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Bis(acetato-κO)bis­[2-(pyridin-2-yl)ethanol-κ(2) N,O]copper(II)

The title compound, [Cu(CH(3)COO)(2)(C(7)H(9)NO)(2)], is a monomeric complex with an octa­hedral geometry. The Cu(II) atom is located on an inversion center and is coordinated by acetate and 2-(pyridin-2-yl)ethanol ligands. The acetate group is coordinated in a monodentate manner, while the 2-(pyrid...

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Detalles Bibliográficos
Autores principales: Lapanje, Katja, Leban, Ivan, Lah, Nina
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344340/
https://www.ncbi.nlm.nih.gov/pubmed/22590106
http://dx.doi.org/10.1107/S1600536812015747
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author Lapanje, Katja
Leban, Ivan
Lah, Nina
author_facet Lapanje, Katja
Leban, Ivan
Lah, Nina
author_sort Lapanje, Katja
collection PubMed
description The title compound, [Cu(CH(3)COO)(2)(C(7)H(9)NO)(2)], is a monomeric complex with an octa­hedral geometry. The Cu(II) atom is located on an inversion center and is coordinated by acetate and 2-(pyridin-2-yl)ethanol ligands. The acetate group is coordinated in a monodentate manner, while the 2-(pyridin-2-yl)ethanol is coordinated as a bidentate ligand involving the endocyclic N atom and the hy­droxy O atom of the ligand side chain. An intra­molecular hydrogen bond is observed between the hy­droxy O atom and the non-coordinated acetate O atom. No classical inter­molecular hydrogen-bond contacts were observed. However, the crystal packing is effected by C—H⋯O inter­actions, which link the mononuclear entities into layers parallel to the bc plane.
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spelling pubmed-33443402012-05-15 Bis(acetato-κO)bis­[2-(pyridin-2-yl)ethanol-κ(2) N,O]copper(II) Lapanje, Katja Leban, Ivan Lah, Nina Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(CH(3)COO)(2)(C(7)H(9)NO)(2)], is a monomeric complex with an octa­hedral geometry. The Cu(II) atom is located on an inversion center and is coordinated by acetate and 2-(pyridin-2-yl)ethanol ligands. The acetate group is coordinated in a monodentate manner, while the 2-(pyridin-2-yl)ethanol is coordinated as a bidentate ligand involving the endocyclic N atom and the hy­droxy O atom of the ligand side chain. An intra­molecular hydrogen bond is observed between the hy­droxy O atom and the non-coordinated acetate O atom. No classical inter­molecular hydrogen-bond contacts were observed. However, the crystal packing is effected by C—H⋯O inter­actions, which link the mononuclear entities into layers parallel to the bc plane. International Union of Crystallography 2012-04-18 /pmc/articles/PMC3344340/ /pubmed/22590106 http://dx.doi.org/10.1107/S1600536812015747 Text en © Lapanje et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lapanje, Katja
Leban, Ivan
Lah, Nina
Bis(acetato-κO)bis­[2-(pyridin-2-yl)ethanol-κ(2) N,O]copper(II)
title Bis(acetato-κO)bis­[2-(pyridin-2-yl)ethanol-κ(2) N,O]copper(II)
title_full Bis(acetato-κO)bis­[2-(pyridin-2-yl)ethanol-κ(2) N,O]copper(II)
title_fullStr Bis(acetato-κO)bis­[2-(pyridin-2-yl)ethanol-κ(2) N,O]copper(II)
title_full_unstemmed Bis(acetato-κO)bis­[2-(pyridin-2-yl)ethanol-κ(2) N,O]copper(II)
title_short Bis(acetato-κO)bis­[2-(pyridin-2-yl)ethanol-κ(2) N,O]copper(II)
title_sort bis(acetato-κo)bis­[2-(pyridin-2-yl)ethanol-κ(2) n,o]copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344340/
https://www.ncbi.nlm.nih.gov/pubmed/22590106
http://dx.doi.org/10.1107/S1600536812015747
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