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catena-Poly[[[tetra­aqua­copper(II)]-μ-4,4′-bipyridyl-κ(2) N:N′] tetra­fluorido­succinate tetra­hydrate]

In the title compound, {[Cu(C(10)H(8)N(2))(H(2)O)(4)](C(4)F(4)O(4))·4H(2)O}(n), the Cu(II) atom adopts an elongated octa­hedral geometry because of the Jahn–Teller effect. Both cation and anion have crystallographic twofold rotation symmetry with the twofold axes passing through the Cu and N atoms a...

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Detalles Bibliográficos
Autores principales: Yu, Guo-Jun, Xu, Lan-Ping, Qin, Lan, Han, Lei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344339/
https://www.ncbi.nlm.nih.gov/pubmed/22590105
http://dx.doi.org/10.1107/S1600536812014948
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author Yu, Guo-Jun
Xu, Lan-Ping
Qin, Lan
Han, Lei
author_facet Yu, Guo-Jun
Xu, Lan-Ping
Qin, Lan
Han, Lei
author_sort Yu, Guo-Jun
collection PubMed
description In the title compound, {[Cu(C(10)H(8)N(2))(H(2)O)(4)](C(4)F(4)O(4))·4H(2)O}(n), the Cu(II) atom adopts an elongated octa­hedral geometry because of the Jahn–Teller effect. Both cation and anion have crystallographic twofold rotation symmetry with the twofold axes passing through the Cu and N atoms and through the midpoint of the central C—C bond. The 4,4′-bipyridyl ligand links the Cu(II) atoms into a linear chain along the b axis. O—H⋯O hydrogen-bonding inter­actions between the cationic chains and the tetra­fluorido­succinate anions and the free water mol­ecules generate a three-dimensional supra­molecular network.
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spelling pubmed-33443392012-05-15 catena-Poly[[[tetra­aqua­copper(II)]-μ-4,4′-bipyridyl-κ(2) N:N′] tetra­fluorido­succinate tetra­hydrate] Yu, Guo-Jun Xu, Lan-Ping Qin, Lan Han, Lei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Cu(C(10)H(8)N(2))(H(2)O)(4)](C(4)F(4)O(4))·4H(2)O}(n), the Cu(II) atom adopts an elongated octa­hedral geometry because of the Jahn–Teller effect. Both cation and anion have crystallographic twofold rotation symmetry with the twofold axes passing through the Cu and N atoms and through the midpoint of the central C—C bond. The 4,4′-bipyridyl ligand links the Cu(II) atoms into a linear chain along the b axis. O—H⋯O hydrogen-bonding inter­actions between the cationic chains and the tetra­fluorido­succinate anions and the free water mol­ecules generate a three-dimensional supra­molecular network. International Union of Crystallography 2012-04-18 /pmc/articles/PMC3344339/ /pubmed/22590105 http://dx.doi.org/10.1107/S1600536812014948 Text en © Yu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yu, Guo-Jun
Xu, Lan-Ping
Qin, Lan
Han, Lei
catena-Poly[[[tetra­aqua­copper(II)]-μ-4,4′-bipyridyl-κ(2) N:N′] tetra­fluorido­succinate tetra­hydrate]
title catena-Poly[[[tetra­aqua­copper(II)]-μ-4,4′-bipyridyl-κ(2) N:N′] tetra­fluorido­succinate tetra­hydrate]
title_full catena-Poly[[[tetra­aqua­copper(II)]-μ-4,4′-bipyridyl-κ(2) N:N′] tetra­fluorido­succinate tetra­hydrate]
title_fullStr catena-Poly[[[tetra­aqua­copper(II)]-μ-4,4′-bipyridyl-κ(2) N:N′] tetra­fluorido­succinate tetra­hydrate]
title_full_unstemmed catena-Poly[[[tetra­aqua­copper(II)]-μ-4,4′-bipyridyl-κ(2) N:N′] tetra­fluorido­succinate tetra­hydrate]
title_short catena-Poly[[[tetra­aqua­copper(II)]-μ-4,4′-bipyridyl-κ(2) N:N′] tetra­fluorido­succinate tetra­hydrate]
title_sort catena-poly[[[tetra­aqua­copper(ii)]-μ-4,4′-bipyridyl-κ(2) n:n′] tetra­fluorido­succinate tetra­hydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344339/
https://www.ncbi.nlm.nih.gov/pubmed/22590105
http://dx.doi.org/10.1107/S1600536812014948
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