Diaqua­bis­[5-(pyrazin-2-yl-κN (1))-3-(pyridin-4-yl)-1H-1,2,4-triazol-1-ido-κN (1)]cobalt(II) methanol disolvate

The Co(II) ion in the title mononuclear compound, [Co(C(11)H(7)N(6))(2)(H(2)O)(2)]·2CH(3)OH, is located on an inversion center and is six-coordinated in a distorted octa­hedral geometry defined by four N atoms from two deprotonated 5-(pyrazin-2-yl-κN)-3-(pyridin-4-yl)-1H-1,2,4-triazol-1-ide (ppt) li...

Descripción completa

Detalles Bibliográficos
Autores principales: Bi, Yan, Wu, Na, Chen, Jing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344341/
https://www.ncbi.nlm.nih.gov/pubmed/22590107
http://dx.doi.org/10.1107/S160053681201495X
_version_ 1782231970630074368
author Bi, Yan
Wu, Na
Chen, Jing
author_facet Bi, Yan
Wu, Na
Chen, Jing
author_sort Bi, Yan
collection PubMed
description The Co(II) ion in the title mononuclear compound, [Co(C(11)H(7)N(6))(2)(H(2)O)(2)]·2CH(3)OH, is located on an inversion center and is six-coordinated in a distorted octa­hedral geometry defined by four N atoms from two deprotonated 5-(pyrazin-2-yl-κN)-3-(pyridin-4-yl)-1H-1,2,4-triazol-1-ide (ppt) ligands and two water mol­ecules. In the crystal, the complex mol­ecules and lattice methanol mol­ecules are linked via O—H⋯N and O—H⋯O hydrogen bonds, generating a two-dimensional supra­molecular network parallel to (001). π–π inter­actions between the triazole and pyrazine rings and between the pyridine rings are present [centroid–centroid distances = 3.686 (3) and 3.929 (4) Å, respectively].
format Online
Article
Text
id pubmed-3344341
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-33443412012-05-15 Diaqua­bis­[5-(pyrazin-2-yl-κN (1))-3-(pyridin-4-yl)-1H-1,2,4-triazol-1-ido-κN (1)]cobalt(II) methanol disolvate Bi, Yan Wu, Na Chen, Jing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Co(II) ion in the title mononuclear compound, [Co(C(11)H(7)N(6))(2)(H(2)O)(2)]·2CH(3)OH, is located on an inversion center and is six-coordinated in a distorted octa­hedral geometry defined by four N atoms from two deprotonated 5-(pyrazin-2-yl-κN)-3-(pyridin-4-yl)-1H-1,2,4-triazol-1-ide (ppt) ligands and two water mol­ecules. In the crystal, the complex mol­ecules and lattice methanol mol­ecules are linked via O—H⋯N and O—H⋯O hydrogen bonds, generating a two-dimensional supra­molecular network parallel to (001). π–π inter­actions between the triazole and pyrazine rings and between the pyridine rings are present [centroid–centroid distances = 3.686 (3) and 3.929 (4) Å, respectively]. International Union of Crystallography 2012-04-18 /pmc/articles/PMC3344341/ /pubmed/22590107 http://dx.doi.org/10.1107/S160053681201495X Text en © Bi et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Bi, Yan
Wu, Na
Chen, Jing
Diaqua­bis­[5-(pyrazin-2-yl-κN (1))-3-(pyridin-4-yl)-1H-1,2,4-triazol-1-ido-κN (1)]cobalt(II) methanol disolvate
title Diaqua­bis­[5-(pyrazin-2-yl-κN (1))-3-(pyridin-4-yl)-1H-1,2,4-triazol-1-ido-κN (1)]cobalt(II) methanol disolvate
title_full Diaqua­bis­[5-(pyrazin-2-yl-κN (1))-3-(pyridin-4-yl)-1H-1,2,4-triazol-1-ido-κN (1)]cobalt(II) methanol disolvate
title_fullStr Diaqua­bis­[5-(pyrazin-2-yl-κN (1))-3-(pyridin-4-yl)-1H-1,2,4-triazol-1-ido-κN (1)]cobalt(II) methanol disolvate
title_full_unstemmed Diaqua­bis­[5-(pyrazin-2-yl-κN (1))-3-(pyridin-4-yl)-1H-1,2,4-triazol-1-ido-κN (1)]cobalt(II) methanol disolvate
title_short Diaqua­bis­[5-(pyrazin-2-yl-κN (1))-3-(pyridin-4-yl)-1H-1,2,4-triazol-1-ido-κN (1)]cobalt(II) methanol disolvate
title_sort diaqua­bis­[5-(pyrazin-2-yl-κn (1))-3-(pyridin-4-yl)-1h-1,2,4-triazol-1-ido-κn (1)]cobalt(ii) methanol disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344341/
https://www.ncbi.nlm.nih.gov/pubmed/22590107
http://dx.doi.org/10.1107/S160053681201495X
work_keys_str_mv AT biyan diaquabis5pyrazin2ylkn13pyridin4yl1h124triazol1idokn1cobaltiimethanoldisolvate
AT wuna diaquabis5pyrazin2ylkn13pyridin4yl1h124triazol1idokn1cobaltiimethanoldisolvate
AT chenjing diaquabis5pyrazin2ylkn13pyridin4yl1h124triazol1idokn1cobaltiimethanoldisolvate

Ejemplares similares