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Bis[μ-N-(2-oxidobenzyl­idene)pyridine-2-carbohydrazidato]bis­[chlorido(methanol-κO)erbium(III)]

In the binuclear title complex, [Er(2)(C(13)H(9)N(3)O(2))(2)Cl(2)(CH(3)OH)(2)], the entire mol­ecule is generated by the application of inversion symmetry. Each Er(III) ion is seven-coordinated by two O atoms and one N atom from one N-(2-oxidobenzyl­idene)pyridine-2-carbohydrazidate (L (2−)) ligand,...

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Detalles Bibliográficos
Autor principal: Yang, Hua
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344327/
https://www.ncbi.nlm.nih.gov/pubmed/22590093
http://dx.doi.org/10.1107/S1600536812013979
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author Yang, Hua
author_facet Yang, Hua
author_sort Yang, Hua
collection PubMed
description In the binuclear title complex, [Er(2)(C(13)H(9)N(3)O(2))(2)Cl(2)(CH(3)OH)(2)], the entire mol­ecule is generated by the application of inversion symmetry. Each Er(III) ion is seven-coordinated by two O atoms and one N atom from one N-(2-oxidobenzyl­idene)pyridine-2-carbohydrazidate (L (2−)) ligand, one O atom and one N atom from the symmetry-related L (2−) ligand, one O atom of a methanol mol­ecule and one chloride anion. The coordination geometry is based on a pseudo-penta­gonal bipyramid. Linear supra­molecular chains along [010] are formed in the crystal packing through O—H⋯Cl hydrogen bonds.
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spelling pubmed-33443272012-05-15 Bis[μ-N-(2-oxidobenzyl­idene)pyridine-2-carbohydrazidato]bis­[chlorido(methanol-κO)erbium(III)] Yang, Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the binuclear title complex, [Er(2)(C(13)H(9)N(3)O(2))(2)Cl(2)(CH(3)OH)(2)], the entire mol­ecule is generated by the application of inversion symmetry. Each Er(III) ion is seven-coordinated by two O atoms and one N atom from one N-(2-oxidobenzyl­idene)pyridine-2-carbohydrazidate (L (2−)) ligand, one O atom and one N atom from the symmetry-related L (2−) ligand, one O atom of a methanol mol­ecule and one chloride anion. The coordination geometry is based on a pseudo-penta­gonal bipyramid. Linear supra­molecular chains along [010] are formed in the crystal packing through O—H⋯Cl hydrogen bonds. International Union of Crystallography 2012-04-13 /pmc/articles/PMC3344327/ /pubmed/22590093 http://dx.doi.org/10.1107/S1600536812013979 Text en © Hua Yang 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yang, Hua
Bis[μ-N-(2-oxidobenzyl­idene)pyridine-2-carbohydrazidato]bis­[chlorido(methanol-κO)erbium(III)]
title Bis[μ-N-(2-oxidobenzyl­idene)pyridine-2-carbohydrazidato]bis­[chlorido(methanol-κO)erbium(III)]
title_full Bis[μ-N-(2-oxidobenzyl­idene)pyridine-2-carbohydrazidato]bis­[chlorido(methanol-κO)erbium(III)]
title_fullStr Bis[μ-N-(2-oxidobenzyl­idene)pyridine-2-carbohydrazidato]bis­[chlorido(methanol-κO)erbium(III)]
title_full_unstemmed Bis[μ-N-(2-oxidobenzyl­idene)pyridine-2-carbohydrazidato]bis­[chlorido(methanol-κO)erbium(III)]
title_short Bis[μ-N-(2-oxidobenzyl­idene)pyridine-2-carbohydrazidato]bis­[chlorido(methanol-κO)erbium(III)]
title_sort bis[μ-n-(2-oxidobenzyl­idene)pyridine-2-carbohydrazidato]bis­[chlorido(methanol-κo)erbium(iii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344327/
https://www.ncbi.nlm.nih.gov/pubmed/22590093
http://dx.doi.org/10.1107/S1600536812013979
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