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Trichlorido{μ-6,6′-dimethoxy-2,2′-[cyclohexane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}dimethanolcopper(II)samarium(III)
In the title hetero-dinuclear complex, [CuSm(C(22)H(24)N(2)O(4))Cl(3)(CH(3)OH)(2)], the Cu(II) cation is N,N′,O,O′-chelated by a 6,6′-dimethoxy-2,2′-[cyclohexane-1,2-diylbis(nitrilomethanylylidene)]diphenolate ligand, and one Cl(−) anion further coordinates to the Cu(II) cation to complete the d...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344333/ https://www.ncbi.nlm.nih.gov/pubmed/22590099 http://dx.doi.org/10.1107/S1600536812014523 |
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author | Wang, Yan Zhang, Qian Yan, Peng-Fei Hou, Guang-Feng Li, Hong-Feng |
author_facet | Wang, Yan Zhang, Qian Yan, Peng-Fei Hou, Guang-Feng Li, Hong-Feng |
author_sort | Wang, Yan |
collection | PubMed |
description | In the title hetero-dinuclear complex, [CuSm(C(22)H(24)N(2)O(4))Cl(3)(CH(3)OH)(2)], the Cu(II) cation is N,N′,O,O′-chelated by a 6,6′-dimethoxy-2,2′-[cyclohexane-1,2-diylbis(nitrilomethanylylidene)]diphenolate ligand, and one Cl(−) anion further coordinates to the Cu(II) cation to complete the distorted square-pyramidal coordination geometry, while the Sm(III) cation is chelated by four O atoms from the same ligand, and is further coordinated by two methanol molecules and two Cl(−) anions in an bicapped trigonal–prismatic geometry. Intra- and intermolecular O—H⋯Cl hydrogen bonds are present in the structure. |
format | Online Article Text |
id | pubmed-3344333 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33443332012-05-15 Trichlorido{μ-6,6′-dimethoxy-2,2′-[cyclohexane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}dimethanolcopper(II)samarium(III) Wang, Yan Zhang, Qian Yan, Peng-Fei Hou, Guang-Feng Li, Hong-Feng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title hetero-dinuclear complex, [CuSm(C(22)H(24)N(2)O(4))Cl(3)(CH(3)OH)(2)], the Cu(II) cation is N,N′,O,O′-chelated by a 6,6′-dimethoxy-2,2′-[cyclohexane-1,2-diylbis(nitrilomethanylylidene)]diphenolate ligand, and one Cl(−) anion further coordinates to the Cu(II) cation to complete the distorted square-pyramidal coordination geometry, while the Sm(III) cation is chelated by four O atoms from the same ligand, and is further coordinated by two methanol molecules and two Cl(−) anions in an bicapped trigonal–prismatic geometry. Intra- and intermolecular O—H⋯Cl hydrogen bonds are present in the structure. International Union of Crystallography 2012-04-13 /pmc/articles/PMC3344333/ /pubmed/22590099 http://dx.doi.org/10.1107/S1600536812014523 Text en © Wang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Yan Zhang, Qian Yan, Peng-Fei Hou, Guang-Feng Li, Hong-Feng Trichlorido{μ-6,6′-dimethoxy-2,2′-[cyclohexane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}dimethanolcopper(II)samarium(III) |
title | Trichlorido{μ-6,6′-dimethoxy-2,2′-[cyclohexane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}dimethanolcopper(II)samarium(III) |
title_full | Trichlorido{μ-6,6′-dimethoxy-2,2′-[cyclohexane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}dimethanolcopper(II)samarium(III) |
title_fullStr | Trichlorido{μ-6,6′-dimethoxy-2,2′-[cyclohexane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}dimethanolcopper(II)samarium(III) |
title_full_unstemmed | Trichlorido{μ-6,6′-dimethoxy-2,2′-[cyclohexane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}dimethanolcopper(II)samarium(III) |
title_short | Trichlorido{μ-6,6′-dimethoxy-2,2′-[cyclohexane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}dimethanolcopper(II)samarium(III) |
title_sort | trichlorido{μ-6,6′-dimethoxy-2,2′-[cyclohexane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}dimethanolcopper(ii)samarium(iii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344333/ https://www.ncbi.nlm.nih.gov/pubmed/22590099 http://dx.doi.org/10.1107/S1600536812014523 |
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