Bis{2-[(4-chloro­phen­yl)imino­meth­yl]pyrrol-1-ido-κ(2) N,N′}bis­(dimethyl­amido-κN)titanium(IV) toluene monosolvate

The mononuclear title compound, [Ti(C(11)H(8)ClN(2))(2)(C(2)H(6)N)(2)]·C(7)H(8), was synthesized by the reaction of N-(4-chloro­phen­yl)-2-pyrrolylcarbaldimine with Ti(C(2)H(6)N)(4). The Ti(IV) ion is situated on a twofold rotation axis and displays a distorted octa­hedral geometry defined by four N atoms from two 2-[(4-chloro­phen­yl)imino­meth­yl]pyrrol-1-ide ligands and two N atoms from two dimethyl­amine ligands. The Ti—N(pyrrole) bond length [2.1041 (19) Å] is longer than the Ti—N(dimethyl­amine) bond length [1.9013 (19) Å]; the imine N atom exhibits the longest Ti—N bond [2.3152 (17) Å]. The toluene solvent mol­ecule is located on a twofold rotation axis running through the C atom of the methyl group. Consequently, the H atoms of the latter are rotationally disordered. The compound contains no markable hydrogen-bonding inter­actions.