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Tetrakis(1-phenyl-1H-imidazole-κN (3))bis(thiocyanato-κN)nickel(II)
The title compound, [Ni(NCS)(2)(C(9)H(8)N(2))(4)], crystallizes with two independent half-molecules in the asymmetric unit and the Ni(II) ions situated on centres of symmetry. In both independent molecules, the Ni(II) ion displays a compressed octahedral environment formed by four N atoms from th...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344356/ https://www.ncbi.nlm.nih.gov/pubmed/22590122 http://dx.doi.org/10.1107/S1600536812015437 |
| _version_ | 1782231974079889408 |
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| author | Zheng, Shao-Mei Liu, Bao-Cheng |
| author_facet | Zheng, Shao-Mei Liu, Bao-Cheng |
| author_sort | Zheng, Shao-Mei |
| collection | PubMed |
| description | The title compound, [Ni(NCS)(2)(C(9)H(8)N(2))(4)], crystallizes with two independent half-molecules in the asymmetric unit and the Ni(II) ions situated on centres of symmetry. In both independent molecules, the Ni(II) ion displays a compressed octahedral environment formed by four N atoms from the 1-phenyl-1H-imidazole ligands, which define the equatorial plane, with a mean Ni—N distance of 2.119 (11) Å, and two axial N atoms from two NCS(−) anions, with a mean Ni—N distance of 2.079 (7) Å. The crystal packing exhibits weak intermolecular S⋯S contacts of 3.411 (2) Å. |
| format | Online Article Text |
| id | pubmed-3344356 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33443562012-05-15 Tetrakis(1-phenyl-1H-imidazole-κN (3))bis(thiocyanato-κN)nickel(II) Zheng, Shao-Mei Liu, Bao-Cheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ni(NCS)(2)(C(9)H(8)N(2))(4)], crystallizes with two independent half-molecules in the asymmetric unit and the Ni(II) ions situated on centres of symmetry. In both independent molecules, the Ni(II) ion displays a compressed octahedral environment formed by four N atoms from the 1-phenyl-1H-imidazole ligands, which define the equatorial plane, with a mean Ni—N distance of 2.119 (11) Å, and two axial N atoms from two NCS(−) anions, with a mean Ni—N distance of 2.079 (7) Å. The crystal packing exhibits weak intermolecular S⋯S contacts of 3.411 (2) Å. International Union of Crystallography 2012-04-18 /pmc/articles/PMC3344356/ /pubmed/22590122 http://dx.doi.org/10.1107/S1600536812015437 Text en © Zheng and Liu 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Zheng, Shao-Mei Liu, Bao-Cheng Tetrakis(1-phenyl-1H-imidazole-κN (3))bis(thiocyanato-κN)nickel(II) |
| title | Tetrakis(1-phenyl-1H-imidazole-κN
(3))bis(thiocyanato-κN)nickel(II) |
| title_full | Tetrakis(1-phenyl-1H-imidazole-κN
(3))bis(thiocyanato-κN)nickel(II) |
| title_fullStr | Tetrakis(1-phenyl-1H-imidazole-κN
(3))bis(thiocyanato-κN)nickel(II) |
| title_full_unstemmed | Tetrakis(1-phenyl-1H-imidazole-κN
(3))bis(thiocyanato-κN)nickel(II) |
| title_short | Tetrakis(1-phenyl-1H-imidazole-κN
(3))bis(thiocyanato-κN)nickel(II) |
| title_sort | tetrakis(1-phenyl-1h-imidazole-κn
(3))bis(thiocyanato-κn)nickel(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344356/ https://www.ncbi.nlm.nih.gov/pubmed/22590122 http://dx.doi.org/10.1107/S1600536812015437 |
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