov/pubmed/22590092
http://dx.doi.org/10.1107/S1600536812014055
work_keys_str_mv AT yanghua trichloridotrisnphenylpyridin2ylmethylidenehydroxylaminek2nnneodymiumiii

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