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Bis(methanesulfonato-κO)(5,10,15,20-tetraphenylporphyrinato-κ(4) N,N′,N′′,N′′′)tin(IV) chloroform trisolvate
In the crystal structure of the title compound, [Sn(C(44)H(28)N(4))(CH(3)O(3)S)(2)]·3CHCl(3), the Sn(IV) ion is located on an inversion center and is octahedrally coordinated. The porphyrin N atoms occupy the equatorial positions while the axial positions are occupied by the O atoms of the methane...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344358/ https://www.ncbi.nlm.nih.gov/pubmed/22590124 http://dx.doi.org/10.1107/S1600536812015875 |
Sumario: | In the crystal structure of the title compound, [Sn(C(44)H(28)N(4))(CH(3)O(3)S)(2)]·3CHCl(3), the Sn(IV) ion is located on an inversion center and is octahedrally coordinated. The porphyrin N atoms occupy the equatorial positions while the axial positions are occupied by the O atoms of the methanesulfonate anions. The phenyl rings make dihedral angles of 77.02 (13) and 87.89 (14)° with the porphyrin ring. Of the three solvent chloroform molecules, one is disordered over a twofold rotation axis. In the crystal a three-dimensional assembly is accomplished via C—H⋯O hydrogen bonds between the H atoms of the phenyl groups in the porphyrin ring and the O atoms of the methanesulfonate ligands. |
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