catena-Poly[(aqua­dimethano­lzinc)-μ-furan-2,5-dicarboxyl­ato-κ(3) O (2):O (2),O (2′)]

In the crystal structure of the title compound, [Zn(C(6)H(2)O(5))(CH(3)OH)(2)(H(2)O)](n), an infinite chain is formed along the b axis by linking of the Zn(OH(2))(CH(3)OH)(2) unit with one carboxyl­ate group of the furan-2,5-dicarboxyl­ate ligand. The Zn(II) ion is in a distorted octa­hedral environ...

Descripción completa

Detalles Bibliográficos
Autores principales: Li, Ya-Feng, Gao, Yue, Xu, Yue, Qin, Xiao-Lin, Gao, Wen-Yuan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344337/
https://www.ncbi.nlm.nih.gov/pubmed/22590103
http://dx.doi.org/10.1107/S1600536812014936
Descripción
Sumario:In the crystal structure of the title compound, [Zn(C(6)H(2)O(5))(CH(3)OH)(2)(H(2)O)](n), an infinite chain is formed along the b axis by linking of the Zn(OH(2))(CH(3)OH)(2) unit with one carboxyl­ate group of the furan-2,5-dicarboxyl­ate ligand. The Zn(II) ion is in a distorted octa­hedral environment with one weak coordination [Zn—O(carboxyl­ate) = 2.565 (3) Å] and two meth­anol mol­ecules located in axial positions. In the chain, O(water)—H⋯O hydrogen bonds are present, while adjacent chains are linked by O(methanol)—H⋯O hydrogen bonds into a layer parallel to (10-2).

Ejemplares similares