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Bis[μ-N-(2-oxidobenzylidene)pyridine-2-carbohydrazidato]bis[chlorido(methanol-κO)erbium(III)]
In the binuclear title complex, [Er(2)(C(13)H(9)N(3)O(2))(2)Cl(2)(CH(3)OH)(2)], the entire molecule is generated by the application of inversion symmetry. Each Er(III) ion is seven-coordinated by two O atoms and one N atom from one N-(2-oxidobenzylidene)pyridine-2-carbohydrazidate (L (2−)) ligand,...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344327/ https://www.ncbi.nlm.nih.gov/pubmed/22590093 http://dx.doi.org/10.1107/S1600536812013979 |
Sumario: | In the binuclear title complex, [Er(2)(C(13)H(9)N(3)O(2))(2)Cl(2)(CH(3)OH)(2)], the entire molecule is generated by the application of inversion symmetry. Each Er(III) ion is seven-coordinated by two O atoms and one N atom from one N-(2-oxidobenzylidene)pyridine-2-carbohydrazidate (L (2−)) ligand, one O atom and one N atom from the symmetry-related L (2−) ligand, one O atom of a methanol molecule and one chloride anion. The coordination geometry is based on a pseudo-pentagonal bipyramid. Linear supramolecular chains along [010] are formed in the crystal packing through O—H⋯Cl hydrogen bonds. |
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