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catena-Poly[[[tetra­aqua­copper(II)]-μ-4,4′-bipyridyl-κ(2) N:N′] tetra­fluorido­succinate tetra­hydrate]

In the title compound, {[Cu(C(10)H(8)N(2))(H(2)O)(4)](C(4)F(4)O(4))·4H(2)O}(n), the Cu(II) atom adopts an elongated octa­hedral geometry because of the Jahn–Teller effect. Both cation and anion have crystallographic twofold rotation symmetry with the twofold axes passing through the Cu and N atoms a...

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Detalles Bibliográficos
Autores principales: Yu, Guo-Jun, Xu, Lan-Ping, Qin, Lan, Han, Lei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344339/
https://www.ncbi.nlm.nih.gov/pubmed/22590105
http://dx.doi.org/10.1107/S1600536812014948
Descripción
Sumario:In the title compound, {[Cu(C(10)H(8)N(2))(H(2)O)(4)](C(4)F(4)O(4))·4H(2)O}(n), the Cu(II) atom adopts an elongated octa­hedral geometry because of the Jahn–Teller effect. Both cation and anion have crystallographic twofold rotation symmetry with the twofold axes passing through the Cu and N atoms and through the midpoint of the central C—C bond. The 4,4′-bipyridyl ligand links the Cu(II) atoms into a linear chain along the b axis. O—H⋯O hydrogen-bonding inter­actions between the cationic chains and the tetra­fluorido­succinate anions and the free water mol­ecules generate a three-dimensional supra­molecular network.