trans-Dichloridobis(2,4-dimethyl­aniline-κN)palladium(II)

In the title compound, [PdCl(2)(C(8)H(11)N)(2)], the Pd(II) atom is located on a crystallographic inversion center and adopts a square-planar coordination geometry, with pairs of equivalent ligands in trans positions. In the crystal, adjacent mol­ecules are linked with each other through weak N—H⋯Cl...

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Detalles Bibliográficos
Autores principales: Pan, Yong, Guo, Hai-Fu, Ma, De-Yun, Lu, Kuan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344335/
https://www.ncbi.nlm.nih.gov/pubmed/22590101
http://dx.doi.org/10.1107/S1600536812015279
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author Pan, Yong
Guo, Hai-Fu
Ma, De-Yun
Lu, Kuan
author_facet Pan, Yong
Guo, Hai-Fu
Ma, De-Yun
Lu, Kuan
author_sort Pan, Yong
collection PubMed
description In the title compound, [PdCl(2)(C(8)H(11)N)(2)], the Pd(II) atom is located on a crystallographic inversion center and adopts a square-planar coordination geometry, with pairs of equivalent ligands in trans positions. In the crystal, adjacent mol­ecules are linked with each other through weak N—H⋯Cl hydrogen bonds and π–π stacking inter­actions between the phenyl rings [shortest centroid–centroid distance = 3.720 (2) Å], leading to the formation of layers parallel to the a-axis direction.
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spelling pubmed-33443352012-05-15 trans-Dichloridobis(2,4-dimethyl­aniline-κN)palladium(II) Pan, Yong Guo, Hai-Fu Ma, De-Yun Lu, Kuan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [PdCl(2)(C(8)H(11)N)(2)], the Pd(II) atom is located on a crystallographic inversion center and adopts a square-planar coordination geometry, with pairs of equivalent ligands in trans positions. In the crystal, adjacent mol­ecules are linked with each other through weak N—H⋯Cl hydrogen bonds and π–π stacking inter­actions between the phenyl rings [shortest centroid–centroid distance = 3.720 (2) Å], leading to the formation of layers parallel to the a-axis direction. International Union of Crystallography 2012-04-13 /pmc/articles/PMC3344335/ /pubmed/22590101 http://dx.doi.org/10.1107/S1600536812015279 Text en © Pan et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Pan, Yong
Guo, Hai-Fu
Ma, De-Yun
Lu, Kuan
trans-Dichloridobis(2,4-dimethyl­aniline-κN)palladium(II)
title trans-Dichloridobis(2,4-dimethyl­aniline-κN)palladium(II)
title_full trans-Dichloridobis(2,4-dimethyl­aniline-κN)palladium(II)
title_fullStr trans-Dichloridobis(2,4-dimethyl­aniline-κN)palladium(II)
title_full_unstemmed trans-Dichloridobis(2,4-dimethyl­aniline-κN)palladium(II)
title_short trans-Dichloridobis(2,4-dimethyl­aniline-κN)palladium(II)
title_sort trans-dichloridobis(2,4-dimethyl­aniline-κn)palladium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344335/
https://www.ncbi.nlm.nih.gov/pubmed/22590101
http://dx.doi.org/10.1107/S1600536812015279
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AT lukuan transdichloridobis24dimethylanilineknpalladiumii

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