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Trichlorido{μ-6,6′-dimeth­oxy-2,2′-[cyclo­hexane-1,2-diylbis(nitrilo­methanylyl­idene)]diphenolato}dimethano­l­copper(II)samarium(III)

In the title hetero-dinuclear complex, [CuSm(C(22)H(24)N(2)O(4))Cl(3)(CH(3)OH)(2)], the Cu(II) cation is N,N′,O,O′-chelated by a 6,6′-dimeth­oxy-2,2′-[cyclo­hexane-1,2-diylbis(nitrilo­methanylyl­idene)]diphenolate ligand, and one Cl(−) anion further coordinates to the Cu(II) cation to complete the d...

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Detalles Bibliográficos
Autores principales: Wang, Yan, Zhang, Qian, Yan, Peng-Fei, Hou, Guang-Feng, Li, Hong-Feng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344333/
https://www.ncbi.nlm.nih.gov/pubmed/22590099
http://dx.doi.org/10.1107/S1600536812014523
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author Wang, Yan
Zhang, Qian
Yan, Peng-Fei
Hou, Guang-Feng
Li, Hong-Feng
author_facet Wang, Yan
Zhang, Qian
Yan, Peng-Fei
Hou, Guang-Feng
Li, Hong-Feng
author_sort Wang, Yan
collection PubMed
description In the title hetero-dinuclear complex, [CuSm(C(22)H(24)N(2)O(4))Cl(3)(CH(3)OH)(2)], the Cu(II) cation is N,N′,O,O′-chelated by a 6,6′-dimeth­oxy-2,2′-[cyclo­hexane-1,2-diylbis(nitrilo­methanylyl­idene)]diphenolate ligand, and one Cl(−) anion further coordinates to the Cu(II) cation to complete the distorted square-pyramidal coordination geometry, while the Sm(III) cation is chelated by four O atoms from the same ligand, and is further coordinated by two methanol mol­ecules and two Cl(−) anions in an bicapped trigonal–prismatic geometry. Intra- and inter­molecular O—H⋯Cl hydrogen bonds are present in the structure.
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spelling pubmed-33443332012-05-15 Trichlorido{μ-6,6′-dimeth­oxy-2,2′-[cyclo­hexane-1,2-diylbis(nitrilo­methanylyl­idene)]diphenolato}dimethano­l­copper(II)samarium(III) Wang, Yan Zhang, Qian Yan, Peng-Fei Hou, Guang-Feng Li, Hong-Feng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title hetero-dinuclear complex, [CuSm(C(22)H(24)N(2)O(4))Cl(3)(CH(3)OH)(2)], the Cu(II) cation is N,N′,O,O′-chelated by a 6,6′-dimeth­oxy-2,2′-[cyclo­hexane-1,2-diylbis(nitrilo­methanylyl­idene)]diphenolate ligand, and one Cl(−) anion further coordinates to the Cu(II) cation to complete the distorted square-pyramidal coordination geometry, while the Sm(III) cation is chelated by four O atoms from the same ligand, and is further coordinated by two methanol mol­ecules and two Cl(−) anions in an bicapped trigonal–prismatic geometry. Intra- and inter­molecular O—H⋯Cl hydrogen bonds are present in the structure. International Union of Crystallography 2012-04-13 /pmc/articles/PMC3344333/ /pubmed/22590099 http://dx.doi.org/10.1107/S1600536812014523 Text en © Wang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Yan
Zhang, Qian
Yan, Peng-Fei
Hou, Guang-Feng
Li, Hong-Feng
Trichlorido{μ-6,6′-dimeth­oxy-2,2′-[cyclo­hexane-1,2-diylbis(nitrilo­methanylyl­idene)]diphenolato}dimethano­l­copper(II)samarium(III)
title Trichlorido{μ-6,6′-dimeth­oxy-2,2′-[cyclo­hexane-1,2-diylbis(nitrilo­methanylyl­idene)]diphenolato}dimethano­l­copper(II)samarium(III)
title_full Trichlorido{μ-6,6′-dimeth­oxy-2,2′-[cyclo­hexane-1,2-diylbis(nitrilo­methanylyl­idene)]diphenolato}dimethano­l­copper(II)samarium(III)
title_fullStr Trichlorido{μ-6,6′-dimeth­oxy-2,2′-[cyclo­hexane-1,2-diylbis(nitrilo­methanylyl­idene)]diphenolato}dimethano­l­copper(II)samarium(III)
title_full_unstemmed Trichlorido{μ-6,6′-dimeth­oxy-2,2′-[cyclo­hexane-1,2-diylbis(nitrilo­methanylyl­idene)]diphenolato}dimethano­l­copper(II)samarium(III)
title_short Trichlorido{μ-6,6′-dimeth­oxy-2,2′-[cyclo­hexane-1,2-diylbis(nitrilo­methanylyl­idene)]diphenolato}dimethano­l­copper(II)samarium(III)
title_sort trichlorido{μ-6,6′-dimeth­oxy-2,2′-[cyclo­hexane-1,2-diylbis(nitrilo­methanylyl­idene)]diphenolato}dimethano­l­copper(ii)samarium(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344333/
https://www.ncbi.nlm.nih.gov/pubmed/22590099
http://dx.doi.org/10.1107/S1600536812014523
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