Chlorido[1-phenyl-3-(2,3,5,6-tetra­methyl­benz­yl)benzimidazol-2-yl­idene]silver(I)

In the title compound, [AgCl(C(24)H(24)N(2))], the terminal phenyl and tetra­methyl­benzene rings [which form a dihedral angle of 87.92 (14)°] make dihedral angles of 59.59 (11) and 83.19 (12)° with respect to the central benzimidazole ring system. The Ag—C and Ag—Cl single-bond lengths are 2.087 (3...

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Autores principales: Akkurt, Mehmet, Akkoç, Senem, Gök, Yetkin, Dağdemir, Yılmaz, Tahir, Muhammad Nawaz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344334/
https://www.ncbi.nlm.nih.gov/pubmed/22590100
http://dx.doi.org/10.1107/S1600536812012998
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author Akkurt, Mehmet
Akkoç, Senem
Gök, Yetkin
Dağdemir, Yılmaz
Tahir, Muhammad Nawaz
author_facet Akkurt, Mehmet
Akkoç, Senem
Gök, Yetkin
Dağdemir, Yılmaz
Tahir, Muhammad Nawaz
author_sort Akkurt, Mehmet
collection PubMed
description In the title compound, [AgCl(C(24)H(24)N(2))], the terminal phenyl and tetra­methyl­benzene rings [which form a dihedral angle of 87.92 (14)°] make dihedral angles of 59.59 (11) and 83.19 (12)° with respect to the central benzimidazole ring system. The Ag—C and Ag—Cl single-bond lengths are 2.087 (3) and 2.3267 (9) Å. The C—Ag—Cl bond angle is 172.84 (7)°. C—H⋯π inter­actions contribute to the stabilization of the crystal structure. A very weak π–π stacking inter­action between adjacent tetra­methyl­benzene rings [centroid–centroid distance = 4.0610 (18) Å] is also observed.
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spelling pubmed-33443342012-05-15 Chlorido[1-phenyl-3-(2,3,5,6-tetra­methyl­benz­yl)benzimidazol-2-yl­idene]silver(I) Akkurt, Mehmet Akkoç, Senem Gök, Yetkin Dağdemir, Yılmaz Tahir, Muhammad Nawaz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [AgCl(C(24)H(24)N(2))], the terminal phenyl and tetra­methyl­benzene rings [which form a dihedral angle of 87.92 (14)°] make dihedral angles of 59.59 (11) and 83.19 (12)° with respect to the central benzimidazole ring system. The Ag—C and Ag—Cl single-bond lengths are 2.087 (3) and 2.3267 (9) Å. The C—Ag—Cl bond angle is 172.84 (7)°. C—H⋯π inter­actions contribute to the stabilization of the crystal structure. A very weak π–π stacking inter­action between adjacent tetra­methyl­benzene rings [centroid–centroid distance = 4.0610 (18) Å] is also observed. International Union of Crystallography 2012-04-13 /pmc/articles/PMC3344334/ /pubmed/22590100 http://dx.doi.org/10.1107/S1600536812012998 Text en © Akkurt et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Akkurt, Mehmet
Akkoç, Senem
Gök, Yetkin
Dağdemir, Yılmaz
Tahir, Muhammad Nawaz
Chlorido[1-phenyl-3-(2,3,5,6-tetra­methyl­benz­yl)benzimidazol-2-yl­idene]silver(I)
title Chlorido[1-phenyl-3-(2,3,5,6-tetra­methyl­benz­yl)benzimidazol-2-yl­idene]silver(I)
title_full Chlorido[1-phenyl-3-(2,3,5,6-tetra­methyl­benz­yl)benzimidazol-2-yl­idene]silver(I)
title_fullStr Chlorido[1-phenyl-3-(2,3,5,6-tetra­methyl­benz­yl)benzimidazol-2-yl­idene]silver(I)
title_full_unstemmed Chlorido[1-phenyl-3-(2,3,5,6-tetra­methyl­benz­yl)benzimidazol-2-yl­idene]silver(I)
title_short Chlorido[1-phenyl-3-(2,3,5,6-tetra­methyl­benz­yl)benzimidazol-2-yl­idene]silver(I)
title_sort chlorido[1-phenyl-3-(2,3,5,6-tetra­methyl­benz­yl)benzimidazol-2-yl­idene]silver(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344334/
https://www.ncbi.nlm.nih.gov/pubmed/22590100
http://dx.doi.org/10.1107/S1600536812012998
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