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Carbonylbis(triphenylphosphane-κP)(η(2)-1-vinylpyrrolidin-2-one-κO)ruthenium(0)
The 1-vinylpyrrolidin-2-one ligand in the title compound, [Ru(C(6)H(9)NO)(C(18)H(15)P)(2)(CO)], coordinates to the Ru(0) atom with the olefin double bond and the ketone O atom. The Ru(0) atom adopts a distorted trigonal–bipyramidal coordination geometry, with the C O ligand and the ketone O atom oc...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344346/ https://www.ncbi.nlm.nih.gov/pubmed/22590112 http://dx.doi.org/10.1107/S1600536812014766 |
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author | Ma, Si Jia Niu, Po |
author_facet | Ma, Si Jia Niu, Po |
author_sort | Ma, Si Jia |
collection | PubMed |
description | The 1-vinylpyrrolidin-2-one ligand in the title compound, [Ru(C(6)H(9)NO)(C(18)H(15)P)(2)(CO)], coordinates to the Ru(0) atom with the olefin double bond and the ketone O atom. The Ru(0) atom adopts a distorted trigonal–bipyramidal coordination geometry, with the C O ligand and the ketone O atom occupying the axial positions. The two triphenylphosphane ligands are cis to each other. The olefinic C=C bond is almost coplanar with the Ru(0) atom and the two P atoms (maximum deviation of 0.0516 Å from the mean plane defined by the five constituent atoms). The coordinated C=C bond has a length of 1.449 (3) Å, which is significantly longer than that of a free C=C bond (1.34 Å). There are two C—H⋯π interactions involving neighbouring phenyl rings in the molecule. In the crystal, molecules are linked via two further C—H⋯π interactions. |
format | Online Article Text |
id | pubmed-3344346 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33443462012-05-15 Carbonylbis(triphenylphosphane-κP)(η(2)-1-vinylpyrrolidin-2-one-κO)ruthenium(0) Ma, Si Jia Niu, Po Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The 1-vinylpyrrolidin-2-one ligand in the title compound, [Ru(C(6)H(9)NO)(C(18)H(15)P)(2)(CO)], coordinates to the Ru(0) atom with the olefin double bond and the ketone O atom. The Ru(0) atom adopts a distorted trigonal–bipyramidal coordination geometry, with the C O ligand and the ketone O atom occupying the axial positions. The two triphenylphosphane ligands are cis to each other. The olefinic C=C bond is almost coplanar with the Ru(0) atom and the two P atoms (maximum deviation of 0.0516 Å from the mean plane defined by the five constituent atoms). The coordinated C=C bond has a length of 1.449 (3) Å, which is significantly longer than that of a free C=C bond (1.34 Å). There are two C—H⋯π interactions involving neighbouring phenyl rings in the molecule. In the crystal, molecules are linked via two further C—H⋯π interactions. International Union of Crystallography 2012-04-18 /pmc/articles/PMC3344346/ /pubmed/22590112 http://dx.doi.org/10.1107/S1600536812014766 Text en © Ma and Niu 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ma, Si Jia Niu, Po Carbonylbis(triphenylphosphane-κP)(η(2)-1-vinylpyrrolidin-2-one-κO)ruthenium(0) |
title | Carbonylbis(triphenylphosphane-κP)(η(2)-1-vinylpyrrolidin-2-one-κO)ruthenium(0) |
title_full | Carbonylbis(triphenylphosphane-κP)(η(2)-1-vinylpyrrolidin-2-one-κO)ruthenium(0) |
title_fullStr | Carbonylbis(triphenylphosphane-κP)(η(2)-1-vinylpyrrolidin-2-one-κO)ruthenium(0) |
title_full_unstemmed | Carbonylbis(triphenylphosphane-κP)(η(2)-1-vinylpyrrolidin-2-one-κO)ruthenium(0) |
title_short | Carbonylbis(triphenylphosphane-κP)(η(2)-1-vinylpyrrolidin-2-one-κO)ruthenium(0) |
title_sort | carbonylbis(triphenylphosphane-κp)(η(2)-1-vinylpyrrolidin-2-one-κo)ruthenium(0) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344346/ https://www.ncbi.nlm.nih.gov/pubmed/22590112 http://dx.doi.org/10.1107/S1600536812014766 |
work_keys_str_mv | AT masijia carbonylbistriphenylphosphanekpē21vinylpyrrolidin2onekoruthenium0 AT niupo carbonylbistriphenylphosphanekpē21vinylpyrrolidin2onekoruthenium0 |