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Bis[μ-N-(2-oxidobenzylidene)pyridine-2-carbohydrazidato]bis[chlorido(methanol-κO)erbium(III)]
In the binuclear title complex, [Er(2)(C(13)H(9)N(3)O(2))(2)Cl(2)(CH(3)OH)(2)], the entire molecule is generated by the application of inversion symmetry. Each Er(III) ion is seven-coordinated by two O atoms and one N atom from one N-(2-oxidobenzylidene)pyridine-2-carbohydrazidate (L (2−)) ligand,...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2012
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344327/ https://www.ncbi.nlm.nih.gov/pubmed/22590093 http://dx.doi.org/10.1107/S1600536812013979 |
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author | Yang, Hua |
author_facet | Yang, Hua |
author_sort | Yang, Hua |
collection | PubMed |
description | In the binuclear title complex, [Er(2)(C(13)H(9)N(3)O(2))(2)Cl(2)(CH(3)OH)(2)], the entire molecule is generated by the application of inversion symmetry. Each Er(III) ion is seven-coordinated by two O atoms and one N atom from one N-(2-oxidobenzylidene)pyridine-2-carbohydrazidate (L (2−)) ligand, one O atom and one N atom from the symmetry-related L (2−) ligand, one O atom of a methanol molecule and one chloride anion. The coordination geometry is based on a pseudo-pentagonal bipyramid. Linear supramolecular chains along [010] are formed in the crystal packing through O—H⋯Cl hydrogen bonds. |
format | Online Article Text |
id | pubmed-3344327 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33443272012-05-15 Bis[μ-N-(2-oxidobenzylidene)pyridine-2-carbohydrazidato]bis[chlorido(methanol-κO)erbium(III)] Yang, Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the binuclear title complex, [Er(2)(C(13)H(9)N(3)O(2))(2)Cl(2)(CH(3)OH)(2)], the entire molecule is generated by the application of inversion symmetry. Each Er(III) ion is seven-coordinated by two O atoms and one N atom from one N-(2-oxidobenzylidene)pyridine-2-carbohydrazidate (L (2−)) ligand, one O atom and one N atom from the symmetry-related L (2−) ligand, one O atom of a methanol molecule and one chloride anion. The coordination geometry is based on a pseudo-pentagonal bipyramid. Linear supramolecular chains along [010] are formed in the crystal packing through O—H⋯Cl hydrogen bonds. International Union of Crystallography 2012-04-13 /pmc/articles/PMC3344327/ /pubmed/22590093 http://dx.doi.org/10.1107/S1600536812013979 Text en © Hua Yang 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Yang, Hua Bis[μ-N-(2-oxidobenzylidene)pyridine-2-carbohydrazidato]bis[chlorido(methanol-κO)erbium(III)] |
title | Bis[μ-N-(2-oxidobenzylidene)pyridine-2-carbohydrazidato]bis[chlorido(methanol-κO)erbium(III)] |
title_full | Bis[μ-N-(2-oxidobenzylidene)pyridine-2-carbohydrazidato]bis[chlorido(methanol-κO)erbium(III)] |
title_fullStr | Bis[μ-N-(2-oxidobenzylidene)pyridine-2-carbohydrazidato]bis[chlorido(methanol-κO)erbium(III)] |
title_full_unstemmed | Bis[μ-N-(2-oxidobenzylidene)pyridine-2-carbohydrazidato]bis[chlorido(methanol-κO)erbium(III)] |
title_short | Bis[μ-N-(2-oxidobenzylidene)pyridine-2-carbohydrazidato]bis[chlorido(methanol-κO)erbium(III)] |
title_sort | bis[μ-n-(2-oxidobenzylidene)pyridine-2-carbohydrazidato]bis[chlorido(methanol-κo)erbium(iii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344327/ https://www.ncbi.nlm.nih.gov/pubmed/22590093 http://dx.doi.org/10.1107/S1600536812013979 |
work_keys_str_mv | AT yanghua bismn2oxidobenzylidenepyridine2carbohydrazidatobischloridomethanolkoerbiumiii |