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(2,2′-Biquinoline-κ(2) N,N′)dibromidopalladium(II)

The Pd(II) ion in the title complex, [PdBr(2)(C(18)H(12)N(2))], is four-coordinated in a distorted square-planar environment by the two N atoms from the chelating 2,2′-biquinoline (Biqu) ligand and two mutually cis Br(−) anions. The Biqu ligand is not planar, the dihedral angle between the quinoline...

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Detalles Bibliográficos
Autor principal: Ha, Kwang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344352/
https://www.ncbi.nlm.nih.gov/pubmed/22590118
http://dx.doi.org/10.1107/S1600536812015425
Descripción
Sumario:The Pd(II) ion in the title complex, [PdBr(2)(C(18)H(12)N(2))], is four-coordinated in a distorted square-planar environment by the two N atoms from the chelating 2,2′-biquinoline (Biqu) ligand and two mutually cis Br(−) anions. The Biqu ligand is not planar, the dihedral angle between the quinoline systems being 17.2 (2)°. In the crystal, the complex mol­ecules are connected by C—H⋯Br hydrogen bonds, forming chains along the c axis. When viewed down the b axis, successive chains are stacked in opposite directions. Intra­molecular C—H⋯Br hydrogen bonds are also observed.