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catena-Poly[[[pentaaquacerium(III)]-μ-pyridine-2,4,6-tricarboxylato-κ(4) N,O (2),O (6):O (6′)] tetrahydrate]
The Ce(III) atom in the title compound, {[Ce(C(8)H(2)NO(6))(H(2)O)(5)]·4H(2)O}(n), is N,O,O′-chelated by the carboxylate trianion and is coordinated by five water molecules; a carboxyl O atom from an adjacent trianion bridges the Ce(III) atom, resulting in a chain running along the a axis. The nin...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344357/ https://www.ncbi.nlm.nih.gov/pubmed/22590123 http://dx.doi.org/10.1107/S1600536812015887 |
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author | Sharif, Shahzad Khan, Islam Ullah Zaheer, Samia Ng, Seik Weng |
author_facet | Sharif, Shahzad Khan, Islam Ullah Zaheer, Samia Ng, Seik Weng |
author_sort | Sharif, Shahzad |
collection | PubMed |
description | The Ce(III) atom in the title compound, {[Ce(C(8)H(2)NO(6))(H(2)O)(5)]·4H(2)O}(n), is N,O,O′-chelated by the carboxylate trianion and is coordinated by five water molecules; a carboxyl O atom from an adjacent trianion bridges the Ce(III) atom, resulting in a chain running along the a axis. The nine atoms surrounding the metal atom comprise a tricapped trigonal-prismatic polyhedron. The coordinated and lattice water molecules interact with each other and with the carboxyl O atoms by O—H⋯O hydrogen bonds, generating a three-dimensional network. |
format | Online Article Text |
id | pubmed-3344357 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33443572012-05-15 catena-Poly[[[pentaaquacerium(III)]-μ-pyridine-2,4,6-tricarboxylato-κ(4) N,O (2),O (6):O (6′)] tetrahydrate] Sharif, Shahzad Khan, Islam Ullah Zaheer, Samia Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Ce(III) atom in the title compound, {[Ce(C(8)H(2)NO(6))(H(2)O)(5)]·4H(2)O}(n), is N,O,O′-chelated by the carboxylate trianion and is coordinated by five water molecules; a carboxyl O atom from an adjacent trianion bridges the Ce(III) atom, resulting in a chain running along the a axis. The nine atoms surrounding the metal atom comprise a tricapped trigonal-prismatic polyhedron. The coordinated and lattice water molecules interact with each other and with the carboxyl O atoms by O—H⋯O hydrogen bonds, generating a three-dimensional network. International Union of Crystallography 2012-04-18 /pmc/articles/PMC3344357/ /pubmed/22590123 http://dx.doi.org/10.1107/S1600536812015887 Text en © Sharif et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Sharif, Shahzad Khan, Islam Ullah Zaheer, Samia Ng, Seik Weng catena-Poly[[[pentaaquacerium(III)]-μ-pyridine-2,4,6-tricarboxylato-κ(4) N,O (2),O (6):O (6′)] tetrahydrate] |
title |
catena-Poly[[[pentaaquacerium(III)]-μ-pyridine-2,4,6-tricarboxylato-κ(4)
N,O
(2),O
(6):O
(6′)] tetrahydrate] |
title_full |
catena-Poly[[[pentaaquacerium(III)]-μ-pyridine-2,4,6-tricarboxylato-κ(4)
N,O
(2),O
(6):O
(6′)] tetrahydrate] |
title_fullStr |
catena-Poly[[[pentaaquacerium(III)]-μ-pyridine-2,4,6-tricarboxylato-κ(4)
N,O
(2),O
(6):O
(6′)] tetrahydrate] |
title_full_unstemmed |
catena-Poly[[[pentaaquacerium(III)]-μ-pyridine-2,4,6-tricarboxylato-κ(4)
N,O
(2),O
(6):O
(6′)] tetrahydrate] |
title_short |
catena-Poly[[[pentaaquacerium(III)]-μ-pyridine-2,4,6-tricarboxylato-κ(4)
N,O
(2),O
(6):O
(6′)] tetrahydrate] |
title_sort | catena-poly[[[pentaaquacerium(iii)]-μ-pyridine-2,4,6-tricarboxylato-κ(4)
n,o
(2),o
(6):o
(6′)] tetrahydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344357/ https://www.ncbi.nlm.nih.gov/pubmed/22590123 http://dx.doi.org/10.1107/S1600536812015887 |
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