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Carbonyl­bis­(triphenyl­phosphane-κP)(η(2)-1-vinyl­pyrrolidin-2-one-κO)ruthenium(0)

The 1-vinyl­pyrrolidin-2-one ligand in the title compound, [Ru(C(6)H(9)NO)(C(18)H(15)P)(2)(CO)], coordinates to the Ru(0) atom with the olefin double bond and the ketone O atom. The Ru(0) atom adopts a distorted trigonal–bipyramidal coordination geometry, with the C O ligand and the ketone O atom oc...

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Autores principales: Ma, Si Jia, Niu, Po
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344346/
https://www.ncbi.nlm.nih.gov/pubmed/22590112
http://dx.doi.org/10.1107/S1600536812014766
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author Ma, Si Jia
Niu, Po
author_facet Ma, Si Jia
Niu, Po
author_sort Ma, Si Jia
collection PubMed
description The 1-vinyl­pyrrolidin-2-one ligand in the title compound, [Ru(C(6)H(9)NO)(C(18)H(15)P)(2)(CO)], coordinates to the Ru(0) atom with the olefin double bond and the ketone O atom. The Ru(0) atom adopts a distorted trigonal–bipyramidal coordination geometry, with the C O ligand and the ketone O atom occupying the axial positions. The two triphenyl­phosphane ligands are cis to each other. The olefinic C=C bond is almost coplanar with the Ru(0) atom and the two P atoms (maximum deviation of 0.0516 Å from the mean plane defined by the five constituent atoms). The coordinated C=C bond has a length of 1.449 (3) Å, which is significantly longer than that of a free C=C bond (1.34 Å). There are two C—H⋯π inter­actions involving neighbouring phenyl rings in the mol­ecule. In the crystal, mol­ecules are linked via two further C—H⋯π inter­actions.
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spelling pubmed-33443462012-05-15 Carbonyl­bis­(triphenyl­phosphane-κP)(η(2)-1-vinyl­pyrrolidin-2-one-κO)ruthenium(0) Ma, Si Jia Niu, Po Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The 1-vinyl­pyrrolidin-2-one ligand in the title compound, [Ru(C(6)H(9)NO)(C(18)H(15)P)(2)(CO)], coordinates to the Ru(0) atom with the olefin double bond and the ketone O atom. The Ru(0) atom adopts a distorted trigonal–bipyramidal coordination geometry, with the C O ligand and the ketone O atom occupying the axial positions. The two triphenyl­phosphane ligands are cis to each other. The olefinic C=C bond is almost coplanar with the Ru(0) atom and the two P atoms (maximum deviation of 0.0516 Å from the mean plane defined by the five constituent atoms). The coordinated C=C bond has a length of 1.449 (3) Å, which is significantly longer than that of a free C=C bond (1.34 Å). There are two C—H⋯π inter­actions involving neighbouring phenyl rings in the mol­ecule. In the crystal, mol­ecules are linked via two further C—H⋯π inter­actions. International Union of Crystallography 2012-04-18 /pmc/articles/PMC3344346/ /pubmed/22590112 http://dx.doi.org/10.1107/S1600536812014766 Text en © Ma and Niu 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ma, Si Jia
Niu, Po
Carbonyl­bis­(triphenyl­phosphane-κP)(η(2)-1-vinyl­pyrrolidin-2-one-κO)ruthenium(0)
title Carbonyl­bis­(triphenyl­phosphane-κP)(η(2)-1-vinyl­pyrrolidin-2-one-κO)ruthenium(0)
title_full Carbonyl­bis­(triphenyl­phosphane-κP)(η(2)-1-vinyl­pyrrolidin-2-one-κO)ruthenium(0)
title_fullStr Carbonyl­bis­(triphenyl­phosphane-κP)(η(2)-1-vinyl­pyrrolidin-2-one-κO)ruthenium(0)
title_full_unstemmed Carbonyl­bis­(triphenyl­phosphane-κP)(η(2)-1-vinyl­pyrrolidin-2-one-κO)ruthenium(0)
title_short Carbonyl­bis­(triphenyl­phosphane-κP)(η(2)-1-vinyl­pyrrolidin-2-one-κO)ruthenium(0)
title_sort carbonyl­bis­(triphenyl­phosphane-κp)(η(2)-1-vinyl­pyrrolidin-2-one-κo)ruthenium(0)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344346/
https://www.ncbi.nlm.nih.gov/pubmed/22590112
http://dx.doi.org/10.1107/S1600536812014766
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