Bis[μ-N′-(adamantan-1-ylcarbon­yl)-2-oxidobenzohydrazidato(3−)]tetra­pyridine­trinickel(II) dimethyl­formamide monosolvate monohydrate

In the title trinuclear Ni(II) compound, [Ni(3)(C(18)H(19)N(2)O(3))(2)(C(5)H(5)N)(4)]·C(3)H(7)NO·H(2)O, three Ni(II) cations are bridged by two N′-(adamantan-1-ylcarbon­yl)-2-oxidobenzohydrazidate trianions. The central Ni(II) cation has a distorted octa­hedral N(4)O(2) coordination environment wher...

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Autores principales: Wei, Han-Chang, Huang, Wan-Yun, Zhou, Xiang, Shi, Meng, Liang, Fu-Pei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344353/
https://www.ncbi.nlm.nih.gov/pubmed/22590119
http://dx.doi.org/10.1107/S1600536812013396
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author Wei, Han-Chang
Huang, Wan-Yun
Zhou, Xiang
Shi, Meng
Liang, Fu-Pei
author_facet Wei, Han-Chang
Huang, Wan-Yun
Zhou, Xiang
Shi, Meng
Liang, Fu-Pei
author_sort Wei, Han-Chang
collection PubMed
description In the title trinuclear Ni(II) compound, [Ni(3)(C(18)H(19)N(2)O(3))(2)(C(5)H(5)N)(4)]·C(3)H(7)NO·H(2)O, three Ni(II) cations are bridged by two N′-(adamantan-1-ylcarbon­yl)-2-oxidobenzohydrazidate trianions. The central Ni(II) cation has a distorted octa­hedral N(4)O(2) coordination environment where a reverse torsion occurs between the two bridging ligands, whereas the two Ni(II) cations on the sides each adopt an N(2)O(2) square-planar coordination. Weak intra­molecular C—H⋯O and C—H⋯N inter­actions help to stabilize the mol­ecular structure. In the crystal, the lattice water mol­ecule links with the Ni(II) complex and dimethyl­formamide solvent mol­ecule via O—H⋯O hydrogen bonding.
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spelling pubmed-33443532012-05-15 Bis[μ-N′-(adamantan-1-ylcarbon­yl)-2-oxidobenzohydrazidato(3−)]tetra­pyridine­trinickel(II) dimethyl­formamide monosolvate monohydrate Wei, Han-Chang Huang, Wan-Yun Zhou, Xiang Shi, Meng Liang, Fu-Pei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title trinuclear Ni(II) compound, [Ni(3)(C(18)H(19)N(2)O(3))(2)(C(5)H(5)N)(4)]·C(3)H(7)NO·H(2)O, three Ni(II) cations are bridged by two N′-(adamantan-1-ylcarbon­yl)-2-oxidobenzohydrazidate trianions. The central Ni(II) cation has a distorted octa­hedral N(4)O(2) coordination environment where a reverse torsion occurs between the two bridging ligands, whereas the two Ni(II) cations on the sides each adopt an N(2)O(2) square-planar coordination. Weak intra­molecular C—H⋯O and C—H⋯N inter­actions help to stabilize the mol­ecular structure. In the crystal, the lattice water mol­ecule links with the Ni(II) complex and dimethyl­formamide solvent mol­ecule via O—H⋯O hydrogen bonding. International Union of Crystallography 2012-04-18 /pmc/articles/PMC3344353/ /pubmed/22590119 http://dx.doi.org/10.1107/S1600536812013396 Text en © Wei et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wei, Han-Chang
Huang, Wan-Yun
Zhou, Xiang
Shi, Meng
Liang, Fu-Pei
Bis[μ-N′-(adamantan-1-ylcarbon­yl)-2-oxidobenzohydrazidato(3−)]tetra­pyridine­trinickel(II) dimethyl­formamide monosolvate monohydrate
title Bis[μ-N′-(adamantan-1-ylcarbon­yl)-2-oxidobenzohydrazidato(3−)]tetra­pyridine­trinickel(II) dimethyl­formamide monosolvate monohydrate
title_full Bis[μ-N′-(adamantan-1-ylcarbon­yl)-2-oxidobenzohydrazidato(3−)]tetra­pyridine­trinickel(II) dimethyl­formamide monosolvate monohydrate
title_fullStr Bis[μ-N′-(adamantan-1-ylcarbon­yl)-2-oxidobenzohydrazidato(3−)]tetra­pyridine­trinickel(II) dimethyl­formamide monosolvate monohydrate
title_full_unstemmed Bis[μ-N′-(adamantan-1-ylcarbon­yl)-2-oxidobenzohydrazidato(3−)]tetra­pyridine­trinickel(II) dimethyl­formamide monosolvate monohydrate
title_short Bis[μ-N′-(adamantan-1-ylcarbon­yl)-2-oxidobenzohydrazidato(3−)]tetra­pyridine­trinickel(II) dimethyl­formamide monosolvate monohydrate
title_sort bis[μ-n′-(adamantan-1-ylcarbon­yl)-2-oxidobenzohydrazidato(3−)]tetra­pyridine­trinickel(ii) dimethyl­formamide monosolvate monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344353/
https://www.ncbi.nlm.nih.gov/pubmed/22590119
http://dx.doi.org/10.1107/S1600536812013396
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