Poly[[bis­[3-(1H-tetra­zol-1-yl)propanoic acid-κN (4)]cadmium]-di-μ-thio­cyanato-κ(2) N:S;κ(2) S:N]

In the title compound, [Cd(NCS)(2)(C(4)H(6)N(4)O(2))(2)](n), the Cd(II) cation is located on an inversion center and is coordinated by two N and two S atoms from four SCN(−) anions and two N atoms from two 3-(1H-tetra­zol-1-yl)propanoic acid (Htzp) ligands in a distorted octa­hedral geometry. The SC...

Descripción completa

Detalles Bibliográficos
Autores principales: Wang, Jian-Guo, Zhang, Yuan, Su, Zhong-Xing, Liu, Xiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344336/
https://www.ncbi.nlm.nih.gov/pubmed/22590102
http://dx.doi.org/10.1107/S1600536812014730
_version_ 1782231969498660864
author Wang, Jian-Guo
Zhang, Yuan
Su, Zhong-Xing
Liu, Xiang
author_facet Wang, Jian-Guo
Zhang, Yuan
Su, Zhong-Xing
Liu, Xiang
author_sort Wang, Jian-Guo
collection PubMed
description In the title compound, [Cd(NCS)(2)(C(4)H(6)N(4)O(2))(2)](n), the Cd(II) cation is located on an inversion center and is coordinated by two N and two S atoms from four SCN(−) anions and two N atoms from two 3-(1H-tetra­zol-1-yl)propanoic acid (Htzp) ligands in a distorted octa­hedral geometry. The SCN(−) anions bridge the Cd(II) cations into a layer structure parallel to (100). A weak intra­molecular C—H⋯N inter­action occurs. The layers are further assembled into a three-dimensional supra­molecular structure via classical O—H⋯O hydrogen bonds.
format Online
Article
Text
id pubmed-3344336
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-33443362012-05-15 Poly[[bis­[3-(1H-tetra­zol-1-yl)propanoic acid-κN (4)]cadmium]-di-μ-thio­cyanato-κ(2) N:S;κ(2) S:N] Wang, Jian-Guo Zhang, Yuan Su, Zhong-Xing Liu, Xiang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(NCS)(2)(C(4)H(6)N(4)O(2))(2)](n), the Cd(II) cation is located on an inversion center and is coordinated by two N and two S atoms from four SCN(−) anions and two N atoms from two 3-(1H-tetra­zol-1-yl)propanoic acid (Htzp) ligands in a distorted octa­hedral geometry. The SCN(−) anions bridge the Cd(II) cations into a layer structure parallel to (100). A weak intra­molecular C—H⋯N inter­action occurs. The layers are further assembled into a three-dimensional supra­molecular structure via classical O—H⋯O hydrogen bonds. International Union of Crystallography 2012-04-13 /pmc/articles/PMC3344336/ /pubmed/22590102 http://dx.doi.org/10.1107/S1600536812014730 Text en © Wang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Jian-Guo
Zhang, Yuan
Su, Zhong-Xing
Liu, Xiang
Poly[[bis­[3-(1H-tetra­zol-1-yl)propanoic acid-κN (4)]cadmium]-di-μ-thio­cyanato-κ(2) N:S;κ(2) S:N]
title Poly[[bis­[3-(1H-tetra­zol-1-yl)propanoic acid-κN (4)]cadmium]-di-μ-thio­cyanato-κ(2) N:S;κ(2) S:N]
title_full Poly[[bis­[3-(1H-tetra­zol-1-yl)propanoic acid-κN (4)]cadmium]-di-μ-thio­cyanato-κ(2) N:S;κ(2) S:N]
title_fullStr Poly[[bis­[3-(1H-tetra­zol-1-yl)propanoic acid-κN (4)]cadmium]-di-μ-thio­cyanato-κ(2) N:S;κ(2) S:N]
title_full_unstemmed Poly[[bis­[3-(1H-tetra­zol-1-yl)propanoic acid-κN (4)]cadmium]-di-μ-thio­cyanato-κ(2) N:S;κ(2) S:N]
title_short Poly[[bis­[3-(1H-tetra­zol-1-yl)propanoic acid-κN (4)]cadmium]-di-μ-thio­cyanato-κ(2) N:S;κ(2) S:N]
title_sort poly[[bis­[3-(1h-tetra­zol-1-yl)propanoic acid-κn (4)]cadmium]-di-μ-thio­cyanato-κ(2) n:s;κ(2) s:n]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344336/
https://www.ncbi.nlm.nih.gov/pubmed/22590102
http://dx.doi.org/10.1107/S1600536812014730
work_keys_str_mv AT wangjianguo polybis31htetrazol1ylpropanoicacidkn4cadmiumdimthiocyanatok2nsk2sn
AT zhangyuan polybis31htetrazol1ylpropanoicacidkn4cadmiumdimthiocyanatok2nsk2sn
AT suzhongxing polybis31htetrazol1ylpropanoicacidkn4cadmiumdimthiocyanatok2nsk2sn
AT liuxiang polybis31htetrazol1ylpropanoicacidkn4cadmiumdimthiocyanatok2nsk2sn

Ejemplares similares