Bis[μ-N′-(adamantan-1-ylcarbon­yl)-2-oxidobenzohydrazidato(3−)]tetra­pyridine­trinickel(II) dimethyl­formamide monosolvate monohydrate

In the title trinuclear Ni(II) compound, [Ni(3)(C(18)H(19)N(2)O(3))(2)(C(5)H(5)N)(4)]·C(3)H(7)NO·H(2)O, three Ni(II) cations are bridged by two N′-(adamantan-1-ylcarbon­yl)-2-oxidobenzohydrazidate trianions. The central Ni(II) cation has a distorted octa­hedral N(4)O(2) coordination environment wher...

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Detalles Bibliográficos
Autores principales: Wei, Han-Chang, Huang, Wan-Yun, Zhou, Xiang, Shi, Meng, Liang, Fu-Pei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344353/
https://www.ncbi.nlm.nih.gov/pubmed/22590119
http://dx.doi.org/10.1107/S1600536812013396
Descripción
Sumario:In the title trinuclear Ni(II) compound, [Ni(3)(C(18)H(19)N(2)O(3))(2)(C(5)H(5)N)(4)]·C(3)H(7)NO·H(2)O, three Ni(II) cations are bridged by two N′-(adamantan-1-ylcarbon­yl)-2-oxidobenzohydrazidate trianions. The central Ni(II) cation has a distorted octa­hedral N(4)O(2) coordination environment where a reverse torsion occurs between the two bridging ligands, whereas the two Ni(II) cations on the sides each adopt an N(2)O(2) square-planar coordination. Weak intra­molecular C—H⋯O and C—H⋯N inter­actions help to stabilize the mol­ecular structure. In the crystal, the lattice water mol­ecule links with the Ni(II) complex and dimethyl­formamide solvent mol­ecule via O—H⋯O hydrogen bonding.

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