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Trichlorido{μ-6,6′-dimethoxy-2,2′-[cyclohexane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}dimethanolcopper(II)samarium(III)
In the title hetero-dinuclear complex, [CuSm(C(22)H(24)N(2)O(4))Cl(3)(CH(3)OH)(2)], the Cu(II) cation is N,N′,O,O′-chelated by a 6,6′-dimethoxy-2,2′-[cyclohexane-1,2-diylbis(nitrilomethanylylidene)]diphenolate ligand, and one Cl(−) anion further coordinates to the Cu(II) cation to complete the d...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344333/ https://www.ncbi.nlm.nih.gov/pubmed/22590099 http://dx.doi.org/10.1107/S1600536812014523 |
Sumario: | In the title hetero-dinuclear complex, [CuSm(C(22)H(24)N(2)O(4))Cl(3)(CH(3)OH)(2)], the Cu(II) cation is N,N′,O,O′-chelated by a 6,6′-dimethoxy-2,2′-[cyclohexane-1,2-diylbis(nitrilomethanylylidene)]diphenolate ligand, and one Cl(−) anion further coordinates to the Cu(II) cation to complete the distorted square-pyramidal coordination geometry, while the Sm(III) cation is chelated by four O atoms from the same ligand, and is further coordinated by two methanol molecules and two Cl(−) anions in an bicapped trigonal–prismatic geometry. Intra- and intermolecular O—H⋯Cl hydrogen bonds are present in the structure. |
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