Poly[[bis­[3-(1H-tetra­zol-1-yl)propanoic acid-κN (4)]cadmium]-di-μ-thio­cyanato-κ(2) N:S;κ(2) S:N]

In the title compound, [Cd(NCS)(2)(C(4)H(6)N(4)O(2))(2)](n), the Cd(II) cation is located on an inversion center and is coordinated by two N and two S atoms from four SCN(−) anions and two N atoms from two 3-(1H-tetra­zol-1-yl)propanoic acid (Htzp) ligands in a distorted octa­hedral geometry. The SC...

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Detalles Bibliográficos
Autores principales: Wang, Jian-Guo, Zhang, Yuan, Su, Zhong-Xing, Liu, Xiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344336/
https://www.ncbi.nlm.nih.gov/pubmed/22590102
http://dx.doi.org/10.1107/S1600536812014730
Descripción
Sumario:In the title compound, [Cd(NCS)(2)(C(4)H(6)N(4)O(2))(2)](n), the Cd(II) cation is located on an inversion center and is coordinated by two N and two S atoms from four SCN(−) anions and two N atoms from two 3-(1H-tetra­zol-1-yl)propanoic acid (Htzp) ligands in a distorted octa­hedral geometry. The SCN(−) anions bridge the Cd(II) cations into a layer structure parallel to (100). A weak intra­molecular C—H⋯N inter­action occurs. The layers are further assembled into a three-dimensional supra­molecular structure via classical O—H⋯O hydrogen bonds.

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