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catena-Poly[[[pentaaquacerium(III)]-μ-pyridine-2,4,6-tricarboxylato-κ(4) N,O (2),O (6):O (6′)] tetrahydrate]
The Ce(III) atom in the title compound, {[Ce(C(8)H(2)NO(6))(H(2)O)(5)]·4H(2)O}(n), is N,O,O′-chelated by the carboxylate trianion and is coordinated by five water molecules; a carboxyl O atom from an adjacent trianion bridges the Ce(III) atom, resulting in a chain running along the a axis. The nin...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344357/ https://www.ncbi.nlm.nih.gov/pubmed/22590123 http://dx.doi.org/10.1107/S1600536812015887 |
Sumario: | The Ce(III) atom in the title compound, {[Ce(C(8)H(2)NO(6))(H(2)O)(5)]·4H(2)O}(n), is N,O,O′-chelated by the carboxylate trianion and is coordinated by five water molecules; a carboxyl O atom from an adjacent trianion bridges the Ce(III) atom, resulting in a chain running along the a axis. The nine atoms surrounding the metal atom comprise a tricapped trigonal-prismatic polyhedron. The coordinated and lattice water molecules interact with each other and with the carboxyl O atoms by O—H⋯O hydrogen bonds, generating a three-dimensional network. |
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