Cargando…
catena-Poly[[[tetraaquacopper(II)]-μ-4,4′-bipyridyl-κ(2) N:N′] tetrafluoridosuccinate tetrahydrate]
In the title compound, {[Cu(C(10)H(8)N(2))(H(2)O)(4)](C(4)F(4)O(4))·4H(2)O}(n), the Cu(II) atom adopts an elongated octahedral geometry because of the Jahn–Teller effect. Both cation and anion have crystallographic twofold rotation symmetry with the twofold axes passing through the Cu and N atoms a...
Autores principales: | , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344339/ https://www.ncbi.nlm.nih.gov/pubmed/22590105 http://dx.doi.org/10.1107/S1600536812014948 |
_version_ | 1782231970167652352 |
---|---|
author | Yu, Guo-Jun Xu, Lan-Ping Qin, Lan Han, Lei |
author_facet | Yu, Guo-Jun Xu, Lan-Ping Qin, Lan Han, Lei |
author_sort | Yu, Guo-Jun |
collection | PubMed |
description | In the title compound, {[Cu(C(10)H(8)N(2))(H(2)O)(4)](C(4)F(4)O(4))·4H(2)O}(n), the Cu(II) atom adopts an elongated octahedral geometry because of the Jahn–Teller effect. Both cation and anion have crystallographic twofold rotation symmetry with the twofold axes passing through the Cu and N atoms and through the midpoint of the central C—C bond. The 4,4′-bipyridyl ligand links the Cu(II) atoms into a linear chain along the b axis. O—H⋯O hydrogen-bonding interactions between the cationic chains and the tetrafluoridosuccinate anions and the free water molecules generate a three-dimensional supramolecular network. |
format | Online Article Text |
id | pubmed-3344339 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33443392012-05-15 catena-Poly[[[tetraaquacopper(II)]-μ-4,4′-bipyridyl-κ(2) N:N′] tetrafluoridosuccinate tetrahydrate] Yu, Guo-Jun Xu, Lan-Ping Qin, Lan Han, Lei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Cu(C(10)H(8)N(2))(H(2)O)(4)](C(4)F(4)O(4))·4H(2)O}(n), the Cu(II) atom adopts an elongated octahedral geometry because of the Jahn–Teller effect. Both cation and anion have crystallographic twofold rotation symmetry with the twofold axes passing through the Cu and N atoms and through the midpoint of the central C—C bond. The 4,4′-bipyridyl ligand links the Cu(II) atoms into a linear chain along the b axis. O—H⋯O hydrogen-bonding interactions between the cationic chains and the tetrafluoridosuccinate anions and the free water molecules generate a three-dimensional supramolecular network. International Union of Crystallography 2012-04-18 /pmc/articles/PMC3344339/ /pubmed/22590105 http://dx.doi.org/10.1107/S1600536812014948 Text en © Yu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Yu, Guo-Jun Xu, Lan-Ping Qin, Lan Han, Lei catena-Poly[[[tetraaquacopper(II)]-μ-4,4′-bipyridyl-κ(2) N:N′] tetrafluoridosuccinate tetrahydrate] |
title |
catena-Poly[[[tetraaquacopper(II)]-μ-4,4′-bipyridyl-κ(2)
N:N′] tetrafluoridosuccinate tetrahydrate] |
title_full |
catena-Poly[[[tetraaquacopper(II)]-μ-4,4′-bipyridyl-κ(2)
N:N′] tetrafluoridosuccinate tetrahydrate] |
title_fullStr |
catena-Poly[[[tetraaquacopper(II)]-μ-4,4′-bipyridyl-κ(2)
N:N′] tetrafluoridosuccinate tetrahydrate] |
title_full_unstemmed |
catena-Poly[[[tetraaquacopper(II)]-μ-4,4′-bipyridyl-κ(2)
N:N′] tetrafluoridosuccinate tetrahydrate] |
title_short |
catena-Poly[[[tetraaquacopper(II)]-μ-4,4′-bipyridyl-κ(2)
N:N′] tetrafluoridosuccinate tetrahydrate] |
title_sort | catena-poly[[[tetraaquacopper(ii)]-μ-4,4′-bipyridyl-κ(2)
n:n′] tetrafluoridosuccinate tetrahydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344339/ https://www.ncbi.nlm.nih.gov/pubmed/22590105 http://dx.doi.org/10.1107/S1600536812014948 |
work_keys_str_mv | AT yuguojun catenapolytetraaquacopperiim44bipyridylk2nntetrafluoridosuccinatetetrahydrate AT xulanping catenapolytetraaquacopperiim44bipyridylk2nntetrafluoridosuccinatetetrahydrate AT qinlan catenapolytetraaquacopperiim44bipyridylk2nntetrafluoridosuccinatetetrahydrate AT hanlei catenapolytetraaquacopperiim44bipyridylk2nntetrafluoridosuccinatetetrahydrate |