catena-Poly[(dichloridozinc)-μ-1-{4-[(1H-imidazol-1-yl)meth­yl]benz­yl}-1H-imidazole-κ(2) N (3):N (3′)]

The asymmetric unit of the title compound, [ZnCl(2)(C(14)H(14)N(4))](n), contains a Zn(II) ion situated on a twofold rotation axis and one-half of a 1-{4-[(1H-imidazol-1-yl)meth­yl]benz­yl}-1H-imidazole (L) ligand with the benzene ring situated on an inversion center. The Zn(II) ion is coordinated b...

Descripción completa

Detalles Bibliográficos
Autores principales: Wang, Cheng, Wen, Bo, Sun, Zhi-Yao, Yan, Peng-Fei, Gao, Jin-Sheng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344354/
https://www.ncbi.nlm.nih.gov/pubmed/22590120
http://dx.doi.org/10.1107/S1600536812015395
_version_ 1782231973627953152
author Wang, Cheng
Wen, Bo
Sun, Zhi-Yao
Yan, Peng-Fei
Gao, Jin-Sheng
author_facet Wang, Cheng
Wen, Bo
Sun, Zhi-Yao
Yan, Peng-Fei
Gao, Jin-Sheng
author_sort Wang, Cheng
collection PubMed
description The asymmetric unit of the title compound, [ZnCl(2)(C(14)H(14)N(4))](n), contains a Zn(II) ion situated on a twofold rotation axis and one-half of a 1-{4-[(1H-imidazol-1-yl)meth­yl]benz­yl}-1H-imidazole (L) ligand with the benzene ring situated on an inversion center. The Zn(II) ion is coordinated by two chloride anions and two N atoms from two L ligands in a distorted tetra­hedral geometry. The L ligands bridge ZnCl(2) fragments into polymeric chains parallel to [20-1].
format Online
Article
Text
id pubmed-3344354
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-33443542012-05-15 catena-Poly[(dichloridozinc)-μ-1-{4-[(1H-imidazol-1-yl)meth­yl]benz­yl}-1H-imidazole-κ(2) N (3):N (3′)] Wang, Cheng Wen, Bo Sun, Zhi-Yao Yan, Peng-Fei Gao, Jin-Sheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [ZnCl(2)(C(14)H(14)N(4))](n), contains a Zn(II) ion situated on a twofold rotation axis and one-half of a 1-{4-[(1H-imidazol-1-yl)meth­yl]benz­yl}-1H-imidazole (L) ligand with the benzene ring situated on an inversion center. The Zn(II) ion is coordinated by two chloride anions and two N atoms from two L ligands in a distorted tetra­hedral geometry. The L ligands bridge ZnCl(2) fragments into polymeric chains parallel to [20-1]. International Union of Crystallography 2012-04-18 /pmc/articles/PMC3344354/ /pubmed/22590120 http://dx.doi.org/10.1107/S1600536812015395 Text en © Wang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Cheng
Wen, Bo
Sun, Zhi-Yao
Yan, Peng-Fei
Gao, Jin-Sheng
catena-Poly[(dichloridozinc)-μ-1-{4-[(1H-imidazol-1-yl)meth­yl]benz­yl}-1H-imidazole-κ(2) N (3):N (3′)]
title catena-Poly[(dichloridozinc)-μ-1-{4-[(1H-imidazol-1-yl)meth­yl]benz­yl}-1H-imidazole-κ(2) N (3):N (3′)]
title_full catena-Poly[(dichloridozinc)-μ-1-{4-[(1H-imidazol-1-yl)meth­yl]benz­yl}-1H-imidazole-κ(2) N (3):N (3′)]
title_fullStr catena-Poly[(dichloridozinc)-μ-1-{4-[(1H-imidazol-1-yl)meth­yl]benz­yl}-1H-imidazole-κ(2) N (3):N (3′)]
title_full_unstemmed catena-Poly[(dichloridozinc)-μ-1-{4-[(1H-imidazol-1-yl)meth­yl]benz­yl}-1H-imidazole-κ(2) N (3):N (3′)]
title_short catena-Poly[(dichloridozinc)-μ-1-{4-[(1H-imidazol-1-yl)meth­yl]benz­yl}-1H-imidazole-κ(2) N (3):N (3′)]
title_sort catena-poly[(dichloridozinc)-μ-1-{4-[(1h-imidazol-1-yl)meth­yl]benz­yl}-1h-imidazole-κ(2) n (3):n (3′)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344354/
https://www.ncbi.nlm.nih.gov/pubmed/22590120
http://dx.doi.org/10.1107/S1600536812015395
work_keys_str_mv AT wangcheng catenapolydichloridozincm141himidazol1ylmethylbenzyl1himidazolek2n3n3
AT wenbo catenapolydichloridozincm141himidazol1ylmethylbenzyl1himidazolek2n3n3
AT sunzhiyao catenapolydichloridozincm141himidazol1ylmethylbenzyl1himidazolek2n3n3
AT yanpengfei catenapolydichloridozincm141himidazol1ylmethylbenzyl1himidazolek2n3n3
AT gaojinsheng catenapolydichloridozincm141himidazol1ylmethylbenzyl1himidazolek2n3n3

Ejemplares similares