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(2,2′-Biquinoline-κ(2) N,N′)dibromidopalladium(II)
The Pd(II) ion in the title complex, [PdBr(2)(C(18)H(12)N(2))], is four-coordinated in a distorted square-planar environment by the two N atoms from the chelating 2,2′-biquinoline (Biqu) ligand and two mutually cis Br(−) anions. The Biqu ligand is not planar, the dihedral angle between the quinoline...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2012
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344352/ https://www.ncbi.nlm.nih.gov/pubmed/22590118 http://dx.doi.org/10.1107/S1600536812015425 |
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author | Ha, Kwang |
author_facet | Ha, Kwang |
author_sort | Ha, Kwang |
collection | PubMed |
description | The Pd(II) ion in the title complex, [PdBr(2)(C(18)H(12)N(2))], is four-coordinated in a distorted square-planar environment by the two N atoms from the chelating 2,2′-biquinoline (Biqu) ligand and two mutually cis Br(−) anions. The Biqu ligand is not planar, the dihedral angle between the quinoline systems being 17.2 (2)°. In the crystal, the complex molecules are connected by C—H⋯Br hydrogen bonds, forming chains along the c axis. When viewed down the b axis, successive chains are stacked in opposite directions. Intramolecular C—H⋯Br hydrogen bonds are also observed. |
format | Online Article Text |
id | pubmed-3344352 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33443522012-05-15 (2,2′-Biquinoline-κ(2) N,N′)dibromidopalladium(II) Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Pd(II) ion in the title complex, [PdBr(2)(C(18)H(12)N(2))], is four-coordinated in a distorted square-planar environment by the two N atoms from the chelating 2,2′-biquinoline (Biqu) ligand and two mutually cis Br(−) anions. The Biqu ligand is not planar, the dihedral angle between the quinoline systems being 17.2 (2)°. In the crystal, the complex molecules are connected by C—H⋯Br hydrogen bonds, forming chains along the c axis. When viewed down the b axis, successive chains are stacked in opposite directions. Intramolecular C—H⋯Br hydrogen bonds are also observed. International Union of Crystallography 2012-04-18 /pmc/articles/PMC3344352/ /pubmed/22590118 http://dx.doi.org/10.1107/S1600536812015425 Text en © Kwang Ha 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ha, Kwang (2,2′-Biquinoline-κ(2) N,N′)dibromidopalladium(II) |
title | (2,2′-Biquinoline-κ(2)
N,N′)dibromidopalladium(II) |
title_full | (2,2′-Biquinoline-κ(2)
N,N′)dibromidopalladium(II) |
title_fullStr | (2,2′-Biquinoline-κ(2)
N,N′)dibromidopalladium(II) |
title_full_unstemmed | (2,2′-Biquinoline-κ(2)
N,N′)dibromidopalladium(II) |
title_short | (2,2′-Biquinoline-κ(2)
N,N′)dibromidopalladium(II) |
title_sort | (2,2′-biquinoline-κ(2)
n,n′)dibromidopalladium(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344352/ https://www.ncbi.nlm.nih.gov/pubmed/22590118 http://dx.doi.org/10.1107/S1600536812015425 |
work_keys_str_mv | AT hakwang 22biquinolinek2nndibromidopalladiumii |