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(2,2′-Biquinoline-κ(2) N,N′)dibromidopalladium(II)

The Pd(II) ion in the title complex, [PdBr(2)(C(18)H(12)N(2))], is four-coordinated in a distorted square-planar environment by the two N atoms from the chelating 2,2′-biquinoline (Biqu) ligand and two mutually cis Br(−) anions. The Biqu ligand is not planar, the dihedral angle between the quinoline...

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Autor principal: Ha, Kwang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344352/
https://www.ncbi.nlm.nih.gov/pubmed/22590118
http://dx.doi.org/10.1107/S1600536812015425
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author Ha, Kwang
author_facet Ha, Kwang
author_sort Ha, Kwang
collection PubMed
description The Pd(II) ion in the title complex, [PdBr(2)(C(18)H(12)N(2))], is four-coordinated in a distorted square-planar environment by the two N atoms from the chelating 2,2′-biquinoline (Biqu) ligand and two mutually cis Br(−) anions. The Biqu ligand is not planar, the dihedral angle between the quinoline systems being 17.2 (2)°. In the crystal, the complex mol­ecules are connected by C—H⋯Br hydrogen bonds, forming chains along the c axis. When viewed down the b axis, successive chains are stacked in opposite directions. Intra­molecular C—H⋯Br hydrogen bonds are also observed.
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spelling pubmed-33443522012-05-15 (2,2′-Biquinoline-κ(2) N,N′)dibromidopalladium(II) Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Pd(II) ion in the title complex, [PdBr(2)(C(18)H(12)N(2))], is four-coordinated in a distorted square-planar environment by the two N atoms from the chelating 2,2′-biquinoline (Biqu) ligand and two mutually cis Br(−) anions. The Biqu ligand is not planar, the dihedral angle between the quinoline systems being 17.2 (2)°. In the crystal, the complex mol­ecules are connected by C—H⋯Br hydrogen bonds, forming chains along the c axis. When viewed down the b axis, successive chains are stacked in opposite directions. Intra­molecular C—H⋯Br hydrogen bonds are also observed. International Union of Crystallography 2012-04-18 /pmc/articles/PMC3344352/ /pubmed/22590118 http://dx.doi.org/10.1107/S1600536812015425 Text en © Kwang Ha 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ha, Kwang
(2,2′-Biquinoline-κ(2) N,N′)dibromidopalladium(II)
title (2,2′-Biquinoline-κ(2) N,N′)dibromidopalladium(II)
title_full (2,2′-Biquinoline-κ(2) N,N′)dibromidopalladium(II)
title_fullStr (2,2′-Biquinoline-κ(2) N,N′)dibromidopalladium(II)
title_full_unstemmed (2,2′-Biquinoline-κ(2) N,N′)dibromidopalladium(II)
title_short (2,2′-Biquinoline-κ(2) N,N′)dibromidopalladium(II)
title_sort (2,2′-biquinoline-κ(2) n,n′)dibromidopalladium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344352/
https://www.ncbi.nlm.nih.gov/pubmed/22590118
http://dx.doi.org/10.1107/S1600536812015425
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