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catena-Poly[[[penta­aqua­cerium(III)]-μ-pyridine-2,4,6-tricarboxyl­ato-κ(4) N,O (2),O (6):O (6′)] tetra­hydrate]

The Ce(III) atom in the title compound, {[Ce(C(8)H(2)NO(6))(H(2)O)(5)]·4H(2)O}(n), is N,O,O′-chelated by the carboxyl­ate trianion and is coordinated by five water mol­ecules; a carboxyl O atom from an adjacent trianion bridges the Ce(III) atom, resulting in a chain running along the a axis. The nin...

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Detalles Bibliográficos
Autores principales: Sharif, Shahzad, Khan, Islam Ullah, Zaheer, Samia, Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344357/
https://www.ncbi.nlm.nih.gov/pubmed/22590123
http://dx.doi.org/10.1107/S1600536812015887
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author Sharif, Shahzad
Khan, Islam Ullah
Zaheer, Samia
Ng, Seik Weng
author_facet Sharif, Shahzad
Khan, Islam Ullah
Zaheer, Samia
Ng, Seik Weng
author_sort Sharif, Shahzad
collection PubMed
description The Ce(III) atom in the title compound, {[Ce(C(8)H(2)NO(6))(H(2)O)(5)]·4H(2)O}(n), is N,O,O′-chelated by the carboxyl­ate trianion and is coordinated by five water mol­ecules; a carboxyl O atom from an adjacent trianion bridges the Ce(III) atom, resulting in a chain running along the a axis. The nine atoms surrounding the metal atom comprise a tricapped trigonal-prismatic polyhedron. The coordinated and lattice water mol­ecules inter­act with each other and with the carboxyl O atoms by O—H⋯O hydrogen bonds, generating a three-dimensional network.
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spelling pubmed-33443572012-05-15 catena-Poly[[[penta­aqua­cerium(III)]-μ-pyridine-2,4,6-tricarboxyl­ato-κ(4) N,O (2),O (6):O (6′)] tetra­hydrate] Sharif, Shahzad Khan, Islam Ullah Zaheer, Samia Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Ce(III) atom in the title compound, {[Ce(C(8)H(2)NO(6))(H(2)O)(5)]·4H(2)O}(n), is N,O,O′-chelated by the carboxyl­ate trianion and is coordinated by five water mol­ecules; a carboxyl O atom from an adjacent trianion bridges the Ce(III) atom, resulting in a chain running along the a axis. The nine atoms surrounding the metal atom comprise a tricapped trigonal-prismatic polyhedron. The coordinated and lattice water mol­ecules inter­act with each other and with the carboxyl O atoms by O—H⋯O hydrogen bonds, generating a three-dimensional network. International Union of Crystallography 2012-04-18 /pmc/articles/PMC3344357/ /pubmed/22590123 http://dx.doi.org/10.1107/S1600536812015887 Text en © Sharif et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sharif, Shahzad
Khan, Islam Ullah
Zaheer, Samia
Ng, Seik Weng
catena-Poly[[[penta­aqua­cerium(III)]-μ-pyridine-2,4,6-tricarboxyl­ato-κ(4) N,O (2),O (6):O (6′)] tetra­hydrate]
title catena-Poly[[[penta­aqua­cerium(III)]-μ-pyridine-2,4,6-tricarboxyl­ato-κ(4) N,O (2),O (6):O (6′)] tetra­hydrate]
title_full catena-Poly[[[penta­aqua­cerium(III)]-μ-pyridine-2,4,6-tricarboxyl­ato-κ(4) N,O (2),O (6):O (6′)] tetra­hydrate]
title_fullStr catena-Poly[[[penta­aqua­cerium(III)]-μ-pyridine-2,4,6-tricarboxyl­ato-κ(4) N,O (2),O (6):O (6′)] tetra­hydrate]
title_full_unstemmed catena-Poly[[[penta­aqua­cerium(III)]-μ-pyridine-2,4,6-tricarboxyl­ato-κ(4) N,O (2),O (6):O (6′)] tetra­hydrate]
title_short catena-Poly[[[penta­aqua­cerium(III)]-μ-pyridine-2,4,6-tricarboxyl­ato-κ(4) N,O (2),O (6):O (6′)] tetra­hydrate]
title_sort catena-poly[[[penta­aqua­cerium(iii)]-μ-pyridine-2,4,6-tricarboxyl­ato-κ(4) n,o (2),o (6):o (6′)] tetra­hydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344357/
https://www.ncbi.nlm.nih.gov/pubmed/22590123
http://dx.doi.org/10.1107/S1600536812015887
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