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Bis(acetato-κO)bis[2-(pyridin-2-yl)ethanol-κ(2) N,O]copper(II)
The title compound, [Cu(CH(3)COO)(2)(C(7)H(9)NO)(2)], is a monomeric complex with an octahedral geometry. The Cu(II) atom is located on an inversion center and is coordinated by acetate and 2-(pyridin-2-yl)ethanol ligands. The acetate group is coordinated in a monodentate manner, while the 2-(pyrid...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344340/ https://www.ncbi.nlm.nih.gov/pubmed/22590106 http://dx.doi.org/10.1107/S1600536812015747 |
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author | Lapanje, Katja Leban, Ivan Lah, Nina |
author_facet | Lapanje, Katja Leban, Ivan Lah, Nina |
author_sort | Lapanje, Katja |
collection | PubMed |
description | The title compound, [Cu(CH(3)COO)(2)(C(7)H(9)NO)(2)], is a monomeric complex with an octahedral geometry. The Cu(II) atom is located on an inversion center and is coordinated by acetate and 2-(pyridin-2-yl)ethanol ligands. The acetate group is coordinated in a monodentate manner, while the 2-(pyridin-2-yl)ethanol is coordinated as a bidentate ligand involving the endocyclic N atom and the hydroxy O atom of the ligand side chain. An intramolecular hydrogen bond is observed between the hydroxy O atom and the non-coordinated acetate O atom. No classical intermolecular hydrogen-bond contacts were observed. However, the crystal packing is effected by C—H⋯O interactions, which link the mononuclear entities into layers parallel to the bc plane. |
format | Online Article Text |
id | pubmed-3344340 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33443402012-05-15 Bis(acetato-κO)bis[2-(pyridin-2-yl)ethanol-κ(2) N,O]copper(II) Lapanje, Katja Leban, Ivan Lah, Nina Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(CH(3)COO)(2)(C(7)H(9)NO)(2)], is a monomeric complex with an octahedral geometry. The Cu(II) atom is located on an inversion center and is coordinated by acetate and 2-(pyridin-2-yl)ethanol ligands. The acetate group is coordinated in a monodentate manner, while the 2-(pyridin-2-yl)ethanol is coordinated as a bidentate ligand involving the endocyclic N atom and the hydroxy O atom of the ligand side chain. An intramolecular hydrogen bond is observed between the hydroxy O atom and the non-coordinated acetate O atom. No classical intermolecular hydrogen-bond contacts were observed. However, the crystal packing is effected by C—H⋯O interactions, which link the mononuclear entities into layers parallel to the bc plane. International Union of Crystallography 2012-04-18 /pmc/articles/PMC3344340/ /pubmed/22590106 http://dx.doi.org/10.1107/S1600536812015747 Text en © Lapanje et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Lapanje, Katja Leban, Ivan Lah, Nina Bis(acetato-κO)bis[2-(pyridin-2-yl)ethanol-κ(2) N,O]copper(II) |
title | Bis(acetato-κO)bis[2-(pyridin-2-yl)ethanol-κ(2)
N,O]copper(II) |
title_full | Bis(acetato-κO)bis[2-(pyridin-2-yl)ethanol-κ(2)
N,O]copper(II) |
title_fullStr | Bis(acetato-κO)bis[2-(pyridin-2-yl)ethanol-κ(2)
N,O]copper(II) |
title_full_unstemmed | Bis(acetato-κO)bis[2-(pyridin-2-yl)ethanol-κ(2)
N,O]copper(II) |
title_short | Bis(acetato-κO)bis[2-(pyridin-2-yl)ethanol-κ(2)
N,O]copper(II) |
title_sort | bis(acetato-κo)bis[2-(pyridin-2-yl)ethanol-κ(2)
n,o]copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344340/ https://www.ncbi.nlm.nih.gov/pubmed/22590106 http://dx.doi.org/10.1107/S1600536812015747 |
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